scholarly journals Investigation of Heavy Metals Level in selected Boreholes around the Vicinity of some Cemeteries in Benin City, Nigeria

2021 ◽  
Vol 25 (5) ◽  
pp. 841-845
Author(s):  
C.A.E. Ibhadode ◽  
I.R. Ilaboya

Groundwater pollution by heavy metals such as lead, copper, nickel and iron is one of the major environmental issues of concern which has developed into a widely studied area. In this study, attempt was made to investigate the level of heavy metals in selected boreholes around the vicinity of cemeteries in Benin City. Seventy-two (72) samples of groundwater were taken from boreholes in 9 stations around the three cemeteries in Benin City on monthly basis. The samples were analysed for 7 heavy metals, in accordance with standard procedures. The heavy metals include; Zinc, Lead Iron, Copper, Cadmium, Nickel and Mercury. From the results of the study, a variation in the mean concentration of zinc was observed. The mean concentration of zinc in site 1 was 0.450mg/l, for site 2, it was 0.140mg/l and for site 3, it was 1.0533mg/l. For iron, mean concentration was 0.072mg/l in site 1. For site 2, mean concentration of iron was 2.140mg/l and for site 3, mean concentration of iron was 0.560mg/l. It was further revealed based on the results that mean value of heavy metals in groundwater around cemeteries in Benin City were generally lower during dry season compared to wet season. In addition, result of computed pollution index (Pi) revealed that the heavy metal with the highest potential to pollute groundwater is Cadmium, with Pi of 0.5333 and 0.400 representing dry season and wet season respectively.

2021 ◽  
Vol 5 (2) ◽  
pp. 498-510
Author(s):  
A. H. Santuraki ◽  
A. U. Babayo ◽  
Abdu Zakari ◽  
A. G. Abdulkadir

This study was carried out in ten (10) different locations within River Gongola, its Dam, and Dadinkowa Dam, Gombe State, Nigeria during the wet and dry season to study the water quality in terms of physicochemical properties to ascertain the levels of contaminants due to flooding and anthropogenic activities and the levels of heavy metals (Cr, Cd, Pb, and Ni) in the two species of fish (Clarias gariepinus and Bagrus docmak). A total of 200 water and 360 fish samples comprising two different species were collected in the month of March-June 2017 (Dry season) and July-October 2017 (Wet Season). The results of physicochemical properties obtained ranges between Temperature 29.0-30 0C and 30-32 0C, pH 5.4-7.8 and 6.0-6.9, Conductivity 93.3-161 μS/cm3 and 104.9-128 μS/cm3, Dissolved oxygen 1.2-3.98 mg/l and 0.4-3.1 mg/l, Total Suspended Solids 10-860 mg/l and 13-1180 mg/l, Total Dissolved Solids 46.5-80.5 mg/l and 54.2-76.5 mg/l, Turbidity 424.7-783.5 NTU and 11.15-442.1 NTU, Phosphate 1.82-7.23 mg/l and 0.00-0.11 mg/l, and Nitrate 2.25-8.82 mg/l and 2.68-6.81 mg/l during wet and dry season respectively. The result reveals that turbidity, PO43, DO, TSS, and TDS were above the acceptable permissible limits of WHO While the mean concentration levels of heavy metals in Clarias gariepinus and Bagrus docmak revealed that Cr was below the detectable limit while Cd ranges between 0.5-7.75 µg/g, Pb rangesbetween 3.9-35.6 µg/g during the wet and dry season. The mean concentrations of all the studied metals were above the permissible limit of WHO with a higher concentration during the dry season.


The Polycyclic aromatic hydrocarbons (PAHs) and some heavy metals were analysis in the soil samples from urban areas of Kaduna state for their concentration and distribution. Naphthalene, acenaphthylene, acenaphthene, fluorine, phenanthrene, anthracene, fluoranthene, pyrene, chrysene, benzo(a)anthracene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(a) pyrene, indeno(1,2,3-cd)perylene, benzo(ghi) perylene and dibenzo(a,h) anthracene were analyzed in three urban soils of Kaduna North, Alegbi and Kaduna South, at 0-15 cm and 16-30 cm depth in wet and dry seasons. After extraction using ultrasonication with hexane and dichloromethane and clean-up, PAHs concentration was measured using gas chromatography. The concentration of all the PAHs obtained ranged between 178.00 mg/g and 787.0 0 mg/g for wet season and 105.10 mg/g and 437.70 mg/g for dry season. The concentrations of PAHs were higher in the subsoil (15-30 cm depth) in the wet season than in the dry season while higher concentrations of all the PAHs were observed in topsoil than subsoil during the dry season. The concentration of PAHs followed the order Kaduna North > Kaduna South > Algabi during the wet season and Kaduna South > Algabi > Kaduna Nort during the dry season. The concentration values of all determined PAHs were below the target value of 1000 mg/g stipulated by Department of Petroleum Resources. The Cd, Cr, Cu and Pb levels in the soil from the study sites were higher than the corresponding control values. The degree of pollution of various metals using the graded standard of Nemero pollution index varied. The concentrations of the metals were found to be above the recommended limits given by USEPA/WHO. This could pose risks and hazards to human and the ecosystem through direct ingestion of contaminated soil


