CTAB Reverse Micelles as Catalysts for the Oxidation of Ascorbic Acid by K3[Fe(CN)6]

The oxidation of ascorbic acid by K3[Fe(CN)6] was studied in reverse micellar systems composed of CTAB (Cetyltrimethylammonium bromide), and it was found the observed first order (k1(aq) = 5.2×10−5 s−1, k1(rev) = 61.4×10−4 s−1) rate constant in reverse micellar medium is around forty times higher compared to aqueous medium under identical conditions. The rate enhancement (k2(aq) = 0.9×10−5 mole−1.dm3.sec−1, k2(rev) = 1.75×10−3 mole−1.dm3.sec−1) is attributed to the large concentration effect and lower dielectric constant in the reverse micelles. The rate of the reaction increases with increase in W = {[H2O]/[surfactant]} which is explained in terms of ionic strength of the water pool. The effect of surfactant concentration on rate was explained on the basis of Berezin pseudo phase model. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Sacred Water Pools of Hindu Sacredscapes in North India

The basic metaphysical frame of life in ancient India, that of sacred water (paviṭra jala) and the notion that “Water itself is life” (jala hī jivan hai), can be illustrated with case studies of two cities. Settled continuously since 1000 BCE, the cities of Varanasi and Ayodhya have been eulogized as the salvific holy-heritage cities in India known for their ritualscapes associated with sacred waters and pools. According to the ancient treatises and tales, there were fifty-four sacred tanks (kunds) and wells (kūpas) in each of these cities, and they became important sites for purification rituals, pilgrimage, healing and festive celebration by devout Hindus. After providing descriptions of the sacred water pools, this essay in part explores traditions associated with a water-pool sacred to the Sun god in both the cities. More broadly, using ancient texts, present participatory surveys, and ethnological narration, the essay considers the long-lived sacrality of water pools in these holy cities and current development strategies involving them.

COVID-19 Restrictions in a Nature Reserve Reveal the Costs of Human Presence for the Threatened Nubian Ibex (Capra nubiana)

The increasing pressure of ecotourism on wildlife in their natural habitats leads many wild animals to alter their behaviors. The restrictions issued in many places due to COVID-19 provide a rare opportunity to examine wildlife behavior in nature reserves with reduced human presence, and to reveal the impact of human visitation on the behaviors and fitness of local wildlife species. In 2019 and 2020 we placed trail cameras next to two natural springs in the Israeli Negev Desert, Ein-Avdat and Ein-Shaviv, located 9 km apart. Both sites serve as the main water source for local Nubian ibex (Capra nubiana) populations, but Ein-Avdat is situated within a popular national park into which visitors’ entrance was restricted due to COVID-19 regulations in 2020, while Ein-Shaviv is more remote and thus attracts only few visitors regardless of COVID-19 regulations. Our study revealed that during 2020, ibex in Ein-Avdat arrived to drink earlier in the day and the population’s Female:Kids ratio more than doubled. These changes were not observed in Ein-Shaviv. We found that the daily number of visitors in Ein-Avdat affected the arrival time of ibex to the water pool. We conclude that the reduced number of visitors to Ein-Avdat in 2020 compared to 2019 may have allowed ibex to arrive in preferred hours, and may have contributed to the increased kid-to-females ratio. Our study shows that behavioral adaptions to human visitation in nature reserves might carry a high fitness cost.

Modelling of water jet impact on molten metal

Splashes of high-temperature melt spreading over a water pool bottom can be a reason for the formation of a zone where melt, water and steam are mixed, providing conditions for powerful steam explosions. The paper considers the formation of melt splashes arising from the impact of a water jet on the surface of the melt. Numerical simulations are performed in 3D formulation, using the VOF method and an improved phase change model. The evolution of melt surface following the water jet impact is demonstrated, including the formation of a cavern, a primary melt splash known as the crown, as well as a secondary splash following the collapse of the cavern, known as the cumulative jet. Parametric study for the melt splash height dependence on the water jet geometry and velocity is carried out. The results of numerical analysis are discussed from the point of view of the similarity with respect to the momentum and kinetic energy of water jet. The significance of the results for the steam explosion problem is discussed.

Height of Water Pool in the Roll Nip of Secondary Cooling Zone in Continuous Slab Caster: Application of Open Channel Hydraulics

In continuous casting of steel, the strand is cooled in the upper part of the secondary cooling zone with water sprayed by nozzles towards the strand surface. The water accumulates in the nip of the lower roll of a roll pair, forming a water pool which then drains off towards the ends of the roll. In the present work, open channel hydraulics was applied for computation of the water pool height in the nip between roll and strand in continuous slab casting. The differential equation describing the change of pool height for the spatially varied flow with increasing discharge was solved with the Runge–Kutta technique using as boundary condition the pool height at the end of the nip. The effects of the Manning friction factor n and the energy coefficient α were determined in sets of computation. It was shown that the hydraulic theory could predict water profiles in the nip of continuous casting rolls to a good approximation.

Triple Oxygen Isotope Measurements (Δ'17O) of Body Water Reflect Water Intake, Metabolism, and δ18O of Ingested Water in Passerines

Understanding physiological traits and ecological conditions that influence a species reliance on metabolic water is critical to creating accurate physiological models that can assess their ability to adapt to environmental perturbations (e.g., drought) that impact water availability. However, relatively few studies have examined variation in the sources of water animals use to maintain water balance, and even fewer have focused on the role of metabolic water. A key reason is methodological limitations. Here, we applied a new method that measures the triple oxygen isotopic composition of a single blood sample to estimate the contribution of metabolic water to the body water pool of three passerine species. This approach relies on Δ'17O, defined as the residual from the tight linear correlation that naturally exists between δ17O and δ18O values. Importantly, Δ'17O is relatively insensitive to key fractionation processes, such as Rayleigh distillation in the water cycle that have hindered previous isotope-based assessments of animal water balance. We evaluated the effects of changes in metabolic rate and water intake on Δ'17O values of captive rufous-collared sparrows (Zonotrichia capensis) and two invertivorous passerine species in the genus Cinclodes from the field. As predicted, colder acclimation temperatures induced increases in metabolic rate, decreases in water intake, and increases in the contribution of metabolic water to the body water pool of Z. capensis, causing a consistent change in Δ'17O. Measurement of Δ'17O also provides an estimate of the δ18O composition of ingested pre-formed (drinking/food) water. Estimated δ18O values of drinking/food water for captive Z. capensis were ~ −11‰, which is consistent with that of tap water in Santiago, Chile. In contrast, δ18O values of drinking/food water ingested by wild-caught Cinclodes were similar to that of seawater, which is consistent with their reliance on marine resources. Our results confirm the utility of this method for quantifying the relative contribution of metabolic versus pre-formed drinking/food water to the body water pool in birds.