Сканирующая туннельная микроскопия в халькогенидных термоэлектриках (Bi, Sb)-=SUB=-2-=/SUB=-(Te, Se, S)-=SUB=-3-=/SUB=-

The morphology studies of the interlayer surface (0001) were carried out by the method of scanning tunneling microscopy in the n–Bi1.6Sb0.4Te2.94Se0.06, n- Bi1.8Sb0.2Te2.82Se0.09S0.09, p-Bi0.8Sb1.2Te2.91Se0.09 and p-Bi0.7Sb1.3Te2.91Se0.09 solid solutions. On the surface (0001), impurity and native defects were found (vacancies of tellurium, antisite defects, adatoms), formed in the compositions due to substitutions of atoms in the Bi2Te3 sublattices. The average values of HM and the standard deviations of HS in height in the distribution of atoms on the surface are determined depending on the composition of the solid solution. The effect of detected defects on the thermoelectric properties of solid solutions has been established.

"Non-stoichiometry and point native defects in non-oxide non-linear optical large single crystals: advantages and problems"

Advances and limitations in the field of growing large, a high optical quality single crystals of AgGaS2 (AGS), AgGaGeS4 (AGGS), ZnGeP2 (ZGP), LiInS2 (LIS), LiGaS2 (LGS), LiInSe2 (LISe), LiGaSe2 (LGSe)...

Defects and impurities in colloidal Ga2O3 nanocrystals: new opportunities for photonics and lighting

Defects, both native and extrinsic, critically determine functional properties of metal oxides. Gallium oxide has recently gained significant attention for its promise in microelectronics, owing to the unique combination of conductivity and high breakdown voltage, and solid-state lighting, owing to the strong photoluminescence in the visible spectral region. These properties are associated with the presence of native defects that can form both donor and acceptor states in Ga2O3. Recently, Ga2O3 nanocrystal synthesis in solution and optical glasses has been developed, allowing for a range of new applications in photonics, lighting, and photocatalysis. This review focuses on the structure and properties of Ga2O3 nanocrystals with a particular emphasis on the electronic structure and interaction of defects in reduced dimensions and their role in the observed photoluminescence properties. In addition to native defects, the effect of selected external impurities, including lanthanide and aliovalent dopants, and alloying on the emission properties of Ga2O3 nanocrystals are also discussed.

Enhancement of the near-band-edge electroluminescence from the active ZnO layer in the ZnO/GaN-based light emitting diodes using AlN-ZnO/ZnO/AlN-ZnO double heterojunction structure

In this work, an AlN-ZnO/ZnO/AlN-ZnO double heterojunction (DH) structure prepared using the cosputtering technology was deposited onto the p-type GaN epitaxial layer. The indiffusion of the oxygen atoms to the p-GaN epilayer was obstructed as the cosputtered AlN-ZnO film inset between n-ZnO/p-GaN interface. The near-ultraviolet (UV) emission from this ZnO/GaN-based light emitting diode (LED) was greatly improved as compared to an n-type ZnO film directly deposited onto the p-GaN epilayer. Meanwhile, the native defects in the n-ZnO layer associated with the green luminescence was less likely to form while it was sandwiched by the cosputtered AlN-ZnO film. As the thickness of the active n-ZnO layer in the DH structure reached 10 nm, the near-band-edge (NBE) emission became the predominated luminescence over the resulting LED spectrum.

Collision-Free Motion Planning of a Six-Link Manipulator Used in a Citrus Picking Robot

This paper presents the results of a motion planning algorithm that has been used in an intelligent citrus-picking robot consisting of a six-link manipulator. The real-time performance of a motion planning algorithm is urgently required by the picking robot. Within the artificial potential field (APF) method, the motion planning of the picking manipulator was basically solved. However, the real-time requirement of the picking robot had not been totally satisfied by APF because of some native defects, such as the large number of calculations used to map forces into torques by the Jacobian matrix, local minimum trap, and target not reachable problem, which greatly reduce motion planning efficiency and real-time performance of citrus-picking robots. To circumvent those problems, this paper proposed some novel methods that improved the mathematical models of APF and directly calculates the attractive torques in the joint space. By using the latter approach, the calculation time and the total joint error were separately reduced by 54.89% and 45.41% compared with APF. Finally, the novel algorithm is presented and demonstrated with some illustrative examples of the citrus picking robot, both offline during the design phase as well as online during a realistic picking test.

Doping Limitation Due to Self-compensation by Native Defects in In-doped Rocksalt CdxZn1-xO

CdO-ZnO alloys (CdxZn1-xO) exhibit a transformation from the wurtzite (WZ) to the rocksalt (RS) phase at a CdO composition of ~70% with a drastic change in the band gap and electrical properties. RS-CdxZn1-xO alloys (x>0.7) are particularly interesting for transparent conductor applications due to their wide band gap and high electron mobility. In this work, we synthesized RS-CdxZn1-xO alloys doped with different concentrations of In dopants and evaluated their electrical and optical properties. Experimental results are analyzed in terms of the amphoteric native defect model and compared directly to defect formation energies obtained by hybrid density functional theory (DFT) calculations. A saturation in electron concentration of ~7x1020cm-3 accompanied by a rapid drop in electron mobility is observed for the RS-CdxZn1-xO films with 0.7≤x<1 when the In dopant concentration [In] is larger than 3%. Hybrid DFT calculations confirm that the formation energy of metal vacancy acceptor defects is significantly lower in RS-CdxZn1-xO than in CdO, and hence limits the free carrier concentration. Mobility calculations reveal that due to the strong compensation by native defects, RS-CdxZn1-xO alloys exhibit a compensation ratio of >0.7 for films with x<0.8. As a consequence of the compensation by native defects, in heavily doped RS-CdxZn1-xO carrier-induced band filling effect is limited. Furthermore, the much lower mobility of the RS-CdxZn1-xO alloys also results in a higher resistivity and reduced transmittance in the near infra-red region (λ>1100 nm), making the material not suitable as transparent conductors for full spectrum photovoltaics.