Selection of Nanostructured Zirconium Dioxide Crystals under Dry Friction against Molybdenum

The article considers the issues of contact interaction of nanostructured zirconium dioxide crystals with molybdenum coating on titanium-based alloy ВТ9. The following statement is substantiated: the best mechanical properties of crystals correspond to the total amount of 2.8% additives of stabilizing and doping rare earths elements. Antifriction properties of crystals under dry friction against molybdenum are investigated. Tribological testing was performed on a reciprocating friction gauge simulating the operation of a plunger in a cylinder. The high scoring resistance of the friction couple under study was experimentally proved; the friction coefficient did not exceed 0.07. On the basis of the study performed, the friction couple is defined as promising for increasing the lifetime and reliability of friction units for hydraulic equipment and fuel pumps.

Mechanical and Tribological Properties of Polytetrafluoroethylene Composites Modified by Carbon Fibers and Zeolite

Currently, lightweight and high-strength polymer composites can provide weight savings in the automotive and process equipment industries by replacing metal parts. Polytetrafluoroethylene and polymer composites based on it are used in various tribological applications due to their excellent antifriction properties and thermal stability. This article examines the effect of combined fillers (carbon fibers and zeolite) on the mechanical, tribological properties, and structure of polytetrafluoroethylene. It is shown that the introduction of combined fillers into polytetrafluoroethylene retains the tensile strength and elongation at break at a content of 1–5 wt.% of carbon fibers, the compressive stress increased by 53%, and the yield stress increased by 45% relative to the initial polymer. The wear resistance of polymer composites increased 810-fold compared to the initial polytetrafluoroethylene while maintaining a low coefficient of friction. The structural features of polymer composites are characterized by X-ray diffraction analysis, infrared spectroscopy, and scanning electron microscopy.

Research of surface layer properties of piston rings after gas thermal spraying

Today, one of the important problems of mechanical engineering is to increase the reliability and durability of machines. A special place in this matter is occupied by increasing the wear resistance of parts. As for diesel construction, the problem of increasing the hardness and wear resistance of piston rings is very important. Goal. The goal is study of the structure and nature of changes in the hardness of the surface layer obtained by gas-thermal combined spraying, after grinding, running-in and mileage of the diesel engine, i. e., at all stages of the production cycle. Methodology. The coating on the rings was applied by the method of two-wire metallization with independent supply of wires made of 11X18M steel and molybdenum. Metallographic analysis was used to study the structure of the obtained coating. The condition of the surface layer after coating, grinding, running-in and diesel run was studied by measuring the microhardness. Results. Metallographic analysis of the interface between steel and molybdenum coating – cast iron for many rings and different parts of one ring shows that the coating interacts closely with the substrate along the entire application profile. The structure of molybdenum particles demonstrates their fineness. This is due to the fact that the rapid crystallization under pressure contributes to the creation of a fine-grained structure. Comparison of the microhardness of molybdenum and steel wires with steel-molybdenum coating indicates a significant strengthening of molybdenum and steel particles during spraying, due to the processes of structure formation. Experimental data indicate the stability of the hardness of both molybdenum particles and steel particles, which is important for the coating in operation. Originality. Features of formation of a gas-thermal covering at a simultaneous electric arc spraying of molybdenum and 11Х18М steel on piston rings from pig-iron are established. It is shown that a layered structure is formed, which consists mainly of steel and molybdenum particles. The reasons for the wide range of properties of steel and molybdenum particles have been clarified. It is proved that the operational properties of steel-molybdenum coating are due to its antifriction properties, porosity, which provides self-lubrication of the friction surface, good adhesion to the substrate, which increases by 3–4 times compared to traditional methods. Practical value. The proposed technology of gas-thermal spraying significantly increases the service life of piston rings operating in wear conditions.

Investigation of changes in the properties of diamond-like films under friction by the XPS method

The combination of unique physicochemical, mechanical and tribological properties of diamond-like coatings determines the prospects for their use in critical friction units, including those operating in a rarefied atmosphere and vacuum. The properties of diamond-like carbon (DLC) coatings depend on the contribution of the sp2 and sp3 fractions of the carbon hybrid atomic electron orbitals. Modern methods of determining the graphite and diamond proportion in coatings are time-consuming and insufficiently accurate. In addition, the determination of the sp3/sp2 ratio is often difficult due to the displacement of the energy position of the C1s electron line. In this paper, the change in the chemical state of carbon over the thickness of a diamond-like coating is studied by X-ray photoelectron spectroscopy. Analysis of the carbon line fine structure of the differential graphite spectra (sp2 bonds) and diamond (sp3 bonds) allowed us to establish the parameter δ, which determines the ratio of the graphite and diamond components in the DLC coating. Profiling with Ar+ ions of the diamondlike coating surface showed that with an increase in the etching time, the proportion of amorphized carbon increases, which means that the antifriction properties increase with the abrasion of the coating. The obtained regularities allow us to predict changes in the tribological properties of DLC coatings during operation. Ion profiling also allows to determine the thickness of coatings with high accuracy.

