scholarly journals Synthesis and Characterizations of High Carbon Ferrochrome (HCFC) Slag Based Geopolymer

2021 ◽  
Author(s):  
Muktikanta Panigrahi ◽  
Saralasrita Mohanty ◽  
Ratan Indu Ganguly ◽  
Radha Raman Dash

In the present Investigation, Geopolymer (GP) is made using High carbon Ferrochrome (HCFC) slag by synthesizing silicon and aluminum present in it with alkali liquid solution which binds other non-reactive materials present in the slag. The compressive strength of GP is found to be 11 MPa after 7-days of air curing. Increasing air curing time to 28-days, the strength is measured to be 15 MPa. XRD analyses indicate that there is gradual transformation of crystalline phases to non-crystalline glassy phases. SEM images show presence of more amount of glassy phase after air curing for a longer time. This is also corroborated with mechanical properties such as compressive strength. TGA results are also discussed for both uncured and cured GP samples. DSC isotherms indicate oozing out of inbuilt water present in the prepared GP materials which is an indication of condensation polymerization reaction occurring during the formation of Geopolymers.

2021 ◽  
Vol 11 (7) ◽  
pp. 3032
Author(s):  
Tuan Anh Le ◽  
Sinh Hoang Le ◽  
Thuy Ninh Nguyen ◽  
Khoa Tan Nguyen

The use of fluid catalytic cracking (FCC) by-products as aluminosilicate precursors in geopolymer binders has attracted significant interest from researchers in recent years owing to their high alumina and silica contents. Introduced in this study is the use of geopolymer concrete comprising FCC residue combined with fly ash as the requisite source of aluminosilicate. Fly ash was replaced with various FCC residue contents ranging from 0–100% by mass of binder. Results from standard testing methods showed that geopolymer concrete rheological properties such as yield stress and plastic viscosity as well as mechanical properties including compressive strength, flexural strength, and elastic modulus were affected significantly by the FCC residue content. With alkali liquid to geopolymer solid ratios (AL:GS) of 0.4 and 0.5, a reduction in compressive and flexural strength was observed in the case of geopolymer concrete with increasing FCC residue content. On the contrary, geopolymer concrete with increasing FCC residue content exhibited improved strength with an AL:GS ratio of 0.65. Relationships enabling estimation of geopolymer elastic modulus based on compressive strength were investigated. Scanning electron microscope (SEM) images and X-ray diffraction (XRD) patterns revealed that the final product from the geopolymerization process consisting of FCC residue was similar to fly ash-based geopolymer concrete. These observations highlight the potential of FCC residue as an aluminosilicate source for geopolymer products.


2013 ◽  
Vol 438-439 ◽  
pp. 197-201
Author(s):  
Xian Hua Yao ◽  
Peng Li ◽  
Jun Feng Guan

Based on the generalization and analysis of laboratory experimental results on mix ratio, the effects of various factors such as cement content, water-cement ratio, curing time, curing conditions and types of cement on the mechanical properties of unconfined compressive strength of cement soil are presented. Results show that the unconfined compressive strength of cement soil increases with the growing curing time, and it is greatly affected by the cement content, water-cement ratio, cement types and curing time, while the effect of curing conditions is weak with a cement content of more than 10%. Moreover, the stress-strain of the cement soil responds with the cement content and curing time, increasing curing time and cement content makes the cement soil to be harder and brittle, and leads to a larger Young's modulus.


2011 ◽  
Vol 250-253 ◽  
pp. 788-794
Author(s):  
Shu Lin Zhan ◽  
Shu Sen Gao ◽  
Jun Ying Lai

In order to study the influence of modified polypropylene (PP) fiber on the physical and mechanical properties of curing sludge, the same amount of cement and different content of polypropylene fiber were mixed into the sludge. Unconfined compressive strength tests, water content tests and shear strength tests were carried out on different specimens with different curing time. The results show that the sludge curing effect is markedly improved by the addition of the polypropylene fiber. As to the curing sludge with the same curing time, when the content of the polypropylene fiber increases, the unconfined compressive strength and the cohesive strength greatly increase, and the internal frictional angle decreases.


