The influence of carbon morphologies and concentrations on the rheology and electrical performance of screen-printed carbon pastes

Screen-printing inks containing various morphologies of carbon are used in the production of a variety of printed electronics applications. Particle morphology influences the rheology of the ink which will affect the deposition and therefore the electrical performance of a printed component. To assess the effect of both carbon morphology and concentration on print topography and conductivity, screen printable carbon inks with differing loading concentrations of graphite, carbon black and graphite nanoplatelets (GNPs) were formulated, printed and characterised, with rheological and novel print visualisation techniques used to elucidate the mechanisms responsible. Carbon morphology had significant effects on the packing of particles. The smaller carbon black particles had more interparticle interactions leading to better conductivities, but also higher ink viscosities and elasticities than the other morphologies. Increases in carbon concentration led to increases in film thickness and roughness for all morphologies. However, beyond a critical point further increases in carbon concentration led to agglomerations of particles, mesh marking and increases in surface roughness, preventing further improvements in the print conductivity. The optimal loading concentrations were identifiable using a custom-made screen-printing apparatus used with high speed imaging for all morphologies. Notable increases in filamentation during ink separation were found to occur with further increases in carbon concentration beyond the optimum. As this point could not be identified using shear rheology alone, this method combined with shear rheology could be used to optimise the carbon concentration of screen-printing inks, preventing the use of excess material which has no benefit on print quality and conductivity.

Characterization of Two Historical Postage Stamps Made from Cotton Fibers and Their Restoration Trials Based on the Experimental Studies

Ancient stamps are suffering from the destructive effects of different kinds of inks that were prepared from different ingredients. Two Egyptian historical postage stamps printed in blue and red printing inks were evaluated and examined for their composition using a light microscope, SEM-EDS, FTIR, and Raman spectroscopic analyses. Mechanical, chemical, and deacidification treatments were done for the two stamps. Model stamps were made from the cotton pulp in the book house to simulate historical stamp paper with an average thickness of 11 microns. The unprinted and printed paper samples with printing inks that aged and unaged were treated with 0.7% Klucel G, 0.2% TiO2 NP, or a mixture of 0.7% Klucel G + 0.2% TiO2 NP, and the color change was measured and compared with the blank samples. The two stamps are suffering from high pH, where the margin color of the stamps changed to yellow-brown with weakness of the stamp paper. By SEM examination, stamps have suffered from fibers’ weakness and dryness resulting from the self-oxidation reactions. EDS elemental composition of the red stamp showed the presence of C, O, Na, Al, Si, Mg, S, Ca, Ba, and Fe, while in the blue stamp, it was C, O, Na, Al, Si, P, S, Cl, and Ca. Raman spectrometer wavelengths turn out that the blueprinting ink of the stamp was characterized with spectra of ultramarine blue (lazurite), while hematite was characterized by the red stamp. FTIR analysis for the printing inks identified that gum Arabic sample and linseed oil were the binding and color medium, respectively. From the model trials, it was observed that the treatment of a mixture of Klucel G and TiO2 NP had the best properties for the consolidation of stamps. The two historical stamps were documented through different spectroscopic analyses, and from the restoration trials, it was observed that the mixture of 7% Klucel G + 0.2% TiO2 NP appeared to be a new and effective method for recovering the historical postage stamps.

Current Advances in Microbial Production of Acetoin and 2,3-Butanediol by Bacillus spp.