Arctic transmission oil

The tasks of the development of the Far North, the Arctic and the Antarctic require ensuring the operability of equipment units in low temperatures. To solve this problem, it is necessary to develop lubricants using new synthetic oils, a distinctive feature of which are low pour points. On the basis of polyethylsiloxane fluid and petroleum oil, we have developed a gear oil for the Arctic latitudes, which is efficient at temperatures down to -75 ° C (TMarktic). It is shown TMarktic’s antifriction properties are better than those of TSgip helicopter tail gear oil. The combined use of XPS and IR-Fourier methods for the analysis of the friction surface made it possible to conclude that the formation of the boundary film involves both antiwear additive molecules, which are part of the modified oil, due to the P-O, P=O, S=O bonds, so and molecules of polyethylsiloxane liquid due to C-O and Si-O bonds. Secondary surface structures are formed by TMarctic oil on the surface of iron oxide and include hydrocarbon and siloxane fragments. The high antiwear and extreme pressure properties of TMarktic are due to free sulfur and bound in iron sulfide.

Friction surface modifiers of carbon-containing material for high-temperature operation

The results of high-temperature tribological tests of carbon-containing material in friction on heat-resistant stainless steel 40X13 in the temperature range from 20 to 700 °C under atmospheric conditions are presented. Friction surface modifiers “Argolon-2D” material improve antifriction properties and decrease friction coefficient value. Friction coefficient when using Ni-Se-PTFE modifier at load of 0.67 MPa and speed of 0.16 m/s is less by 5% than at speed of 0.05 m/s, and at speed of 0.25 m/s friction coefficient is less by 13% than at speed of 0.05 m/s. At 500 °C and a load of 0.67 MPa the friction coefficient when using Ni-Se-PTFE modifier is 30% higher than when using InSb-PTFE modifier, and the friction coefficient when using CuO-PTFE modifier is 1.2 times higher than when using InSb-PTFE modifier.

High-temperature friction units with carbon-containing materials

The frictional interaction of carbon-carbon composites with steel at high temperatures is considered. Antifriction properties of carbon composites are investigated at friction on a steel at speeds of 0,050,25 m/s and pressures of 0,31,0 MPa. The advantages of Hardcarb-T material in comparison with Argalon-2D material are experimentally determined. Keywords: temperature, friction, contact pressure, composites, steel, speed, friction coefficient. [email protected]

Antifriction properties of ceramic materials under high-speed sliding process

The issues of tribology of a composite cermet material under high-speed short-term dry sliding friction process are discussed in this article. The possibility of reducing the friction coefficient due to the processing of cermet with selenium vapor is substantiated. Model experiments were carried out on a laboratory friction machine according to the pin-on-disk test at sliding speeds up to 100 m/s. Experimental dependences of the coefficient of friction on speed, load and the effect of mechanical properties on friction and wear of a friction couple are analyzed. These studies were based on the assumption about the possibility of reducing the friction coefficient of cermet by processing in chalcogen vapor and restoring the antifriction properties of the resulting lubricating film with an increase in temperature from friction heating of friction surfaces. It is proposed to carry out processing in chalcogen vapors of thermal protection ceramic coatings of the housings of the axial machines gas path, in particular, in aircraft engines. This technological process in conditions of emergency contact of the housing with the blades of the rapidly rotating disk will reduce the risk of engine destruction with catastrophic consequences.

Improving the antifriction properties of the housing-rotor coupling in axial turbomachines

The article discusses the frictional interaction of carbon-carbon composite material on steel. Antifriction properties and wear resistance of the material under dry friction at speeds up to 100 m/s are investigated. The effect of velocity and contact pressure on the friction coefficient and wear resistance of a carbon composite is analyzed. The regularities of the change in the coefficient of friction are determined depending on the load-speed factors. The assumption is substantiated that the high thermal stability of the carbon composite, its low hardness, good antifriction properties and high wear resistance allow the material to be used in friction units operating at very high speeds and temperatures. In order to improve the reliability and reduce gas flows in axial turbomachines, on the basis of the study carried out, it is recommended that instead of heat-resistant coatings, a lining of the gas duct casing should be made of carbon composite.