2016 ◽  
Vol 6 (1) ◽  
pp. 85
Author(s):  
Eneojo Godwin Ameh ◽  
Mofoloronsho Samuel Kolawole ◽  
Sunday Ojochogwu Idakwo ◽  
Caroline Ojone Ameh ◽  
Ebo GabrielImeokparia

Soil samples were collected randomly but uniformly distributed around Itakpe iron-ore mines in both dry and wet seasons. Surface soils were collected from 0cm to 10cm using stainless steel augers and located using Global Positioning System (GPS). Soil samples were air-dried, sieved through 500um mesh and 1.0g digested, evaporated and analysed using Atomic Absorption Spectrometer (AAS).Five (5) geo-environmental indices were used to quantitatively evaluate the degree of soil contamination due to iron ore mining. The anthropogenic factor (AF) for both seasons revealed that all heavy metals have greater than 50% AF except for Cd in the dry season. The geo accumulation index (Igeo) for both seasons showed background concentration to unpolluted for Cu and Zn while Fe, Ni, Cdand Pb recorded moderately to very highly polluted. The pollution index (Eri), showed tiny hazard level for all the heavy metals in dry season and in wet season, Cd and Ni recorded strong hazard level while tiny hazard level were observed for Cu and Pb. The ecological pollution index for the area is strong (RI=323.25). Dry and wet season enrichment factor (EF) revealed background concentration for all the heavy metals except Fe with EF> 40 (extremely high enrichment). While contamination factor (CF) was very high for Fe in both seasons, Cu and Ni recorded considerable to very high contamination in dry season. The wet season also revealed considerable contamination for Ni and Cd; moderate to considerable contamination for Cu, Zn and Pb. The sites in both seasons have experienced various degrees of deterioration but more significant in wet season. Based on these indices, the soils around Itakpe iron-ore area has suffered significant degrees of contaminations with respect to Fe, Ni, Cd and Pb.


Author(s):  
Akpe, Michael Akomaye ◽  
Ubua, Placcidus Unimuyi

The soil and edible vegetable samples were collected from Obudu Urban Area of Cross River State and were digested and analyzed for the Cd, Co, Cr, and Fe (heavy metals) concentration using Atomic Absorption Spectrometer (AAS) in the University of Calabar Laboratory. The eight vegetables considered for the study were Amaranthus spp., Corchorus olitorius, Murraya koenigii, Ocimum grattissimum, Solanum melongena, Talinum triangulare, Telferia occidentalis and Vernonia amygdalina. The results showed that the mean concentration of the metal in the soil in mgkg-1 ranged from (0.004-0.0048) and (0.005-0.046) in rainy and dry seasons respectively for Cd, (0.004-0.025) and (0.006-0.016) in rainy and dry season respectively for Cr, and (0.112-0.173) and (0.116-0.151) in rainy and dry season respectively for Fe. The concentration of Co was not detected in the soil or vegetables. The mean concentration accumulated by the vegetables and that present in the soil was in the order: Fe> Cd> Cr> Co. These results suggest that there is no significant difference between the amount of metals in the soil or that accumulated by the vegetables in rainy and dry seasons of the year. Also the amount of metals accumulated by most of the vegetables was directly proportional to the amount present in the soil where they are planted. The bioaccumulation ratios were all less than 1. These results indicate that the concentration of Cd, Co, Cr, & Fe in the soil and vegetables were still low and within the permissible limits of WHO/FAO. Thus, the consumption of the vegetables in the area may not cause any harm for now.


