scholarly journals Concentration of Heavy Metals (Cd, Co, Cr, & Fe) in Soil and Edible Vegetables in Obudu Urban Area of Cross River State, Nigeria

Author(s):  
Akpe, Michael Akomaye ◽  
Ubua, Placcidus Unimuyi

The soil and edible vegetable samples were collected from Obudu Urban Area of Cross River State and were digested and analyzed for the Cd, Co, Cr, and Fe (heavy metals) concentration using Atomic Absorption Spectrometer (AAS) in the University of Calabar Laboratory. The eight vegetables considered for the study were Amaranthus spp., Corchorus olitorius, Murraya koenigii, Ocimum grattissimum, Solanum melongena, Talinum triangulare, Telferia occidentalis and Vernonia amygdalina. The results showed that the mean concentration of the metal in the soil in mgkg-1 ranged from (0.004-0.0048) and (0.005-0.046) in rainy and dry seasons respectively for Cd, (0.004-0.025) and (0.006-0.016) in rainy and dry season respectively for Cr, and (0.112-0.173) and (0.116-0.151) in rainy and dry season respectively for Fe. The concentration of Co was not detected in the soil or vegetables. The mean concentration accumulated by the vegetables and that present in the soil was in the order: Fe> Cd> Cr> Co. These results suggest that there is no significant difference between the amount of metals in the soil or that accumulated by the vegetables in rainy and dry seasons of the year. Also the amount of metals accumulated by most of the vegetables was directly proportional to the amount present in the soil where they are planted. The bioaccumulation ratios were all less than 1. These results indicate that the concentration of Cd, Co, Cr, & Fe in the soil and vegetables were still low and within the permissible limits of WHO/FAO. Thus, the consumption of the vegetables in the area may not cause any harm for now.

Author(s):  
Akpe, Michael Akomaye ◽  
Ashishie, Providence Beteluwhobel ◽  
Inezi, Faith Patrick

Aim: The aim of the study was to determine concentration of heavy metals in the soil and edible vegetables planted consumed Yala Urban Area of Cross River State, Nigeria, ascertained the level of metals contamination and the possible health risk or implication. Sampling: Forty eight (48) soil and edible vegetable samples (6 of each kind of the 8 vegetables) were collected randomly from Yala Urban Area of Cross River State. The eight vegetables considered for the study were Amaranthus spp., Corchorus olitorius, Murraya koenigii, Ocimum grattissimum, Solanum melongena, Talinum triangulare, Telferia occidentalis and Vernonia amygdalina. They were collected between January and March for dry season, and July and September for rainy season of the year.  Methodology: The samples were digested and analyzed for the Cr, Fe, Hg and Ni (heavy metals) concentration using Flame Atomic Absorption Spectrometer (AAS) in the Chemistry Laboratory, University of Calabar. Results: The results showed that the mean concentration of the metals in the soil in mgkg-1 ranged from (0.063 - 0.108) and (0.049 - 0.104) in rainy and dry seasons respectively for Cr, and (0.026 - 0.124) and (0.013 - 0.119) in rainy and dry season respectively for Fe. The mean concentration accumulated by the vegetables ranged from (0.037- 0.063) and (0.029 - 0.066) in rainy and dry season respectively for Cr and (0.012- 0.071) and (0.008- 0.086) in rainy and dry season respectively. Hg and Ni were neither detected in the soil nor in the vegetables. The trend of the metals in both the soil and vegetable was in the order: Cr > Fe> Hg> Ni. The Target Hazard Quotients were all less than 1, indicating no health risk. Conclusion: These results suggest that there is no significant difference between the amount of metals in the soil or that accumulated by the vegetables in rainy and dry seasons of the year. Also the amount of metals accumulated by most of the vegetables was directly proportional to the amount present in the soil where they are planted. These results indicate that the concentration of Cr, Fe, Hg and Ni in the soil and vegetables were still low and within the permissible limits of WHO/FAO. Thus, the consumption of the vegetables in the area may not pose any risk at the moment.


