The Effects of Oil Spill Eater II on Oil Degradation

2021 ◽  
Vol In Press (In Press) ◽  
Author(s):  
Mahdieh Yaghoubi ◽  
Ali Haghmoradkhani ◽  
Mohammad Rafiee ◽  
Mahsa Jahangiri-Rad

Background: Hydrocarbon contamination is considered to be a crucial environmental pollutant, which threatens the marine ecosystem and indirectly affects human health. Petrochemical industries are among the major sources of oil release into the environment. Several approaches are used to remove hydrocarbons from contaminated water, including biological, mechanical, and chemical methods. Oil Spill Eater II (OSE II) is an EPA-listed liquid nutrient with enzymes for the removal of hydrocarbons or other organic contaminants, which has also been proposed for the elimination of oil contaminates worldwide. Objectives: The present study aimed to evaluate the effects of OSE II on hydrocarbon degradation from contaminated seawater. Methods: In accordance with the instructions of the manufacturer, a combination of seawater and crude oil of various regions was prepared with a specific proportion. The amount of total petroleum hydrocarbon (TPH) before the addition of OSE II and after the treatment with OSE II was analyzed via gas chromatography-mass spectrometry (GC-MS). Results: The maximum removal rate of TPH from seawater was within the range of 59-75.5% after the OSE II treatment and 7-15 days of aeration. In addition, GC-MS indicated that the initial sharp peaks declined substantially due to the impact of OSE II on the destruction of hydrocarbon chains. Conclusions: According to the results, OSE II exhibited a high potential for the degradation of petroleum hydrocarbons.

2020 ◽  
Vol 4 (2) ◽  
pp. 127
Author(s):  
Paulin Yosephin Marini ◽  
Sherlly Monica Bonsapia ◽  
Johni R.V. Korwa

<p><em>This study aims to analyze a blowout from an oil and gas leak owned by PTT Exploration and Production (PTTEP) Australasia in the Montara oil field in the Indonesian Timor Sea, and how to resolve disputes between Australia and Indonesia. A qualitative approach was used in this study, whilst the data collection technique was through library research. The theory of state responsibility, the concept of human security, and the concept of international maritime law are used to analyze disputes between Indonesia and Australia. The study found that the Montara oil spill had not only damaged the marine ecosystem but also polluted Indonesian waters. It also found that although the Australian government had formed a special commission to resolve cases and even used dispersant, it had not satisfied all parties. Several points are summarized. First, the Montara oil spill in Australia is a transnational study because the impact has crossed national borders. Secondly, UNCLOS has a weakness in the settlement of the Montara case because the Convention only provides a description related to ‘Responsibility of Each Country’ and does not specifically arrange material compensation mechanisms to countries that cause sea pollution. Third, the Montara oil spill has caused huge losses for Indonesian seaweed farmers, especially 13 districts in NTT. The recommendations are that the Indonesian government along with the Montara Victim Peoples’ Advocacy Team should continue to follow up the case of oil spills from the Montara platform and continue to fight for compensation to the Australian government and the PTTEP as the responsible party.</em></p>


2019 ◽  
Vol 47 (7) ◽  
pp. 765-770 ◽  
Author(s):  
Monika Zbucka-Krętowska ◽  
Urszula Łazarek ◽  
Wojciech Miltyk ◽  
Iwona Sidorkiewicz ◽  
Piotr Pierzyński ◽  
...  

Abstract Background Bisphenol A (BPA) is an estrogenic, endocrine-disrupting compound widely used in the industry. It is also a ubiquitous environmental pollutant. Its presence was confirmed in human fetuses, which results from maternal exposure during pregnancy. The mechanisms behind maternal-fetal transfer, and relationships between pregnant women and fetal exposures remain unclear. The aim of this study was to assess the impact of maternal exposure to BPA on the exposure of the fetus. Methods Maternal plasma and amniotic fluid samples were collected from 52 pregnant women undergoing amniocentesis for prenatal diagnosis of chromosomal abnormalities. BPA was measured by gas chromatography-mass spectrometry (GC-MS). The permeability factor – a ratio of fetal-to-maternal BPA concentration – was used as a measure delineating the transplacental transfer of BPA. Results The median concentration of maternal plasma BPA was 8 times higher than the total BPA concentration in the amniotic fluid (8.69 ng/mL, range: 4.3 ng/mL–55.3 ng/mL vs. median 1.03 ng/mL, range: 0.3 ng/mL–10.1 ng/mL). There was no direct relationship between the levels of BPA in maternal plasma and amniotic fluid levels. The permeability factor, in turn, negatively correlated with fetal development (birth weight) (R = −0.54, P < 0.001). Conclusion Our results suggest that the risk of fetal BPA exposure depends on placental BPA permeability rather than the levels of maternal BPA plasma concentration and support general recommendations to become aware and avoid BPA-containing products.