Minerals ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 922
Author(s):  
Jiajian Li ◽  
Erol Yilmaz ◽  
Shuai Cao

Understanding the flow process of cemented tailings backfill (CTB) is important for successful pumping into underground stopes. This study examines the effects of solid content (SC), cement/tailings (c/t) ratio, and curing time (CT) on rheological and mechanical properties of CTB mixes. The slurry concentration of the mixes was 65, 67, and 69 wt. %, with c/t ratios ranging from 1:4 to 1:20. Unconfined compressive strength (UCS) tests were performed on hardened CTB mixes after curing 3, 7, and 28 days. The rheological properties of CTB slurries are mainly related to SC. The yield stress and viscosity of fresh mixes increase with increasing SC, but the pipeline resistance loss (PRL) also increases with increasing SC. According to the analysis of variance, the SC and flow rate are the most significant parameters which greatly affect the PRL performance. The c/t and CT parameters are the most significant parameters for affecting the shrinkage rate. The findings offer a reference for theoretical optimization for mine filling systems of similar type.


Materials ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1477 ◽  
Author(s):  
Ioana-Codruţa Mirică ◽  
Gabriel Furtos ◽  
Bogdan Bâldea ◽  
Ondine Lucaciu ◽  
Aranka Ilea ◽  
...  

The aim of this study was to evaluate the correlation between the percent of inorganic filler by weight (wt. %) and by volume (vol. %) of 11 flowable resin composites (FRCs) and their mechanical properties. To establish the correlation, the quantity of inorganic filler was determined by combustion and shape/size analyzed by SEM images. The compressive strength (CS), flexural strength (FS), and flexural modulus (FM) were determined. The CS values were between 182.87-310.38 MPa, the FS values ranged between 59.59 and 96.95 MPa, and the FM values were between 2.34 and 6.23 GPa. The percentage of inorganic filler registered values situated between 52.25 and 69.64 wt. % and 35.35 and 53.50 vol. %. There was a very good correlation between CS, FS, and FM vs. the inorganic filler by wt. % and vol. %. (R2 = 0.8899–0.9483). The highest regression was obtained for the FM values vs. vol. %. SEM images of the tested FRCs showed hybrid inorganic filler for Filtek Supreme XT (A3) and StarFlow (A2) and a homogeneous type of inorganic filler for the other investigated materials. All of the FS values were above 50 MPa, the ISO 4049/2019 limit for FRCs.


Materials ◽  
2019 ◽  
Vol 12 (7) ◽  
pp. 1173 ◽  
Author(s):  
Češnovar ◽  
Traven ◽  
Horvat ◽  
Ducman

Alkali activation is studied as a potential technology to produce a group of high performance building materials from industrial residues such as metallurgical slag. Namely, slags containing aluminate and silicate form a useful solid material when activated by an alkaline solution. The alkali-activated (AA) slag-based materials are promising alternative products for civil engineering sector and industrial purposes. In the present study the locally available electric arc furnace steel slag (Slag A) and the ladle furnace basic slag (Slag R) from different metallurgical industries in Slovenia were selected for alkali activation because of promising amorphous Al/Si rich content. Different mixtures of selected precursors were prepared in the Slag A/Slag R ratios 1/0, 3/1, 1/1, 1/3 and 0/1 and further activated with potassium silicate using an activator to slag ratio of 1:2 in order to select the optimal composition with respect to their mechanical properties. Bending strength of investigated samples ranged between 4 and 18 MPa, whereas compressive strength varied between 30 and 60 MPa. The optimal mixture (Slag A/Slag R = 1/1) was further used to study strength development under the influence of different curing temperatures at room temperature (R. T.), and in a heat-chamber at 50, 70 and 90 °C, and the effects of curing time for 1, 3, 7 and 28 days was furthermore studied. The influence of curing time at room temperature on the mechanical strength at an early age was found to be nearly linear. Further, it was shown that specimens cured at 70 °C for 3 days attained almost identical (bending/compressive) strength to those cured at room temperature for 28 days. Additionally, microstructure evaluation of input materials and samples cured under different conditions was performed by means of XRD, FTIR, SEM and mercury intrusion porosimetry (MIP).