Author(s):  
Michael Akomaye Akpe ◽  
Joseph Odey ◽  
John Akwagiobe Agwupuye

The soil and edible vegetable samples were collected from Obanliku Urban Area of Cross River State and were digested and analyzed for the cadmium (Cd), chromium (Cr), iron (Fe) and mercury (Hg) (heavy metals) concentration using Flame Atomic Absorption Spectrometer (AAS) in Chemistry Laboratory, University of Calabar. The eight vegetables were considered such as Amaranthus spp., Corchorus olitorius, Murraya koenigii, Ocimum grattissimum, Solanum melongena, Talinum triangulare, Telfaira occidentalis and Vernonia amygdalina. The results revealed that the mean concentration of the metals in the soil in mgkg-1 ranged from (0.003-0.017) and (0.003-0.015) for Cd, (0.005-0.040) and (0.004-0.038) for Cr, and (0.052-1.541) and (0.050-1.511) for Fe in rainy and dry seasons respectively. Also, the mean concentration of the metals accumulated by the vegetables in mgkg-1 ranged from (0.002-0.010) for Cd, (0.003-0.018) and (0.003-0.016) for Cr, and (0.013-0.175) and (0.013-0.150) for Fe in rainy and dry season respectively. The concentration of Hg was not detected in the soil or vegetables. The mean concentration accumulated by the vegetables and that present in the soil was in the order: Fe > Cr > Cd > Hg. These results showed that there is no significant difference between the amount of metals in the soil or that accumulated by the vegetables in rainy and dry seasons of the year. Also the amount of metals accumulated by most of the vegetables was directly proportional to the amount present in the soil where they are planted. The bioaccumulation ratios and Target Hazard Quotients (THQ) were all less than 1. The results indicate that the concentration of Cd, Cr, Fe & Hg in the soil and vegetables were still low and within the permissible limits of WHO/FAO. Thus, the consumption of the vegetables in the area at the time when this study was carried out may not pose any health risk.


2020 ◽  
Vol 24 (5) ◽  
pp. 835-838
Author(s):  
M.A. Akpe ◽  
P.U. Ubua ◽  
I.B. Onyebuenyi

The average level of cadmium (Cd), cobalt (Co), lead (Pb) and zinc (Zn) in the soil and edible vegetables samples collected randomly in Yala Urban Area of Cross River State was determined using flame Atomic Absorption Spectrometer. The samples were digested and analyzed for the metals level or concentration in Chemistry Laboratory, University of Calabar. The eight vegetables selected for the study were Amaranthus spp., Corchorusolitorius, Murraya koenigii, Ocimum grattissimum, Solanum melongena, Talinum triangulare, Telferia occidentalis and Vernonia amygdalina. The results indicated that the average level of the metals in the soil in mgkg-1 ranged from (0.005-0.021) and (0.004-0.019) in rainy and dry seasons respectively for Cadmium, (0.162- 0.475) and (0.163- 0.472) in rainy and dry season respectively for Cobalt, and (0.434-1.030) and (0.432-1.027) in rainy and dry season respectively for Zinc. Also, the average level of the metals accumulated by the vegetables in mgkg-1 ranged from (0.002-0.009) and (0.001- 0.007) in rainy and dry season respectively for Cadmium, (0.050-0.198) and (0.048-0.195) in rainy and dry season respectively for Cobalt, and (0.158-0.383) and (0.156-0.380) in rainy and dry season respectively for Zinc. The level of Lead in the soil or vegetables was not detected. The average level of metals accumulated by the vegetables and that present in the soil was in the order: Zinc > Cobalt > Cadmium > Lead. These results revealed that there is no significant difference between the level of metals in the soil or that accumulated by the vegetables in rainy and dry seasons of the year. Also the level of metals accumulated by most of the vegetables was directly proportional to the amount present in the soil where they are planted. The Target Hazard Quotients of these metals was less than 1. These results imply that the concentration of Cadmium, Cobalt, Zinc and Lead in the soil and vegetables were still low and within the permissible limits of World Health Organization. Thus, the consumption of the vegetables in the area may not pose any health risk for now. Keywords: Heavy metals, Concentration, Soil, Edible vegetables.