2011 ◽  
Vol 3 (1) ◽  
Author(s):  
Lies Indah Sutiknowati

There is an information how to identify hydrocarbon degrading bacteria for bioremediation of marine oil spill. We have Bioremediation treatment for degradation of oil spill on Pari island and need two kind of experiment there are tanks experiment (sampling 0 to 90 days) and semi enclosed system (sampling 0 to 150 days). Biostimulation with nutrients (N and P) was done to analyze biodegradation of hydrocarbon compounds. Experiment design using fertilizer Super IB and Linstar will stimulate bacteria can degrade oil, n-alkane, and alkane as poly aromatic hydrocarbon. The bacteria communities were monitored and analyzed by Denaturing Gradient Gel Electrophoresis (DGGE) and Clone Library; oil chemistry was analyzed by Gas Chromatography Mass Spectrometry (GCMS). DNA (deoxyribonucleic acid) was extracted from colonies of bacteria and sequence determination of the 16S rDNA was amplified by primers U515f and U1492r. Strains had been sequence and had similarity about 90-99% to their closest taxa by homology Blast search and few of them suspected as new species. The results showed that fertilizers gave a significant effect on alkane, PAH and oil degradation in tanks experiment but not in the field test. Dominant of the specific bacteria on this experiment were Alcanivorax, Marinobacter and Prosthecochloris. Keywords: Bioremediation, Biostimulation, DGGE, PAH, Pari Island


GEOgraphia ◽  
2018 ◽  
Vol 20 (43) ◽  
pp. 124
Author(s):  
Amaury De Souza ◽  
Priscilla V Ikefuti ◽  
Ana Paula Garcia ◽  
Debora A.S Santos ◽  
Soetania Oliveira

Análise e previsão de parâmetros de qualidade do ar são tópicos importantes da pesquisa atmosférica e ambiental atual, devido ao impacto causado pela poluição do ar na saúde humana. Este estudo examina a transformação do dióxido de nitrogênio (NO2) em ozônio (O3) no ambiente urbano, usando o diagrama de séries temporais. Foram utilizados dados de concentração de poluentes ambientais e variáveis meteorológicas para prever a concentração de O3 na atmosfera. Foi testado o emprego de modelos de regressão linear múltipla como ferramenta para a predição da concentração de O3. Os resultados indicam que o valor da temperatura e a presença de NO2 influenciam na concentração de O3 em Campo Grande, capital do Estado do Mato Grosso do Sul. Palavras-chave: Ozônio. Dióxido de nitrogênio. Séries cronológicas. Regressões. ANALYSIS OF THE RELATIONSHIP BETWEEN O3, NO AND NO2 USING MULTIPLE LINEAR REGRESSION TECHNIQUES.Abstract: Analysis and prediction of air quality parameters are important topics of current atmospheric and environmental research due to the impact caused by air pollution on human health. This study examines the transformation of nitrogen dioxide (NO2) into ozone (O3) in the urban environment, using the time series diagram. Environmental pollutant concentration and meteorological variables were used to predict the O3 concentration in the atmosphere. The use of multiple linear regression models was tested as a tool to predict O3 concentration. The results indicate that the temperature value and the presence of NO2 influence the O3 concentration in Campo Grande, capital of the State of Mato Grosso do Sul.Keywords: Ozone. Nitrogen dioxide. Time series. Regressions. ANÁLISIS DE LA RELACIÓN ENTRE O3, NO Y NO2 UTILIZANDO MÚLTIPLES TÉCNICAS DE REGRESIÓN LINEAL.Resumen: Análisis y previsión de los parámetros de calidad del aire son temas importantes de la actual investigación de la atmósfera y el medio ambiente, debido al impacto de la contaminación atmosférica sobre la salud humana. Este estudio examina la transformación del dióxido de nitrógeno (NO2) en ozono (O3) en el entorno urbano, utilizando el diagrama de series de tiempo. Las concentraciones de los contaminantes ambientales de datos y variables climáticas fueron utilizadas para predecir la concentración de O3 en la atmósfera. El uso de múltiples modelos de regresión lineal como herramienta para predecir la concentración de O3 se puso a prueba. Los resultados indican que el valor de la temperatura y la presencia de NO2 influyen en la concentración de O3 en Campo Grande, capital del Estado de Mato Grosso do Sul.Palabras clave: Ozono. Dióxido de nitrógeno. Series de tiempo. Regresiones.


