Spreading Agents Provide a New Oil Spill Response Option
ABSTRACT This paper describes research on a new approach to oil spill response that utilizes a silicone-based spreading agent to cause thick oil slicks to spread to extremely thin sheens. The increased surface area of the thin sheens will enhance the evaporation of the oil. Although this requires additional study, we expect that any residual oil that remains after evaporation will be less toxic because the volatile components are also soluble and contain at least a component of oil toxicity. In addition, spreading the oil will reduce areal loading of the oil and result in very low concentrations of oil entering the water column if wave energy disperses the sheens. Our tests established the ability of a silicone-based spreading agent to spread viscous oil to a thicknesses that was visually not detectable. Further, we found that treating a stable water-in-oil emulsion resulted in breaking of the emulsion and continued spreading to a thickness that was also visually not detectable. We believe the emulsion was broken when the thickness of the oil became less than the diameter of the emulsified water droplets. The new response approach is a method of reducing the impacts of offshore marine oil spills by promoting rapid spreading of the oil. This in turn increases evaporation rates, breaks emulsions, and potentially enhances natural dispersion of residual oil. The final result is less hydrocarbon transferred to the water column and reduced toxicity of the hydrocarbon that is transferred.