2020 ◽  
Vol 4 (2) ◽  
pp. 16-21
Author(s):  
M. M. Karaye ◽  
H. A. Ibrahim

Study of Seven heavy metals namely, Zinc, Lead, Copper, Cadmium, Manganese, Chromium and Nickel was conducted in Mai-Allo pond, Gwale, Kano State in order to assess the concentration of the heavy metals in the pond. The results of the heavy metals showed that Zn has a value of 0.34±0.17 mg-l in the wet season and 0.49±0.37 mg-l in the dry season, Cu has a value of 1.42±0.14 mg-l in the wet season and 0.64±0.09 mg-l in the dry season, and Ni also has 0.12±0.02 mg-l in the wet season and 0.23±0.13 mg-l in the dry season, all these were within acceptable limits, while Pb with a value of 0.05±0.02 mg-l was within the limits during the wet season but during the dry season, the value 0.14±0.09mg-l exceeds the limits. Cd has a value of 0.06±0.01 in the wet season and 0.17±0.12 in the dry season, Cr has 0.36±0.12 in the wet season and 0.04±0.07 in the dry season, and Mn also has values of 0.46±0.12 and 0.22±0.03 in the wet and dry seasons respectively. Hence there was no significant difference (P>0.05) in the mean values of the sampling stations of the heavy metals during the wet and dry seasons. The study showed that the pond water was polluted with some heavy metals and hence measures must be taken to ensure the safety of the aquatic ecosystem, humans and the environment.


2021 ◽  
Vol 25 (5) ◽  
pp. 841-845
Author(s):  
C.A.E. Ibhadode ◽  
I.R. Ilaboya

Groundwater pollution by heavy metals such as lead, copper, nickel and iron is one of the major environmental issues of concern which has developed into a widely studied area. In this study, attempt was made to investigate the level of heavy metals in selected boreholes around the vicinity of cemeteries in Benin City. Seventy-two (72) samples of groundwater were taken from boreholes in 9 stations around the three cemeteries in Benin City on monthly basis. The samples were analysed for 7 heavy metals, in accordance with standard procedures. The heavy metals include; Zinc, Lead Iron, Copper, Cadmium, Nickel and Mercury. From the results of the study, a variation in the mean concentration of zinc was observed. The mean concentration of zinc in site 1 was 0.450mg/l, for site 2, it was 0.140mg/l and for site 3, it was 1.0533mg/l. For iron, mean concentration was 0.072mg/l in site 1. For site 2, mean concentration of iron was 2.140mg/l and for site 3, mean concentration of iron was 0.560mg/l. It was further revealed based on the results that mean value of heavy metals in groundwater around cemeteries in Benin City were generally lower during dry season compared to wet season. In addition, result of computed pollution index (Pi) revealed that the heavy metal with the highest potential to pollute groundwater is Cadmium, with Pi of 0.5333 and 0.400 representing dry season and wet season respectively.


2012 ◽  
Vol 21 (1) ◽  
pp. 28-31
Author(s):  
Claudia Navarro dos Santos ◽  
Luciene Soares de Souza ◽  
Vivian Suane de Freitas Vieira ◽  
Jairo Pinheiro ◽  
Maria de Lurdes de Azevedo Rodrigues

The presence of cyathostomin larvae is directly associated to climatic conditions of each region. This study aimed to evaluate the ecology of infective larvae on Brachiaria humidicola during the dry and rainy seasons from October 2007 to September 2008 in a tropical region, Rio de Janeiro state, southeastern Brazil. Stools were collected from the rectum of horses naturally infected with cyathostomins at the beginning of the rainy season (October to March) and dry season (April to September). They were divided into four samples of 500 g and deposited on a grass patch of B. humidicola. Seven days later and every 15 days thereafter samples of feces and grass were collected and processed by the Baermann technique. The mean number of larvae recovered from the grass varied according to the season, with greater recovery of larvae during the peak of the dry season (14,700 L3.kg-¹ DM). There was a statistically significant difference between L3 recovered from feces and grass, but not between L3 recovered from the grass base and apex. These results show that the region’s climate favors the development and survival of infective cyathostomin larvae throughout the year, with a greater number of larvae during the dry season.