Polar Biology ◽  
2021 ◽  
Vol 44 (3) ◽  
pp. 575-586
Author(s):  
Pepijn De Vries ◽  
Jacqueline Tamis ◽  
Jasmine Nahrgang ◽  
Marianne Frantzen ◽  
Robbert Jak ◽  
...  

AbstractIn order to assess the potential impact from oil spills and decide the optimal response actions, prediction of population level effects of key resources is crucial. These assessments are usually based on acute toxicity data combined with precautionary assumptions because chronic data are often lacking. To better understand the consequences of applying precautionary approaches, two approaches for assessing population level effects on the Arctic keystone species polar cod (Boreogadus saida) were compared: a precautionary approach, where all exposed individuals die when exposed above a defined threshold concentration, and a refined (full-dose-response) approach. A matrix model was used to assess the population recovery duration of scenarios with various but constant exposure concentrations, durations and temperatures. The difference between the two approaches was largest for exposures with relatively low concentrations and short durations. Here, the recovery duration for the refined approach was less than eight times that found for the precautionary approach. Quantifying these differences helps to understand the consequences of precautionary assumptions applied to environmental risk assessment used in oil spill response decision making and it can feed into the discussion about the need for more chronic toxicity testing. An elasticity analysis of our model identified embryo and larval survival as crucial processes in the life cycle of polar cod and the impact assessment of oil spills on its population.


Water ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 156
Author(s):  
Manjing Lu ◽  
Jiaqi Wang ◽  
Yuzhong Wang ◽  
Zhengguang He

Chemical synthetic pharmaceutical wastewater has characteristics of high concentration, high toxicity and poor biodegradability, so it is difficult to directly biodegrade. We used acid modified attapulgite (ATP) supported Fe-Mn-Cu polymetallic oxide as catalyst for multi-phase Fenton-like ultraviolet photocatalytic oxidation (photo-Fenton) treatment with actual chemical synthetic pharmaceutical wastewater as the treatment object. The results showed that at the initial pH of 2.0, light distance of 20 cm, and catalyst dosage and hydrogen peroxide concentration of 10.0 g/L and 0.5 mol/L respectively, the COD removal rate of wastewater reached 65% and BOD5/COD increased to 0.387 when the reaction lasted for 180 min. The results of gas chromatography-mass spectrometry (GC-MS) indicated that Fenton-like reaction with Fe-Mn-Cu@ATP had good catalytic potential and significant synergistic effect, and could remove almost all heterocycle compounds well. 3D-EEM (3D electron microscope) fluorescence spectra showed that the fluorescence intensity decreased significantly during catalytic degradation, and the UV humus-like and fulvic acid were effectively removed. The degradation efficiency of the nanocomposite only decreased by 5.8% after repeated use for 6 cycles. It seems appropriate to use this process as a pre-treatment for actual pharmaceutical wastewater to facilitate further biological treatment.


Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 512
Author(s):  
Jeremiah Chimhundi ◽  
Carla Hörstmann ◽  
Evans M. N. Chirwa ◽  
Hendrik G. Brink

The main objective of this study was to achieve the continuous biorecovery and bioreduction of Pb(II) using an industrially obtained consortia as a biocatalyst. An upflow anaerobic sludge blanket reactor was used in the treatment process. The bioremediation technique that was applied made use of a yeast extract as the microbial substrate and Pb(NO3)2 as the source of Pb(II). The UASB reactor exhibited removal efficiencies of between 90 and 100% for the inlet Pb concentrations from 80 to 2000 ppm and a maximum removal rate of 1948.4 mg/(L·d) was measured. XRD and XPS analyses of the precipitate revealed the presence of Pb0, PbO, PbS and PbSO4. Supporting experimental work carried out included growth measurements, pH, oxidation–reduction potentials and nitrate levels.