Author(s):  
Akpe, Michael Akomaye ◽  
Ashishie, Providence Beteluwhobel ◽  
Inezi, Faith Patrick

Aim: The aim of the study was to determine concentration of heavy metals in the soil and edible vegetables planted consumed Yala Urban Area of Cross River State, Nigeria, ascertained the level of metals contamination and the possible health risk or implication. Sampling: Forty eight (48) soil and edible vegetable samples (6 of each kind of the 8 vegetables) were collected randomly from Yala Urban Area of Cross River State. The eight vegetables considered for the study were Amaranthus spp., Corchorus olitorius, Murraya koenigii, Ocimum grattissimum, Solanum melongena, Talinum triangulare, Telferia occidentalis and Vernonia amygdalina. They were collected between January and March for dry season, and July and September for rainy season of the year.  Methodology: The samples were digested and analyzed for the Cr, Fe, Hg and Ni (heavy metals) concentration using Flame Atomic Absorption Spectrometer (AAS) in the Chemistry Laboratory, University of Calabar. Results: The results showed that the mean concentration of the metals in the soil in mgkg-1 ranged from (0.063 - 0.108) and (0.049 - 0.104) in rainy and dry seasons respectively for Cr, and (0.026 - 0.124) and (0.013 - 0.119) in rainy and dry season respectively for Fe. The mean concentration accumulated by the vegetables ranged from (0.037- 0.063) and (0.029 - 0.066) in rainy and dry season respectively for Cr and (0.012- 0.071) and (0.008- 0.086) in rainy and dry season respectively. Hg and Ni were neither detected in the soil nor in the vegetables. The trend of the metals in both the soil and vegetable was in the order: Cr > Fe> Hg> Ni. The Target Hazard Quotients were all less than 1, indicating no health risk. Conclusion: These results suggest that there is no significant difference between the amount of metals in the soil or that accumulated by the vegetables in rainy and dry seasons of the year. Also the amount of metals accumulated by most of the vegetables was directly proportional to the amount present in the soil where they are planted. These results indicate that the concentration of Cr, Fe, Hg and Ni in the soil and vegetables were still low and within the permissible limits of WHO/FAO. Thus, the consumption of the vegetables in the area may not pose any risk at the moment.


2015 ◽  
Vol 26 (2) ◽  
pp. 136-146
Author(s):  
K Fatima ◽  
MK Hossain ◽  
MA Islam

The study was carried out to assess the water quality of the Jamuna river affected by effluents discharged from the nearby Jamuna Fertilizer Company Limited and its temporal change over wet and dry seasons due to change of the physico-chemical parameters. Effluents of the factories and water samples were collected from four different selected stations during the period of June to August 2014 and January to March 2015.The results further revealed that the water samples showed a remarkable variation in physico-chemical parameters during the wet and dry season. In wet season the mean value of temperature, pH, EC, TDS, TSS, DO, BOD, ammonium, nitrite, nitrate and chloride were28.63± 3.79 °C, 8.10± 0.85, 664.41± 599.54µscm-1, 370.91± 111.38 ppm, 74.49± 25.90 ppm, 6.11 ± 1.28 ppm, 75.39 ± 140.86 ppm 296.74± 303.03 ppm, 12.31±21.38 ppm,  15.19±24.49 ppm and 15.23±8.72 ppm, respectively In the dry season the mean value of temperature, pH, EC, TDS, TSS, DO, BOD, ammonium, nitrite, nitrate and chloride were31.69 ±3.18°C, 8.44± 0.66, 786.25±551.18µscm1, 338.37± 94.70 ppm, 72.08± 58.83 ppm, 5.45 ± 0.95 ppm, 86.93 ± 159.82 ppm, 347.91± 291.60 ppm, 13.68±23.1 ppm, 18.34± 24.92 ppm and 18.3±9.32 ppm, respectively. The comparative study showed that most of the effluent and water quality parameters were higher in dry season than those of the wet season because in dry season less quantity of water remains in the river and in wet season more water remains in river that has great dilution capacity. For existence and conservation of aquatic resources, it is essential to investigate the water quality and surrounding environment of the river.Progressive Agriculture 26 (2): 136-146, 2015


2021 ◽  
Vol 11 (3) ◽  
Author(s):  
Regina Appiah-Opong ◽  
Amoako Ofori ◽  
Mark Ofosuhene ◽  
Ebenezer Ofori-Attah ◽  
Francis K. E. Nunoo ◽  
...  

AbstractThe concentration of seven heavy metals in water samples was analyzed along the southwest coast of Ghana in the wet and dry seasons using atomic absorption spectrophotometer. Some physicochemical properties of the water samples were also determined to assess the quality of the water. The ranges of metal concentration in water in the wet season were; As (1.23–7.84 µg/L), Cu (4.10–24.09 µg/L), Pb (4.08–57.98 µg/L), Se (BDL-0.38 µg/L), Zn (2.86–17.75 µg/L) and Hg (0.023–0.068 µg/L), whereas the ranges of metal concentration in the dry season were; As (2.30–5.78 µg/L), Pb (25.47–70.73 µg/L), Se (0.081–0.158 µg/L), Zn (0.79–22.80 µg/L) and Hg (0.004–0.047 µg/L). The results of physicochemical properties of water in the wet season were pH (6.83 to 7.52), EC (291.15–780.64 µS/cm), TDS (195.07–523.02 mg/L), DO (2.98–4.39 mg/L), BOD (3.33 to 6.84 mg/L), salinity (0.01 to 0.30 ppt) and temperature (27.06–30.94 °C), whereas the dry season recorded the ranges of pH (6.84–6.95), EC (516.83 to 660.67 µS/cm), TDS (307.07–442.65 mg/L), DO (1.71–3.04 mg/L), BOD (4.25–13.38 mg/L), salinity (0.22–0.28ppt) and temperature (28.46–30.44 °C). The results showed that the concentration of heavy metals in water was below the WHO standard except Pb which exceeded the limit. The mean heavy metal pollution index (HPI) were 130 and 143 for wet and dry seasons, respectively, indicating that the water HPI was above the critical limit (HPI > 100), hence unfit for drinking. All the physicochemical properties analyzed were within the WHO permissible limits except BOD.