2021 ◽  
Vol 5 (2) ◽  
pp. 498-510
Author(s):  
A. H. Santuraki ◽  
A. U. Babayo ◽  
Abdu Zakari ◽  
A. G. Abdulkadir

This study was carried out in ten (10) different locations within River Gongola, its Dam, and Dadinkowa Dam, Gombe State, Nigeria during the wet and dry season to study the water quality in terms of physicochemical properties to ascertain the levels of contaminants due to flooding and anthropogenic activities and the levels of heavy metals (Cr, Cd, Pb, and Ni) in the two species of fish (Clarias gariepinus and Bagrus docmak). A total of 200 water and 360 fish samples comprising two different species were collected in the month of March-June 2017 (Dry season) and July-October 2017 (Wet Season). The results of physicochemical properties obtained ranges between Temperature 29.0-30 0C and 30-32 0C, pH 5.4-7.8 and 6.0-6.9, Conductivity 93.3-161 μS/cm3 and 104.9-128 μS/cm3, Dissolved oxygen 1.2-3.98 mg/l and 0.4-3.1 mg/l, Total Suspended Solids 10-860 mg/l and 13-1180 mg/l, Total Dissolved Solids 46.5-80.5 mg/l and 54.2-76.5 mg/l, Turbidity 424.7-783.5 NTU and 11.15-442.1 NTU, Phosphate 1.82-7.23 mg/l and 0.00-0.11 mg/l, and Nitrate 2.25-8.82 mg/l and 2.68-6.81 mg/l during wet and dry season respectively. The result reveals that turbidity, PO43, DO, TSS, and TDS were above the acceptable permissible limits of WHO While the mean concentration levels of heavy metals in Clarias gariepinus and Bagrus docmak revealed that Cr was below the detectable limit while Cd ranges between 0.5-7.75 µg/g, Pb rangesbetween 3.9-35.6 µg/g during the wet and dry season. The mean concentrations of all the studied metals were above the permissible limit of WHO with a higher concentration during the dry season.


2019 ◽  
Vol 1 ◽  
pp. 105-112
Author(s):  
G Chessed ◽  
D C Sakiyo ◽  
A B Yako

Rapid urbanization and industrialization in developing countries have been associated with production and deposition of hazardous wastes in the soil environments. Heavy metals are major components of these wastes and have been implicated in several metal-related diseases and food poisoning in man. This study examined the concentration of Iron (Fe), Lead (Pb), Copper (Cu), Chromium (Cr), and Cadmium (Cd) heavy metals in soil near dumpsites of Jimeta and Ngurore, Yola North Local Government Areas (LGAs), Adamawa State. Soil samples from 0-20cm layer depth were collected in triplicates and analyzed using atomic absorption spectrophotometer (AAS). Results reveal that Fe, Pb, Cu and Chromium were detected, while Cadmium was found to be below the limit of detection. The mean concentration of the exchangeable cation in mg/kg in soil at Jimeta sites were: Fe (31.4 mg/kg) >Pb (0.92 mg/kg) > Cu (0.34 mg/kg) > Cr (0.11 mg/kg) >Cd (below limit of detection), while the mean concentration of the heavy metals in soil at Ngurore sites were: Fe (32 mg/kg) >Pb (0.83 mg/kg) > Cu (0.28 mg/kg) > Cr (0.07 mg/kg) >Cd (below limit of detection), respectively. Iron (Fe) was the most abundant element in both sites, followed by Pb. Heavy metal concentrations in soil followed the order of Fe>Pb>Cu>Cr>Cd, respectively. The paired T-test analyses for concentration of Cr, Fe, and Pb in soil nearthe two dumpsites show that there were statistically significant differences in the concentration levels of Cr, Fe, and Pb, while Cu showed no statistically significant difference between the two dumpsites. However, all the metals detected were below the permissible limit of WHO international standard with the exception of Pb whose concentration was above maximum permissible concentration (MPC). Persistent heavy metals accumulation in soils near these dumpsites may lead to increase uptake by vegetables grown near the dumpsites and this may pose a threat to its quality and safety and ultimately human health. The need to replace open dumpsites with well-designed landfills is advised.


