Formation of Humic-Like Substances during the Technological Process of Lignohumate® Synthesis as a Function of Time

The composition, structure, and biological activity of humic-like substances (HLS) synthesized in the process of lignosulfonate conversion for the production of the humic product Lignohumate® (LH) were examined. It is shown that during the hydrolytic-oxidative process, the transformation of raw material and accumulation of HLS occur. Data on the chemical (elemental content, functional groups, FTIR) and spectral (absorbance and fluorescence) parameters and biological activity (in phytotest) combined with PCA show that the LH samples can be divided into three groups, depending on the duration of synthesis: initial raw material (0-time sample); “young” HLS (15–30 min), and “mature” HLS in 45–120 min of treatment. During the first 30 min, reactions similar to the ones that occur during lignin humification in nature take place: depolymerization, oxidative carboxylation, and further polycondensation with the formation and accumulation of HLS. After 45–60 min, the share of HLS reaches a maximum, and its composition stabilizes. Biological activity reaches a maximum after 45–60 min of treatment, and at that stage, the further synthesis process can be stopped. Further processing (up to 2 h and more) does not provide any added value to the humic product.

Not just shades of grey: life is full of colour for the ocellate freshwater river stingray (Potamotrygon motoro)

Previous studies have shown that marine stingrays have the anatomical and physiological basis for colour vision, with cone spectral sensitivities in the blue to green range of the visible spectrum. Behavioural studies on Glaucostegus typus also showed that blue and grey can be perceived and discriminated. The present study is the first to assess visual opsin genetics in the ocellate river stingray (Potamotrygon motoro) and test if individuals perceive colour in two alternative forced choice experiments. Retinal transcriptome profiling using RNA-Seq and quantification demonstrated the presence of lws and rh2 cone opsin genes and a highly expressed single rod (rh1) opsin gene. Spectral tuning analysis predicted these vitamin-A1 based visual photopigments to exhibit spectral absorbance maxima at 461 nm (rh2), 496 nm (rh1), and 555 nm (lws); suggesting the presence of dichromacy in this species. Indeed, P. motoro demonstrates the potential to be equally sensitive to wavelengths from 380 nm to 600 nm of the visible spectrum. Behavioural results showed that red and green plates, as well as blue and yellow plates, were readily discriminated based on colour; however, brightness differences also played a part in the discrimination of blue and yellow. Red hues of different brightness were distinguished significantly above chance level from one another. In conclusion, the genetic and behavioural results support prior data on marine stingrays. However, this study suggests that freshwater stingrays of the family Potamotrygonidae may have a visual colour system that has ecologically adapted to a riverine habitat.

Fast-Response Colorimetric UVC Sensor Made of a Ga2O3 Photocatalyst with a Hole Scavenger

A fast-response colorimetric ultraviolet-C (UVC) sensor was demonstrated using a gallium oxide (Ga2O3) photocatalyst with small amounts of triethanolamine (TEOA) in methylene blue (MB) solutions and a conventional RGB photodetector. The color of the MB solution changed upon UVC exposure, which was observed using an in situ RGB photodetector. Thereby, the UVC exposure was numerically quantified as an MB reduction rate with the R value of the photodetector, which was linearly correlated with the measured spectral absorbance using a UV-Vis spectrophotometer. Small amount of TEOA in the MB solution served as a hole scavenger, which resulted in fast MB color changes due to the enhanced charge separation. However, excessive TEOA over 5 wt.% started to block the catalytical active site on the surface of Ga2O3, prohibiting the chemical reaction between the MB molecules and catalytic sites. The proposed colorimetric UVC sensor could monitor the detrimental UVC radiation with high responsivity at a low cost.

