Thermal Performance of Different Carbonaceous Nanoparticles as Additives to Thermal Paste as an Interface Material

With increased focus on miniature high power density electronic packages, there is a need for the development of new interface materials with lower thermal resistance. To this end, high conductivity thermal paste or similar thermal interface materials (TIMs), reinforced with superior thermal conductivity materials such as multi-walled carbon nanotubes (MWCNTs), graphene nanoplatelets (GNPs), graphite-derived multilayer graphene (g-MLG) offer an effective strategy to provide efficient paths for heat dissipation from heat source to heat sink. In an earlier paper, we had demonstrated that multilayer graphene derived from coal (coal-MLG) synthesized using our in-house developed one-pot process, has increased presence of phenolic groups on its surfaces, which translates into better dispersion of coal-MLG in silicone thermal paste. In this paper, we first compare the thermal conductance of a high conductivity thermal paste (k = 8.9 W/mK) using coal-MLG as an additive with that realized with other nano additives — MWCNTs, GNPs, and g-MLG. The data shows that coal-MLG as an additive outperforms all the other investigated nano additives in enhancing the thermal performance of the paste. With the coal-MLG as an additive, ∼70% increase in thermal performance was observed as compared to the base thermal paste used. This increase is about 2.5 times higher than that obtained using g-MLG as an additive. We also measured the thermal performance of coal-MLG-based TIM with its different wt.% fractions. The data confirmed our hypothesis that the optimum level of the loading fraction of the additive that can be dispersed in the matrix (paste in this case) before the onset of agglomeration is higher for the coal-MLG (3%) than for the other additives (2%). The implication is further improvement thermal performance with coal-MLG. The data shows the additional thermal enhancement to ∼2X. Finally, since coal-MLG produced by our in-house process is relatively cheaper and more environmentally friendly, we believe that these results would pave the path for enhanced thermal performance with non-silicone thermal pastes at a significantly lower cost. We also expect similar benefits for the silicone-based thermal pastes.

Study of the influence of the housing on the cooling efficiency of the piezoceramic electroacoustic Langevin-type transducer

The object of research is thermal processes in Langevin-type piezoceramic electroacoustic transducers (PET), taking into account the housing. The piezoceramic electroacoustic transducers heat up during operation. Overheating of the converter leads to negative consequences, accompanied by a change in the parameters, characteristics of the device, as well as the failure of the converter. Or limitation on the duration and mode of operation, output power, current, amplitude and speed of oscillation of the converter. The paper investigates the effect of the housing on the temperature field of a Langevin-type PET by the finite element method, using modeling in SolidWorks. The results of temperature reduction of such cooling methods are shown: – filling the housing cavity with electrical insulating liquid, gas, a mixture of thermal paste; – use of holes in the housing; – changing the shape of the rear cover to have radiator side fins, vertical radiator fins, cylindrical radiator fins; – heat-resistant layer; – use of active air cooling at three different speeds. The most efficient 53 % and a uniform temperature field were found when filling with a mixture of thermal paste, but this solution is accompanied by additional experiments and a preparatory stage with the mixture. The cooling efficiency of 47 % was provided by active cooling – blowing with air, and this method requires additional equipment. Filling with insulating liquid gave a cooling efficiency of 27 % – an optimal result that does not require expensive investments. Slow blowing of the housing or adding only holes resulted in a decrease in the maximum heating temperature from 10 to 20 %, therefore, if the PET design allows the presence of holes, then it is necessary to rationally place them. Changing the shape of the back plate, heat-absorbing element, filling the housing with gas gave an efficiency decrease in the maximum temperature by 6–8 % compared to a closed housing with air. The research results make it possible to choose the optimal option for reducing the heating temperature of the Langevin-type PET to increase its efficiency and long-term trouble-free operation.

Effect of Extrusion on the Crystalline Structure of Starch during RS5 Formation

Amylose is well known to be organized helically with six glucose per turn, allowing it to form complexes with various ligands. This interaction can be affected by the type of crystalline structure present in the starch sources. This study evaluated the effect of extrusion on the crystalline structure of starch during RS5 formation. Rice and potato starches were extruded at 100 °C and 15 rpm with 5% and 10% oleic acid (OA), then the physical, thermal, paste properties, and resistant starch content (RS) were evaluated. Potato starch extruded with 10% OA showed granules embedded in a gelatinized starch matrix. The X-ray revealed that rice (orthorhombic) and potato (hexagonal) structures remain unchanged even after extrusion. Differential scanning calorimetry (DSC) evidenced the formation of type IIa amylose-lipid complexes in OA treatments, where potato extruded with 10% OA had the highest enthalpy (0.9 J/g). Moreover, the extruded potato showed the highest pasting temperature (87.19 °C), supporting the complex formation. The RS was reduced from 15.8 (isolated) to 4.14 mg/100 mg (extruded 10% OA) in rice. For potato, RS decreased from 17 to 13 mg/100 mg (isolated and extruded 10% OA). Overall, these findings suggest a tendency in potato starch (ortho-rhombic) to interact with OA during the extrusion process, promoting a crystalline lamellae growth when extruded with 10% OA; therefore, changing their properties.

