Stress Distribution and Failure Characteristics of Stope Overburden of an Inclined Coal Seam

The stress distribution, failure depth, and shape and range of overlying strata of the stope are important bases for the prevention of roof water hazards and determination of reasonable locations of roof roadways. Based on the hydrogeological data of the E9103 workface, FLAC numerical simulation software was used to establish a numerical calculation model of the overlying strata of the E9103 inclined coal seam, and the stress distribution and failure characteristics of the overlying strata were analyzed. The development height of the caving and water-flowing fractured zones in the overlying strata of the workface was determined. Results showed that the stress reduction area appeared above the goaf in the form of an “arched” distribution, and tensile stress occurred in the local area of the overburden. The overburden relief arch of the workface was symmetrically distributed along the advanced direction and asymmetrically distributed along the inclined direction, with the arch crown deflecting above the workface. The horizontal and vertical displacements of the overlying strata of the stope increased with the advancing distance of the workface. The horizontal displacement in the x -direction presented two obvious regions, and the critical points of the two regions moved forward with the advancement of the workface and showed a certain degree of symmetry. The horizontal displacement in the y -direction presented an “inverted bowl” distribution and increased with the advancement of the workface. The main failure forms of the overlying strata of the workface were a tensile and shear failure, and shear failure was dominant in the upper direction. The height of the overburden caving zone in the workface had little relationship with the advancing distance of the workface and increased slowly as the advancing distance of the workface increased. The development height of the caving zone is 7.2–18.13 m. The development height of the water conduction fissure zone increased rapidly with the increase in the advancing distance of the workface. When the advancing distance was equal to the length of the workface, the development height of the water conduction fissure zone was flat and basically maintained at a stable value. The development height of the water conduction fissure zone is 30.8–62.2 m. These research findings have important engineering importance for ensuring safe and efficient mining of E9103 workface.

An Estimation Model for Hydraulic Conductivity of Low-Permeability and Unfilled Fractured Granite in Underground Water-Sealed Storage Caverns

The permeability of rock mass is closely related to the stability and safety of underground structure, especially in underground water-sealed storage caverns. With regard to the estimation approaches in predicting the hydraulic conductivity of fractured granite in water-sealed storage caverns, there are some limitations of parameter selection leading to poor applicability. Focusing on the contribution of the water conduction fractures (WCF) to the hydraulic conductivity, we attempted to propose a novel model, the CA model, for estimating its hydraulic conductivity based on the fracture orientation index and the normal stress index by analyzing the borehole wall imaging results and borehole water-pressure test results in the site of underground water-sealed storage caverns. The results indicated that the proposed model is suitable for low-permeability and unfilled fractured granite, exhibiting good effectiveness by clarifying the relation between geomechanical parameters and hydraulic behavior. Further, the parameters upon which the proposed model is based are representative and easy to obtain, which has certain guiding significance and reference value for analyzing the permeability characteristics of similar rock masses.

The Widened Pipe Model of plant hydraulic evolution

Shaping global water and carbon cycles, plants lift water from roots to leaves through xylem conduits. The importance of xylem water conduction makes it crucial to understand how natural selection deploys conduit diameters within and across plants. Wider conduits transport more water but are likely more vulnerable to conduction-blocking gas embolisms and cost more for a plant to build, a tension necessarily shaping xylem conduit diameters along plant stems. We build on this expectation to present the Widened Pipe Model (WPM) of plant hydraulic evolution, testing it against a global dataset. The WPM predicts that xylem conduits should be narrowest at the stem tips, widening quickly before plateauing toward the stem base. This universal profile emerges from Pareto modeling of a trade-off between just two competing vectors of natural selection: one favoring rapid widening of conduits tip to base, minimizing hydraulic resistance, and another favoring slow widening of conduits, minimizing carbon cost and embolism risk. Our data spanning terrestrial plant orders, life forms, habitats, and sizes conform closely to WPM predictions. The WPM highlights carbon economy as a powerful vector of natural selection shaping plant function. It further implies that factors that cause resistance in plant conductive systems, such as conduit pit membrane resistance, should scale in exact harmony with tip-to-base conduit widening. Furthermore, the WPM implies that alterations in the environments of individual plants should lead to changes in plant height, for example, shedding terminal branches and resprouting at lower height under drier climates, thus achieving narrower and potentially more embolism-resistant conduits.

Artifactual lipid coatings on intervessel pit membranes in dried xylem tissues of some angiosperms

Intervessel pit membranes are recognized as key structures for influencing water flow/embolism resistance. The mechanisms remain largely unclear owing to difficulties in examining them intact in nature. This study investigates ethanol-extractable pit membrane incrustations (PMIs), which were previously reported in certain angiosperms and may affect their water conduction. The presence of PMIs was determined for 40 angiosperms by field-emission scanning electron microscopy (FE-SEM). Candidate components of PMIs were determined by chemical analyses of wood extracts, and their distributions in the xylem were examined by time-of-flight secondary ion mass spectrometry (TOF-SIMS). Cryo-TOF-SIMS and cryo-FE-SEM were also performed to clarify the native distribution of PMIs. PMIs were observed in 11 species. Some of them were categorized as fat trees, which are known to store abundant lipids. Tilia japonica sapwood displaying PMIs contained large amounts of lipids, which were distributed in the dried xylem tissue, consistent with the distribution of the PMIs. In the frozen samples of T. japonica, however, the distributions were restricted to the parenchyma. In conclusion, PMIs consist of an artifactual coating of lipids originated from the parenchyma in dried samples at room temperature. Researchers performing surface analyses of plant cell walls should take strong precautions against such self-coating by these intrinsic chemicals.

