Airborne Gold Nanoparticle Detection Using Photoluminescence Excited with a Continuous Wave Laser

We report the observation of photoluminescence emission from airborne gold, silver, and copper nanoparticles. A continuous wave 532 nm laser was employed for excitation. Photoluminescence from gold nanoparticles carried in a nitrogen gas flow was both spectrally resolved and directly imaged in situ using an intensified charge-coupled device camera. The simultaneously detected Raman signal from the nitrogen molecules enables quantitative estimation of the photoluminescence quantum yield of the gold nanoparticles. Photoluminescence from metal nanoparticles carried in a gas flow provides a potential tool for operando imaging of plasmonic metal nanoparticles in aerosol reactions.

Demonstration of Dynamics of Nanosecond Discharge in Liquid Water Using Four-Channel Time-Resolved ICCD Microscopy

The microscopic physical mechanisms of micro-discharges produced in liquid waters by nanosecond high-voltage pulses are quite complex phenomena, and relevant coherent experimentally supported theoretical descriptions are yet to be provided. In this study, by combining a long-distance microscope with a four-channel image splitter fitted with four synchronised intensified charge-coupled device detectors, we obtained and analysed sequences of microscopic discharge images acquired with sub-nanosecond temporal resolution during a single event. We tracked luminous filaments either through monochromatic images at two specific wavelengths (532 and 656 nm) or through broadband integrated UV–vis–near infrared (NIR) discharge emission. An analysis of the sequences of images capturing discharge filaments in subsequent time windows facilitated the tracking of movement of the luminous fronts during their expansion. The velocity of expansion progressively decreased from the maximum of ~2.3 × 105 m/s observed close to the anode pin until the propagation stopped due to the drop in the anode potential. We demonstrate the basic features characterising the development of the luminous discharge filaments. Our study provides an important insight into the dynamics of micro-discharges during the primary and successive reflected high-voltage pulses in de-ionised water.

Hypersonic Imaging and Emission Spectroscopy of Hydrogen and Cyanide Following Laser-Induced Optical Breakdown

This work communicates the connection of measured shadowgraphs from optically induced air breakdown with emission spectroscopy in selected gas mixtures. Laser-induced optical breakdown is generated using 850 and 170 mJ, 6 ns pulses at a wavelength of 1064 nm, the shadowgraphs are recorded using time-delayed 5 ns pulses at a wavelength of 532 nm and a digital camera, and emission spectra are recorded for typically a dozen of discrete time-delays from optical breakdown by employing an intensified charge-coupled device. The symmetry of the breakdown event can be viewed as close-to spherical symmetry for time-delays of several 100 ns. Spectroscopic analysis explores well-above hypersonic expansion dynamics using primarily the diatomic molecule cyanide and atomic hydrogen emission spectroscopy. Analysis of the air breakdown and selected gas breakdown events permits the use of Abel inversion for inference of the expanding species distribution. Typically, species are prevalent at higher density near the hypersonically expanding shockwave, measured by tracing cyanide and a specific carbon atomic line. Overall, recorded air breakdown shadowgraphs are indicative of laser-plasma expansion in selected gas mixtures, and optical spectroscopy delivers analytical insight into plasma expansion phenomena.

Detecting Minerals and Organics Relevant to Planetary Exploration Using a Compact Portable Remote Raman System at 122 Meters

Raman spectroscopy is a technique that can detect and characterize a range of molecular compounds such as water, water ice, water-bearing minerals, and organics of particular interest to planetary science. The detection and characterization of these molecular compounds, which are indications of habitability on planetary bodies, have become an important goal for planetary exploration missions spanning the solar system. Using a compact portable remote Raman system consisting of a 532 nm neodymium-doped yttrium aluminum garnet- (Nd:YAG-) pulsed laser, a 3-in. (7.62 cm) diameter mirror lens and a compact spectrograph with a miniature intensified charge coupled device (mini-ICCD), we were able to detect water (H2O), water ice (H2O-ice), CO2-ice, hydrous minerals, organics, nitrates, and an amino acid from a remote distance of 122 m in natural lighting conditions. To the best of our knowledge, this is the longest remote Raman detection using a compact system. The development of this uniquely compact portable remote Raman system is applicable to a range of solar system exploration missions including stationary landers for ocean worlds and lunar exploration, as they provide unambiguous detection of compounds indicative of life as well as resources necessary for further human exploration.

