Review of the gas breakdown physics and nanomaterial-based ionization gas sensors and their applications

Ionization gas sensors are a ubiquitous tool that can monitor desired gases or detect abnormalities in real time to protect the environment of living organisms or to maintain clean and/or safe environment in industries. The sensors’ working principle is based on the fingerprinting of the breakdown voltage of one or more target gases using nanostructured materials. Fundamentally, nanomaterial-based ionization-gas sensors operate within a large framework of gas breakdown physics; signifying that an overall understanding of the gas breakdown mechanism is a crucial factor in the technological development of ionization gas sensors. Moreover, many studies have revealed that physical properties of nanomaterials play decisive roles in the gas breakdown physics and the performance of plasma-based gas sensors. Based on this insight, this review provides a comprehensive description of the foundation of both the gas breakdown physics and the nanomaterial-based ionization-gas-sensor technology, as well as introduces research trends on nanomaterial-based ionization gas sensors. The gas breakdown is reviewed, including the classical Townsend discharge theory and modified Paschen curves; and nanomaterial-based-electrodes proposed to improve the performance of ionization gas sensors are introduced. The secondary electron emission at the electrode surface is the key plasma–surface process that affects the performance of ionization gas sensors. Finally, we present our perspectives on possible future directions.

1d3v PIC/MCC simulation of dielectric barrier discharge dynamics in hydrogen sulfide

The products of hydrogen sulfide decomposition by dielectric barrier discharge are hydrogen and sulfur. This process can successfully recover hydrogen from a hazardous by product of fossil fuel extraction, and it has thus been attracting increasing attention. In this study, we computationally examined the dynamics of dielectric barrier discharge in hydrogen sulfide. The simulations were performed with a 1d3v particle-in-cell/Monte Carlo collision model in which a parallel-plate electrode geometry with dielectrics was used. Particle recombination process is represented in the model. The discharge mode was found to be initially Townsend discharge developing from the cathode to the anode, and at the peak of the current, a more stable glow discharge develops from the anode to the cathode. A higher applied voltage results in sufficient secondary electrons to trigger a second current peak, and then the current amplitude increases. As the frequency is increased, it leads to the advance of the phase and an increase in the amplitude of the current peak. A higher dielectric permittivity also makes the discharge occur earlier and more violently in the gap.

Carbon Microstructures Synthesis in Low Temperature Plasma Generated by Microdischarges

The aim of this paper is to investigate the process of growth of different carbon deposits in low-current electrical microdischarges in argon with an admixture of cyclohexane as the carbon feedstock. The method of synthesis of carbon structures is based on the decomposition of hydrocarbons in low-temperature plasma generated by an electrical discharge in gas at atmospheric pressure. The following various types of microdischarges generated at this pressure were tested for both polarities of supply voltage with regard to their applications to different carbon deposit synthesis: Townsend discharge, pre-breakdown streamers, breakdown streamers and glow discharge. In these investigations the discharge was generated between a stainless-steel needle and a plate made of a nickel alloy, by electrode distances varying between 1 and 15 mm. The effect of distance between the electrodes, discharge current and hydrocarbon concentration on the obtained carbon structures was investigated. Carbon nanowalls and carbon microfibers were obtained in these discharges.

Effective ionization coefficients for low current dc discharges in alcohol vapours at low pressure

This paper presents results for effective ionisation coefficients ($$\alpha _{\mathrm {eff}}/N$$ α eff / N , N—gas density) obtained from the breakdown voltage and emission profile measurements in low-pressure dc discharges in vapours of alcohols: methanol, ethanol, isopropanol, and n-butanol. Our results for $$\alpha _{\mathrm {eff}}/N$$ α eff / N are determined from the axial emission profiles in low-current Townsend discharge and lay in the interval of reduced electric field E/N (E—electric field, N—gas density), from 1 kTd to 8.8 kTd. We also give a comparison of our experimental results with those from the available literature. Our data cover the high E/N range of the standard operating conditions and in the region where other data are available we have a good agreement. Graphic abstract

Экспериментальные исследования таунсендовского разряда с многоострийным катодом на динамической платформе из магнитоуправляемых частиц Fe и Fe-Al

Experimental results of the Townsend discharge in the air gap and atmospheric pressure from a multi-pin cathode based on a dynamic platform of magnetically controlled Fe and Fe-Al particles presented. Dynamic platform method formation from magnetically controlled particles for cathode surface presented. The current-voltage characteristics are obtained for various configurations of the cathode design (with a flat electrode without magnetically controlled particles, with a multi-pin cathode with magnetically controlled Fe or Fe-Al particles), as well as with the presence of a heated spiral in the electrode gap. The use of a multi-pin cathode based on the dynamic platform of magnetically controlled Fe and Fe-Al particles allows to maintain the average electric field strength in the discharge gap and to increase the spark discharge current.

DC GAS BREAKDOWN AND TOWNSEND DISCHARGE IN CO2

We report the breakdown curves and current-voltage characteristics (CVC) of the Townsend mode DC discharge we have measured in carbon dioxide. We compare the breakdown curves measured with two different techniques. With the first technique we regard as breakdown voltage the maximum voltage which we can apply across the electrodes without igniting the discharge with fixed values of the inter-electrode distance and the gas pressure. With the second technique we register the CVC of the Townsend mode in the μA-mA range and then extrapolate them to zero current. We reveal that in the nA-μA range the CVCs of the Townsend mode may have a complicated behavior due to the formation of the space charge. Therefore the second technique furnishes incorrect values of the breakdown voltage.

On the breakdown modes and parameter space of ohmic tokamak start-up

Tokamak start-up is strongly dependent on the state of the initial plasma formed during plasma breakdown. We have investigated through numerical simulations the effects that the pre-filling pressure and induced electric field have on pure ohmic heating during the breakdown process. Three breakdown modes during the discharge are found, as a function of different initial parameters: no breakdown mode, successful breakdown mode and runaway mode. No breakdown mode often occurs with low electric field or high pre-filling pressure, while runaway electrons are usually easy to generate at high electric field or low pre-filling pressure (${<}1.33\times 10^{-4}$ Pa). The plasma behaviours and the physical mechanisms under the three breakdown modes are discussed. We have identified the electric field and pressure values at which the different modes occur. In particular, when the electric field is $0.3~\text{V}~\text{m}^{-1}$ (the value at which ITER operates), the pressure range for possible breakdown becomes narrow, which is consistent with Lloyd’s theoretical prediction. In addition, for $0.3~\text{V}~\text{m}^{-1}$, the optimal pre-filling pressure range obtained from our simulations is $1.33\times 10^{-3}\sim 2.66\times 10^{-3}$ Pa, in good agreement with ITER’s design. Besides, we also find that the Townsend discharge model does not appropriately describe the plasma behaviour during tokamak breakdown due to the presence of a toroidal field. Furthermore, we suggest three possible operation mechanisms for general start-up scenarios which could better control the breakdown phase.