The high-yield direct synthesis of dimethyl ether from CO2 and H2 in a dry reaction environment

Highly efficient DME synthesis from CO2 and H2 was realized in a dry reaction environment via the incorporation of a water-conduction membrane.

Na+-gated water-conducting nanochannels for boosting CO2 conversion to liquid fuels

Robust, gas-impeding water-conduction nanochannels that can sieve water from small gas molecules such as hydrogen (H2), particularly at high temperature and pressure, are desirable for boosting many important reactions severely restricted by water (the major by-product) both thermodynamically and kinetically. Identifying and constructing such nanochannels into large-area separation membranes without introducing extra defects is challenging. We found that sodium ion (Na+)–gated water-conduction nanochannels could be created by assembling NaA zeolite crystals into a continuous, defect-free separation membrane through a rationally designed method. Highly efficient in situ water removal through water-conduction nanochannels led to a substantial increase in carbon dioxide (CO2) conversion and methanol yield in CO2 hydrogenation for methanol production.

Capillary-driven desalination in a synthetic mangrove

According to the cohesion-tension theory, mangrove trees desalinate salty water using highly negative pressure (or tension) that is generated by evaporative capillary forces in mangrove leaves. Here, we demonstrate a synthetic mangrove that mimics the main features of the natural mangrove: capillary pumping (leaves), stable water conduction in highly metastable states (stem), and membrane desalination (root). When using nanoporous membranes as leaves, the maximum osmotic pressures of saline feeds (10 to 30 bar) allowing pure water uptake precisely correspond to expected capillary pressures based on the Young-Laplace equation. Hydrogel-based leaves allow for stable operation and desalination of hypersaline solutions with osmotic pressures approaching 400 bar, fivefold greater than the pressure limits of conventional reverse osmosis. Our findings support the applicability of the cohesion-tension theory to desalination in mangroves, provide a new platform to study plant hydraulics, and create possibilities for engineered membrane separations using large, passively generated capillary pressures.

The Progression of Xylem Vessel Cell Differentiation is Dependent on the Activity Level of VND7 in Arabidopsis thaliana

Xylem vessels are important for water conduction in vascular plants. The VASCULAR-RELATED NAC-DOMAIN (VND) family proteins, master regulators of xylem vessel cell differentiation in Arabidopsis thaliana, can upregulate a set of genes required for xylem vessel cell differentiation, including those involved in secondary cell wall (SCW) formation and programmed cell death (PCD); however, it is not fully understood how VND activity levels influence these processes. Here, we examined the Arabidopsis VND7-VP16-GR line, in which VND7 activity is post-translationally activated by treatments with different concentrations of dexamethasone (DEX), a synthetic glucocorticoid. Our observations showed that 1 nM DEX induced weak SCW deposition, but not PCD, whereas 10 or 100 nM DEX induced both SCW deposition and PCD. The decreased chlorophyll contents and SCW deposition were apparent after 24 h of 100 nM DEX treatment, but became evident only after 48 h of 10 nM DEX treatment. Moreover, the lower DEX concentrations delayed the upregulation of VND7 downstream genes, and decreased their induction levels. They collectively suggest that the regulation of VND activity is important not only to initiate xylem vessel cell differentiation, but also regulate the quality of the xylem vessels through VND-activity-dependent upregulation of the PCD- and SCW-related genes.

Involvement of VNS NAC-domain transcription factors in tracheid formation in Pinus taeda

Vascular plants have two types of water-conducting cells, xylem vessel cells (in angiosperms) and tracheid cells (in ferns and gymnosperms). These cells are commonly characterized by secondary cell wall (SCW) formation and programmed cell death (PCD), which increase the efficiency of water conduction. The differentiation of xylem vessel cells is regulated by a set of NAC (NAM, ATAF1/2 and CUC2) transcription factors, called the VASCULAR-RELATED NAC-DOMAIN (VND) family, in Arabidopsis thaliana Linne. The VNDs regulate the transcriptional induction of genes required for SCW formation and PCD. However, information on the transcriptional regulation of tracheid cell differentiation is still limited. Here, we performed functional analysis of loblolly pine (Pinus taeda Linne) VND homologs (PtaVNS, for VND, NST/SND, SMB-related protein). We identified five PtaVNS genes in the loblolly pine genome, and four of these PtaVNS genes were highly expressed in tissues with tracheid cells, such as shoot apices and developing xylem. Transient overexpression of PtaVNS genes induced xylem vessel cell-like patterning of SCW deposition in tobacco (Nicotiana benthamiana Domin) leaves, and up-regulated the promoter activities of loblolly pine genes homologous to SCW-related MYB transcription factor genes and cellulose synthase genes, as well as to cysteine protease genes for PCD. Collectively, our data indicated that PtaVNS proteins possess transcriptional activity to induce the molecular programs required for tracheid formation, i.e., SCW formation and PCD. Moreover, these findings suggest that the VNS–MYB-based transcriptional network regulating water-conducting cell differentiation in angiosperm and moss plants is conserved in gymnosperms.