Optimizing Location of CO2 Recovery Units

In line with ADNOC Sustainability policy, reduction of GHG emissions, AGP has initiated projects for recovery of CO2 from existing plants. The extracted CO2 is planned to be used for Enhanced Oil Recovery. The current paper highlights method used for evaluation of various location and technology options for implementation of the new CO2 recovery units, considering existing plants flow schemes along with their interfaces and associated challenges. Key Performance Indicators (KPIs) were identified based on Inherent Safety, Economics, Technology Maturity, Product Quality, Operability / Flexibility, Constructability. Identified options were further developed and subsequently evaluated based on preliminary economic analysis and available technical information. Accordingly, weighted scores of the KPIs developed for option selection. Major criteria used for ranking were unit cost of CO2 product, adherence to required H2S and COS specifications, technology maturity and deployment in industry.For one location, the options considered included installation of new Acid Gas Removal Unit (AGRU) upstream of existing AGRU, revamp of existing Acid Gas Enrichment Unit (AGEU), new AGEU, and direct feed of Acid gas to new CO2 recovery unit to supplement falling upstream reservoir profile.For another location, the options included new CO2 recovery plant upstream of existing Sulphur Recovery Unit (SRU) or downstream of existing Tail Gas Treatment Unit (TGTU), compression of TGTU gases upstream of proposed CO2 recovery unit, installation of new unit downstream of existing incinerators, combination of CO2 recovery units of both plants, were also assessed.In addition, new CO2 Dehydration and Compression units considered to meet CO2 product specifications and B/L requirements. Based on project requirements, physical methods of CO2 removal like membranes and molecular sieves deemed unsuitable. Further to discussions with various licensors, emphasis remained on chemical and physical solvent technologies. Based on assessment, solvent swap for AGEU (upstream of existing SRUs) with reduced lean solvent temperature at one location, solvent swap in TGTU followed by a new polishing unit at another location combined with common high pressure compression facility, was selected for engineering development.

Simulation and Performance Comparison for CO2 Capture by Aqueous Solvents of N-(2-Hydroxyethyl) Piperazine and Another Five Single Amines

N-(2-Hydroxyethyl) piperazine (HEPZ) has a chemical structure similar to PZ and has less volatility. It is not easy to volatilize in a continuous operation device. It is studied to replace PZ as a promotor to increase the CO2 capture rate. This paper researches the lowest energy consumption and absorbent loss of HEPZ/H2O in the absorption-regeneration process, and compares it with another five amines, including PZ, MEA, 1-MPZ, AMP and DMEA. Based on the thermodynamic model, this work establishes a process simulation based on the equilibrium stage, assuming that all stages of the absorption and desorption towers reach thermodynamic equilibrium and CO2 recovery in the absorption tower is 90%. By optimizing the process parameters, the lowest thermodynamic energy consumption and absorbent loss of process operation are obtained. Our results show that HEPZ as a promotor to replace PZ and MEA has significant economic value. The lowest reboiler energy consumption of HEPZ with the optimal process parameters is 3.018 GJ/tCO2, which is about 35.2% lower than that of PZ and about 11.6% lower than that of MEA, and HEPZ has the lowest solvent loss. The cyclic capacity is 64.7% higher than PZ and 21.6% lower than primary amine MEA.

Sewage Sludge Derived Materials for CO2 Adsorption

The study tried to contribute to solving two serious environmental issues: CO2 reducing and sewage sludge disposal. Thus, sewage-sludge-derived materials were obtained in order to be evaluated for CO2 adsorption capacity. Therefore, the char resulted after the sewage sludge pyrolysis was subjected to oxidation and chemical activation processes by using different quantities of alkaline hydroxide. One of the obtained materials, activated with a lower quantity of alkaline hydroxide, was also treated with acid chloride. Further, the materials were structural and texturally characterized, and material treated with acid chloride was used for CO2 adsorption tests, due to high surface area and pore volume. The handmade system coupled to a gas chromatograph allowed the adsorption efficiency evaluation using different feed gases (rich and poor in CO2) by completed purge of pipe line and on-line check. Additionally, the adsorption capacity, separation efficiency, and CO2 recovery were calculated. Taking into account the values for adsorption capacity (separation efficiency and CO2 recovery), it can be concluded that the sewage sludge derived material could be a promising solution for CO2 reduction and waste disposal.

Review of Cryogenic Carbon Capture Innovations and Their Potential Applications

Our ever-increasing interest in economic growth is leading the way to the decline of natural resources, the detriment of air quality, and is fostering climate change. One potential solution to reduce carbon dioxide emissions from industrial emitters is the exploitation of carbon capture and storage (CCS). Among the various CO2 separation technologies, cryogenic carbon capture (CCC) could emerge by offering high CO2 recovery rates and purity levels. This review covers the different CCC methods that are being developed, their benefits, and the current challenges deterring their commercialisation. It also offers an appraisal for selected feasible small- and large-scale CCC applications, including blue hydrogen production and direct air capture. This work considers their technological readiness for CCC deployment and acknowledges competing technologies and ends by providing some insights into future directions related to the R&D for CCC systems.

Negative CO2 emissions for transportation

Negative emission technologies have recently received increasing attention due to climate change and global warming. One among them is bioenergy with carbon capture and storage (BECCS), but the capture process is very energy intensive. Here, a novel pathway is introduced, based on second generation biofuels followed by carbon circulation in an indefinitely closed chain, effectively resulting in a sink. Instead of using an energy-intensive conventional CCS process, the application of an on-board solid oxide fuel cell (SOFC) running on biofuels in an electric vehicle (FCEV) could result in negative emissions by capturing a concentrated stream of CO2, which is readily stored in a second tank. A CO2 recovery system at the fuel station then takes the CO2 from the tank to be transported to storage locations or to be used for local applications such as CO2-based concrete curing and synthesis of e-fuels. Incorporating CO2 utilization technologies into the FCEVs-SOFC system can close the carbon loop, achieving carbon neutrality through feeding the CO2 in a reverse-logistic to a methanol plant. The methanol produced is also used in SOFC’s, leading to an infinite repetition of this carbon cycle till a saturation stage is reached. It is determined this pathway will reach typical Cradle-to-Grave negative emissions of 0.515 ton CO2 per vehicle, and total negative CO2 emission of 138 Mt for all passenger cars in the EU is potentially achievable. All steps comprise known technologies with medium to high TRL levels, so principally this system can readily be applied in the mid-term.