The growing need for industrial production of bio-based acetoin and 2,3-butanediol (2,3-BD) is due to both environmental concerns, and their widespread use in the food, pharmaceutical, and chemical industries. Acetoin is a common spice added to many foods, but also a valuable reagent in many chemical syntheses. Similarly, 2,3-BD is an indispensable chemical on the platform in the production of synthetic rubber, printing inks, perfumes, antifreeze, and fuel additives. This state-of-the-art review focuses on representatives of the genus Bacillus as prospective producers of acetoin and 2,3-BD. They have the following important advantages: non-pathogenic nature, unpretentiousness to growing conditions, and the ability to utilize a huge number of substrates (glucose, sucrose, starch, cellulose, and inulin hydrolysates), sugars from the composition of lignocellulose (cellobiose, mannose, galactose, xylose, and arabinose), as well as waste glycerol. In addition, these strains can be improved by genetic engineering, and are amenable to process optimization. Bacillus spp. are among the best acetoin producers. They also synthesize 2,3-BD in titer and yield comparable to those of the pathogenic producers. However, Bacillus spp. show relatively lower productivity, which can be increased in the course of challenging future research.

Properties and Colorimetric Performance of Screen-Printed Thermochromic/UV-Visible Fluorescent Hybrid Ink Systems

In the present research, properties and performance of special effect printing inks were observed with the aim of obtaining a printed product with dual functional properties. Thermochromic liquid crystal-based printing ink (TLC) and UV-visible (daylight invisible) fluorescent inks (UVF), pure and as hybrid ink systems, were printed using a screen-printing technique on two types of uncoated paper substrates. Characterization of the paper substrates was performed, as well as detailed analysis of printed layers. Thickness, surface roughness, surface free energy, and adhesion parameters of printed layers were analysed. Spectral reflectance of pure UVF and TLC printing inks, as well as the spectral reflectance of the proposed hybrid ink systems were measured. The thermochromic effect of the TLC ink and hybrid systems was analysed. Microscopy was used to display the visual colour play effect and the effect of the fluorescence. Results of the measurements showed high compatibility of used materials in the proposed hybrid ink systems. Since the effect of luminescence and the colour play effect in the hybrid systems were preserved, it can be concluded that TLC/UVF hybrid ink systems can find their application in the development of functional packaging and in all other applications with special requirements for temperature monitoring and hidden information for different products.

An investigation of the tensile characteristics of printed handsheets

Purpose The purpose of this paper is to investigate the influences of fibre lengths and a given range of paper grammages on the fundamental properties of unprinted and printed papers by using mineral oil-based offset printing inks and also evaluate these results in terms of printing and tensile characteristics. Design/methodology/approach A design research approach has been based on the production of various laboratory handmade papers and their printing process with mineral oil-based offset printing inks. The analysis of mechanical and structural tests results of the unprinted and the printed papers have been evaluated. Findings This study is confirmed that the mineral oil-based offset printing inks can be easily applied to the surface of papers having different grammages and pulp contents. An increase was observed in the tensile index values of the papers with the printing process, and these increases were more evident (about 80%) particularly in low grammage papers having high short fibre content. Originality/value The originality of this work is based on understanding and comparing the effects of grammage and the effect of pulp contents (having long and short fibre) on tensile characteristics of printed and unprinted handsheets.

Effect of Plasma Surface Modification on Print Quality of Biodegradable PLA Films

PLA films, as non-absorbent materials, require modification of the surface before the printing process in order to improve the wettability of the substrate and to obtain proper ink adhesion to the substrate. In this paper, the surfaces of two kinds of PLA films were modified using plasma activation with parameters enabling high surface free energy (SFE) values, and then the films were printed on using different kinds of flexographic inks. Two gases, oxygen and argon, were used for activation, as these make it possible to obtain good hydrophilicity and high SFE values while having different effects on the roughness, or the degree of surface etching. Plasma-activated films were subsequently subjected to the measurements of: contact angle with water, diiodomethane and three printing inks, roughness, weight change, strength properties, color and gloss change, and SFE was determined. Unmodified and activated films were flexographically printed in laboratory conditions and then the quality of obtained prints was analyzed. The results showed a strong effect of activation with both oxygen and argon plasma on the SFE value of the films and the contact angles of water and inks, with the gas used for plasma activation and the type of film significantly influencing the thickness of the fused ink layer and the resultant color. Moreover, plasma activation had a especially favorable and significant effect on the quality of prints made with water-based inks, while it had little effect when printing with solvent-based inks.