Author(s):  
Emilio D’Ugo ◽  
Milena Bruno ◽  
Arghya Mukherjee ◽  
Dhrubajyoti Chattopadhyay ◽  
Roberto Giuseppetti ◽  
...  

AbstractMicrobiomes of freshwater basins intended for human use remain poorly studied, with very little known about the microbial response to in situ oil spills. Lake Pertusillo is an artificial freshwater reservoir in Basilicata, Italy, and serves as the primary source of drinking water for more than one and a half million people in the region. Notably, it is located in close proximity to one of the largest oil extraction plants in Europe. The lake suffered a major oil spill in 2017, where approximately 400 tons of crude oil spilled into the lake; importantly, the pollution event provided a rare opportunity to study how the lacustrine microbiome responds to petroleum hydrocarbon contamination. Water samples were collected from Lake Pertusillo 10 months prior to and 3 months after the accident. The presence of hydrocarbons was verified and the taxonomic and functional aspects of the lake microbiome were assessed. The analysis revealed specialized successional patterns of lake microbial communities that were potentially capable of degrading complex, recalcitrant hydrocarbons, including aromatic, chloroaromatic, nitroaromatic, and sulfur containing aromatic hydrocarbons. Our findings indicated that changes in the freshwater microbial community were associated with the oil pollution event, where microbial patterns identified in the lacustrine microbiome 3 months after the oil spill were representative of its hydrocarbonoclastic potential and may serve as effective proxies for lacustrine oil pollution.


2012 ◽  
Vol 60 (2) ◽  
pp. 117-126 ◽  
Author(s):  
Juliana Souza Azevedo ◽  
Belisandra Lopes ◽  
Alberto Katsumiti ◽  
Elisabete Santis Braga ◽  
Helené Roche ◽  
...  

Different components of the mixed function oxidase (MFO) system and the levels of fluorescent aromatic compounds in bile (FACs) were measured in Cathorops spixii in order to assess the impact of polycyclic aromatic hydrocarbons (PAHs). Fish were sampled in an estuary (Santos/São Vicente) with a history of contamination by PAHs, mainly due to the presence of the industrial complex of Cubatão city and of another of low anthropogenic influence (Cananéia) on the Brazilian coast. FACs were higher in fish from the polluted site, and the PAH 5 and 6-ring metabolites were the most frequent - with 14% and 15%, respectively. Levels of the different components of the MFO system showed the same variation profile as the FACs for both estuaries. Therefore, the values found for somatic indexes and biomarkers with data of bile PAH metabolites indicate the presence of organic contaminants, especially in the area subject to the influence of the industrial complex on the Santos/São Vicente estuary.


2000 ◽  
Vol 37 (3) ◽  
pp. 662-675 ◽  
Author(s):  
R Kerry Rowe ◽  
Chris J Caers ◽  
Glenn Reynolds ◽  
Cliff Chan

Considerations related to the design of the Halton Landfill as a "hydraulic trap" are summarized together with the research that was conducted to support the design concept. The interrelationship between hydrogeology and the engineered design is examined. Laboratory experiments demonstrated that there can be diffusion away from a source, even with significant inward velocity. Existing theory was found to provide a good prediction of the observed concentration profile in these experiments. It is also shown that a pressurized air pocket below the clay effectively acts as a zero-flux boundary and hence, with respect to migration of chloride, could be conservatively neglected in the impact assessment. The results of the impact calculations predict only a small increase in chloride concentration in the receptor aquifer while there is negligible predicted impact due to organic contaminants. The landfill was designed and constructed with a granular "sub-liner contingency layer" (SLCL) beneath the compacted liner. The operation of this layer is discussed. Finally, the construction of the compacted clayey liner with a hydraulic conductivity of 1 × 10-8 cm/s is documented.Key words: landfill, hydraulic containment, liner, field case, construction.


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