Hypersonic Imaging and Emission Spectroscopy of Hydrogen and Cyanide Following Laser-Induced Optical Breakdown

This work communicates the connection of measured shadowgraphs from optically induced air breakdown with emission spectroscopy in selected gas mixtures. Laser-induced optical breakdown is generated using 850 mJ and 170 mJ, 6-ns pulses at a wavelength of 1064 nm, the shadowgraphs are recorded using time-delayed 5-ns pulses at a wavelength of 532 nm and a digital camera, and emission spectra are recorded for typically a dozen of discrete time-delays from optical breakdown by employing an intensified charge-coupled device. The symmetry of the breakdown event can be viewed as close-to spherical symmetry for time-delays of several 100 ns. Spectroscopic analysis explores well-above hypersonic expansion dynamics using primarily the diatomic molecule cyanide and atomic hydrogen emission spectroscopy. Analysis of the air breakdown and selected gas breakdown events permits the use of Abel inversion for inference of the expanding species distribution. Typically, species are prevalent at higher density near the hypersonically expanding shockwave, measured by tracing cyanide and a specific carbon atomic line. Overall, recorded air breakdown shadowgraphs are indicative of laser-plasma expansion in selected gas mixtures, and optical spectroscopy delivers analytical insight into plasma expansion phenomena.

High Resolution 3-D Imaging of Mesospheric Sodium (Na) Layer Utilizing a Novel Multilayer ICCD Imager and a Na Lidar

Equipped with a 1-meter Cassegrain telescope with 6.2 meter focal length and an electronically gated Intensified Charge-Coupled Device (ICCD), a multilayer Na imager is designed and developed at Wuhan in China. This novel instrument has successfully achieved the first preliminary 3-D image of the mesospheric Sodium (Na) layer when running alongside a Na lidar. The vertical Na layer profile is measured by the lidar, while the horizontal structure of the layer at different altitudes is measured by the ICCD imaging with a horizontal resolution of ~3.7 urad. In this experiment, controlled by the delay and width of the ICCD gating signal, the images of the layer are taken with three-second temporal resolution for every 5 km. The results show highly variable structures in both the vertical and horizontal directions within the Na layer. Horizontal images of the Na layer at different altitudes near both the permanent layer (80–100 km) and a sporadic Na layer at 117.5 km are obtained simultaneously for the first time. The Na number density profiles measured by the lidar and those derived from this imaging technique show excellent agreement, demonstrating the success of this observational technique and the first 3-D imaging of the mesospheric Na layer.

Ignition of A Plasma Discharge Inside An Electrodeless Chamber: Methods and Characteristics

In this paper the generation and diagnostics of a reduced pressure (300 mTorr to 3 Torr) plasma generated inside an electrodeless containment vessel/chamber are presented. The plasma is ignited by a guided ionization wave emitted by a low temperature pulsed plasma jet. The diagnostics techniques include Intensified Charge Coupled Device (ICCD) imaging, emission spectroscopy, and Langmuir probe. The reduced-pressure discharge parameters measured are the magnitude of the electric field, the plasma electron number density and temperature, and discharge expansion speed.

Experimental Investigation on the Influence of Target Physical Properties on an Impinging Plasma Jet

The present work aims to investigate the interaction between a plasma jet and targets with different physical properties. Electrical, morphological and fluid-dynamic characterizations were performed on a plasma jet impinging on metal, dielectric and liquid substrates by means of Intensified Charge-Coupled Device (ICCD) and high-speed Schlieren imaging techniques. The results highlight how the light emission of the discharge, its time behavior and morphology, and the plasma-induced turbulence in the flow are affected by the nature of the target. Surprisingly, the liquid target induces the formation of turbulent fronts in the gas flow similar to the metal target, although the dissipated power in the former case is lower than in the latter. On the other hand, the propagation velocity of the turbulent front is independent of the target nature and it is affected only by the working gas flow rate.

Temporally and Spatially Resolved Emission Spectroscopy of Hydrogen, Cyanide and Carbon in Laser-Induced Plasma

In this study, we examine the atomic and molecular signatures in laser-induced plasma. Abel inversions of measured line-of-sight data reveal insight into the radial plasma distribution. Laser-plasma is generated with 6 ns, Q-switched Nd:YAG radiation with energies in the range of 100 to 800 mJ. Temporally- and spatially-resolved emission spectroscopy investigates expansion dynamics. Specific interests include atomic hydrogen (H) and cyanide (CN). Atomic hydrogen spectra indicate axisymmetric shell structures and isentropic expansion of the plasma kernel. The recombination radiation of CN emanates within the first 100 nanoseconds for laser-induced breakdown in a 1:1 mole ratio CO2:N2 gas mixture. CN excitation temperatures are determined from fitting recorded and computed spectra. Chemical equilibrium mole fractions of CN are computed for air and the CO2:N2 gas mixture. Measurements utilize a 0.64-m Czerny–Turner type spectrometer and an intensified charge-coupled device.