2012 ◽  
Vol 193-194 ◽  
pp. 762-769 ◽  
Author(s):  
Hui Wang ◽  
Hai Xia Liu ◽  
Cai Hong Zhuang

Abstract:Polyurethane concrete which applies to the rapid repair highway pavement was systematically researched. Influences on mechanical properties of the polyurethane concrete of cement-dinas and binder-aggregate ratio, curing agent dosage, thinning agent dosage, etc. were analyzed in this paper. Furthermore, the optimal formulation materials were gotten to use in the repairment of used-broken cement blocks in the experiment. Simultaneously, the microstructure of polyurethane concrete and their adhesive situation bewteen waste cement blocks were observed through scanning electron microscope (SEM). The results show that the flexural strength of the specimen for two hours can reach to 6.67 MPa, and the compressive strength can reach to 9.15MPa, which can achieve the rapid pavement repair on highway in two hours, and it is superior to the related Chinese Standard. Besides the SEM images indicate that polyurethane molecular and aggregate are firmly bonded to each other as well as the cementation between polyurethane concrete and concretes, it means that the material has characteristic of rapid repair as well as good mechanical property.


2020 ◽  
Vol 38 (2A) ◽  
pp. 173-184 ◽  
Author(s):  
Saman M. Kamal ◽  
Jalal A. Saeed ◽  
Ahmed Mohammed

One of the main challenges facing Civil Engineering community is to modify cement quantity in the mix design by admixtures to enhance the mechanical properties. According to more than 1000 data from literature, mechanical characteristics of concrete modified with FA were discussed. The statistical variation with modeling were achieved by set of data. The cement was replaced up to 70% with FA (weight of dry cement) and by cube of concrete testing up to 90 days of curing time and different w/c ratio. The compressive strength of concrete varied from 18-67 MPa, while, for modified concrete with FA, compressive strength ranged from 21-94 MPa, tensile strength ranged from 1-9 MPa and flexural strengths ranged from 3 - 10 MPa. The w/c ratio of concrete modified with FA varied from 0.24-0.53, also the FA content varied from 0-50 %. Vipulanandan correlation model was effective by connecting mechanical properties and compare with Hoek-Brown model. The nonlinear model was used to investigate the effect of FA on properties of normal and high strength concrete. Study results presented a worthy correlation between compressive strength and curing time, w/c ratio and FA content. By using the interactive linked (model) for compressive, tensile, and flexural strengths of concrete quantified well as a function of w/c ratio, curing time and FA content by using a nonlinear relationship.


Alloy Digest ◽  
1969 ◽  
Vol 18 (4) ◽  

Abstract EB alloy is a high-carbon chromium alloy steel for general hot-work applications. It possesses good compressive strength and hot mechanical properties. It is recommended for hot header and gripper dies, shear blades, hot rivet sets, forging dies, cold forming and embossing dies. This datasheet provides information on composition, physical properties, hardness, elasticity, and compressive strength as well as fracture toughness. It also includes information on high temperature performance as well as forming, heat treating, machining, and joining. Filing Code: TS-217. Producer or source: Allegheny Ludlum Corporation.


1994 ◽  
Vol 370 ◽  
Author(s):  
Asif Ahmed ◽  
Leslie Struble

AbstractMechanical properties of any material, including hardened cement paste, are assumed to be controlled by its microstructure. An attempt has been made here to establish a link between bulk fracture parameters of hardened cement paste and its microstructure. Paste microstructure has been varied by changing the initial w/c ratio, curing time and curing temperature, and by addition of chemicals to change the calcium hydroxide morphology. It has been found that, like compressive strength, fracture parameters depend directly on porosity. Contrary to our initial hypothesis, CH morphology was found to have no effect on the fracture parameters.


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