A general approach to composites containing nonmetallic fillers and liquid gallium

We report a versatile method to make liquid metal composites by vigorously mixing gallium (Ga) with non-metallic particles of graphene oxide (G-O), graphite, diamond, and silicon carbide that display either paste or putty-like behavior depending on the volume fraction. Unlike Ga, the putty-like mixtures can be kneaded and rolled on any surface without leaving residue. By changing temperature, these materials can be stiffened, softened, and, for the G-O–containing composite, even made porous. The gallium putty (GalP) containing reduced G-O (rG-O) has excellent electromagnetic interference shielding effectiveness. GalP with diamond filler has excellent thermal conductivity and heat transfer superior to a commercial liquid metal–based thermal paste. Composites can also be formed from eutectic alloys of Ga including Ga-In (EGaIn), Ga-Sn (EGaSn), and Ga-In-Sn (EGaInSn or Galinstan). The versatility of our approach allows a variety of fillers to be incorporated in liquid metals, potentially allowing filler-specific “fit for purpose” materials.

A Meta-study on the Thermal Properties of Carbon Nanotubes in Thermal Interface Materials

Computer Integrated Circuit (IC) microprocessors are becoming more powerful and densely packed while cooling mechanisms are seeing an equivalent improvement to compensate. A significant limit to cooling performance is thermal transfer between die and heatsink. In this meta study we evaluate carbon nanotube (CNT) thermal interface materials (TIMs) in order to determine how to maximise thermal transfer efficiency. We gathered information from over 15 articles focused on the thermodynamic parameters of CNT TIMs from databases such as Scopus, IEEE Xplore and ScienceDirect. Articles were filtered by key words including ‘carbon nanotubes’ and ‘thermal interface materials’ to identify scientific articles relevant to our research on TIMs. From our meta study we have found that enhancing CNTs will provide the best improvement in TIMs. The parameters analysed to determine TIM performance included thermal resistance, thermal conductivity and the effect of CNT concentration on computer operation time. Through our investigation we understood that increasing the concentration of CNT from 0 to 2 wt % increases the operation time from 75 seconds at 66°C to 200s at 63°C as well as increasing the thermal conductivity by 1.82 times for the AS5 thermal paste with 2 wt % CNT. Furthermore, CNT TIM pastes with less thickness have a lower thermal resistance of 0.4 K/W. However not all these parameters have been tested with computer chips. This means that in order to increase current heat transfer efficiency limit, we must integrate these parameters into experimental models. Keywords: Thermal Interface Material; Thermal Paste; Carbon Nanotubes; Thermal Transfer Efficiency; Integrated Circuit; Heat Sink; Heat Dissipation.

Carbon-Nanotube Based Thermoelectrical Paste for Enhancing Solar Cell Effciency

A super-passive cooling technique based on a thermal paste is proposed for PV efficiency enhancement in elevated temperature conditions. A mixture between carbon nanotubes and graphene having a promising Seebeck coefficient is chosen. An overall enhancement in efficiency by around 58% was reached while thermoelectrically supplying hundreds of micro-Watt per PV Watt.

A Three-Dimensional Comprehensive Numerical Investigation of Different Operating Parameters on the Performance of a Photovoltaic Thermal System With Pancake Collector

Performance of photovoltaic (PV) module decreases significantly with increasing cell temperature due to its overheating. Photovoltaic thermal (PVT) is an optimized technology that facilitates effective removal and utilization of this excess heat leading to enhanced electrical performance. In this article, a 3D numerical model has been developed and analyzed to investigate the PVT performance with a new pancake-shaped flow channel design. This flow channel is attached directly to the backside of PV module by using thermal paste. The governing equations are solved numerically by using Galerkin's weighted residual finite-element method (FEM), which has been developed using COMSOL Multiphysics® software. The numerical results show that the cell temperature reduces on an average 42 °C, and the electrical efficiency and output power increase by 2% and 20 W, respectively, for both aluminum and copper channels with an increase in inlet velocity from 0.0009 to 0.05 m/s. On the other hand, overall efficiency of the PVT system drops about 13% in both cases as the inlet temperature increases from 20 °C to 40 °C. Cell temperature is found to increase approximately by 5.4 °C and 9.2 °C for every 100 W/m2 increase in irradiation level of the PV module with and without cooling system, respectively. Regarding flow channel material, it has been observed that use of either copper or aluminum produces almost similar performance of the PVT module.