Author(s):  
A. T. Adediji ◽  
S. O. Adebusola ◽  
J. S. Ojo

In this study, results of the variation of maximum and minimum radio horizon distance derived from the computation of surface refractivity through measurement of temperature, relative humidity and pressureacrosssevenlocations((Akure (7.15°N, 5.12°E), Lagos (6.30°N, 3.20°E), Abuja (7.10°N, 9.25°E), Jos (9.50°N, 8.50°E), Makurdi (7.30°N,8.53°E), Port-Harcourt(4.20°N,7.00°E), and Nsukka (6.90°N,7.67°E)) in Nigeria are presented. Two years (Jan., 2011–Dec., 2012) archived data as provided by Tropospheric Data Acquisition Network (TRODAN) of the Centre for Atmospheric Research Anyigba, Kogi State were utilized for the study. Results showed that the values of surface refractivity (Ns) were low during the dry season months and high during the wet season months and also there was high value of NS at the coastal areas compared with the inland areas. It was also deduced that the mean value of NS for Abuja, Akure, Jos, Lagos, Markurdi, Nsukka and Port-Harcourt is 355, 362, 303, 391, 375, 361 and 399 N-units respectively. Results showed that the Radio Horizon Distance (RDH) values were generally low during the wet season months and high during the dry season months. The variability of radio horizon distance of transmitting antennas is higher in the Northern part of Nigeria than the southern part.


2020 ◽  
Vol 4 (2) ◽  
pp. 16-21
Author(s):  
M. M. Karaye ◽  
H. A. Ibrahim

Study of Seven heavy metals namely, Zinc, Lead, Copper, Cadmium, Manganese, Chromium and Nickel was conducted in Mai-Allo pond, Gwale, Kano State in order to assess the concentration of the heavy metals in the pond. The results of the heavy metals showed that Zn has a value of 0.34±0.17 mg-l in the wet season and 0.49±0.37 mg-l in the dry season, Cu has a value of 1.42±0.14 mg-l in the wet season and 0.64±0.09 mg-l in the dry season, and Ni also has 0.12±0.02 mg-l in the wet season and 0.23±0.13 mg-l in the dry season, all these were within acceptable limits, while Pb with a value of 0.05±0.02 mg-l was within the limits during the wet season but during the dry season, the value 0.14±0.09mg-l exceeds the limits. Cd has a value of 0.06±0.01 in the wet season and 0.17±0.12 in the dry season, Cr has 0.36±0.12 in the wet season and 0.04±0.07 in the dry season, and Mn also has values of 0.46±0.12 and 0.22±0.03 in the wet and dry seasons respectively. Hence there was no significant difference (P>0.05) in the mean values of the sampling stations of the heavy metals during the wet and dry seasons. The study showed that the pond water was polluted with some heavy metals and hence measures must be taken to ensure the safety of the aquatic ecosystem, humans and the environment.


Author(s):  
Nazeefa Fatima ◽  
Munazza Khan ◽  
Muhammad Shuaib Kabeer

This study was conducted to determine the mean concentration of heavy metals such as lead (Pb), copper (Cu), zinc (Zn), chromium (Cr), manganese (Mn), nickel (Ni), selenium (Se), magnesium (Mg), and iron (Fe) in canned/packed fruits juices, collected from various stores in Lahore in a period of three months. These juices were categorized into four groups; local packed and canned and also imported packed and canned products. Every group consisted of ten samples. By using the di-acid digestion method, the collected samples were digested and analyzed under Atomic Absorption Spectrophotometer (AAS). The results indicated that the mean values of 7 out of 9 tested heavy metals including Pb, Mg, Ni, Fe, Cr, Se and Mn were above permissible limits (set by WHO) in all four understudy groups. Therefore, it was concluded that commercially available fruit juices are not all safe according to their heavy metals content for the human consumption despite their nutritive values.


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