2021 ◽  
Vol 45 (1) ◽  
Author(s):  
Elijah Abakpa Adegbe ◽  
Oluwaseyi Oluwabukola Babajide ◽  
Lois Riyo Maina ◽  
Shola Elijah Adeniji

Abstract Background Heavy metal accumulation in the ecosystem constitutes a potential toxic effect which is hazardous to human health. Increasing environmental pollution has necessitated the use of cattle egrets to evaluate the levels of heavy metal contamination, to establish their use in biomonitoring of heavy metals and to provide data for monitoring pollution in the environment. Results The present study assessed the utilization of Bubulcus ibis in monitoring pollution in five abattoirs, namely Agege, Bariga, Kara, Itire and Idi-Araba, all situated in Lagos State. The concentration of five (5) heavy metals, cadmium (Cd), copper (Cu), nickel (Ni), lead (Pb) and zinc (Zn) was determined in the liver, muscle and feather of Bubulcus ibis using the atomic absorption spectrophotometer. The trend of metal accumulation was in the order: Zn > Cu > Pb > Cd > Ni for all the sampled tissues. The mean tissue concentrations of the metals were significantly different (p < 0.05) among the sites. The highest levels of metal concentration were reported in the liver in all the locations. Mean concentration of Cd in Kara (0.003 ± 0.00058) was significantly (p < 0.05) higher than those found at Agege (0.0013 ± 0.00058) and Idi-Araba (0.001 ± 0.001). A significant difference (p < 0.05) was also observed between the mean concentrations of Cu in Bariga (0.01 ± 0.001) and Idi-Araba (0.003 ± 0.001). Conclusion All the studied heavy metals were present in the liver, muscle and feathers of the cattle egrets. The contamination levels were ascertained from the study which indicated that cattle egrets are useful in biomonitoring studies and the generated data will serve as baseline data which could be compared with data from other locations for monitoring heavy metal pollution.


2021 ◽  
Vol 11 (5) ◽  
Author(s):  
Saheed Adekunle Ganiyu ◽  
Abimbola Temitope Oyadeyi ◽  
Azeem Adedeji Adeyemi

AbstractThis study has been conducted to appraise the concentrations of selected heavy metals and total dissolved solids (TDSs) in the drinking water from shallow wells in parts of Ibadan metropolis, southwest Nigeria. Fifteen (15) water samples were collected from three representative residential locations [traditional core area (TCA), peri-urban area (PUA), and urban area (UA)] for geochemical analysis. Heavy metals and TDS were analyzed with the aid of atomic absorption spectrophotometer and calibrated meter, respectively. The mean concentration (mg/L) of Zn, Pb Mn, Fe, and Cd has been 3.930, 0.658, 0.0304, 1.698, and 0.501, respectively, and as a consequence, the order of abundance of studied metals was Zn > Fe > Pb > Cd > Mn. Concentrations of Zn, Fe, Pb, and Cd were higher than recommended standards in 60%, 86.7%, 100%, and 100% of groundwater samples, respectively. However, at all points tested, the mean concentrations of Mn and TDS in water samples lie within the safe limits set by World Health Organization. The evaluation of geoaccumulation index (Igeo), enrichment factor (EF), and contamination factor suggests that representative water samples were low-to-moderate contamination. The potential ecological risk index advocates low-to-moderate ecological risk in TCA and PUA, while it demonstrated exclusive “moderate” risk in UA. Further, the range of pollution load index (PLI) (0.55–1.32) in both TCA and PUA shows nil-to-moderate pollution status, while PLI values > 1 in UA indicate moderate contaminated state. The degree of contamination in groundwater showed the following trends: UA > TCA > PUA in the study area. Moreover, the results of EF and quantification of contamination of analyzed metals in water samples indicate geogenic and anthropogenic inputs. The contribution of studied metals to the incidence of non-cancer risk via oral intake within the residential sites follows the order: cadmium > lead > zinc > iron > manganese. The hazard index as a result of ingested heavy metals for the three population classes surpasses the acceptable range in the order of infant < child < adult. Cadmium and lead made considerable impact to the estimation of cancer risk in the study area for the three human population categories. Factor analysis extracted only one component that explained 94.64% of the entire variance, while cluster analysis identified three distinct groups based on similar water quality characteristics. Based on the findings of the study, awareness programs toward protecting the shallow groundwater sources should be launched, encouraged, and sustained. Moreover, the study suggests better hygienic practices and pre-treatment of contaminated water before consumption.


Sign in / Sign up

Export Citation Format

Share Document