Experimental Investigation on Preparation and Stability of Al2O3 Nanofluid In Deionized Water and Ethylene Glycol

Nanofluid has the potential as a cooling medium for the next generation fluid as it possesses many advantages in many engineering applications. However, one of the main challenges is to establish a well-dispersed nanoparticles system in a base fluid. The preparation technique of nanofluid plays an important part as it influences the measurement of thermal conductivity. Therefore, the objectives of this study are to evaluate the nanoparticle dispersion in different base fluid compositions and to determine the optimized suspension sonication time. In detail, 0.2 wt.% of Al2O3 nanofluid stability in the three ratios of base fluid (deionized water:ethylene glycol) 80:20, 70:30 and 60:40 were studied. The studies were based on a visual inspection and spectral absorbance analysis. It has clearly shown that the nanofluids prepared in 60:40 base fluid within 3 hours sonication time was the most stable suspension compared to other nanofluids. The visual inspection indicated nanofluid condition remains stable after 30 days. The spectral absorbance of nanofluids was recorded at 100 % for 5 days after preparation and remains above 95 % compared to the initial value, reflecting stable suspension. Hence the novelty of this work lies in the nanofluid stability based on sonication time and base fluid compositions.

Study of the Optical Characteristics of Aluminim Doped Zno Thin Film

In this work, the study on the influence of the aluminium on the optical properties of ZnO thin film was carried out with a focus on the influence of variation of aluminium ions on the optical behaviour of the ZnO thin film. The film was deposited on the glass substrates by chemical bath deposition technique and aluminium was used in the following varied quantity 0.1, 0.2, and 0.3M to dope the thin films respectively. The solutions were prepared using zinc sulphate, ammonia and Hexamine with aluminium nitrate. The optical characteristics of the film such as the spectral absorbance, reflectance and transmittance within the ultraviolet and near infra-red region of electromagnetic wave spectra were investigated using UV-VIS spectroscopy with the energy band gap found to be in the range of 3.5eV to 3.9eV.

Visual Opsin Diversity in Sharks and Rays

The diversity of color vision systems found in extant vertebrates suggests that different evolutionary selection pressures have driven specializations in photoreceptor complement and visual pigment spectral tuning appropriate for an animal’s behavior, habitat, and life history. Aquatic vertebrates in particular show high variability in chromatic vision and have become important models for understanding the role of color vision in prey detection, predator avoidance, and social interactions. In this study, we examined the capacity for chromatic vision in elasmobranch fishes, a group that have received relatively little attention to date. We used microspectrophotometry to measure the spectral absorbance of the visual pigments in the outer segments of individual photoreceptors from several ray and shark species, and we sequenced the opsin mRNAs obtained from the retinas of the same species, as well as from additional elasmobranch species. We reveal the phylogenetically widespread occurrence of dichromatic color vision in rays based on two cone opsins, RH2 and LWS. We also confirm that all shark species studied to date appear to be cone monochromats but report that in different species the single cone opsin may be of either the LWS or the RH2 class. From this, we infer that cone monochromacy in sharks has evolved independently on multiple occasions. Together with earlier discoveries in secondarily aquatic marine mammals, this suggests that cone-based color vision may be of little use for large marine predators, such as sharks, pinnipeds, and cetaceans.

A fast and sensitive room-temperature graphene nanomechanical bolometer

Bolometers are a powerful means of detecting light. Emerging applications demand that bolometers work at room temperature, while maintaining high speed and sensitivity, properties which are inherently limited by the heat capacity of the detector. To this end, graphene has generated interest, because it has the lowest mass per unit area of any material, while also possessing extreme thermal stability and an unmatched spectral absorbance. Yet, due to its weakly temperature-dependent electrical resistivity, graphene has failed to challenge the state-of-the-art at room temperature. Here, in a departure from conventional bolometry, we use a graphene nanoelectromechanical system to detect light via resonant sensing. In our approach, absorbed light heats and thermally tensions a suspended graphene resonator, thereby shifting its resonant frequency. Using the resonant frequency as a readout for photodetection, we achieve a room-temperature noise-equivalent power (2 pW Hz−1/2) and bandwidth (from 10 kHz up to 1.3 MHz), challenging the state-of-the-art.

Carboxylic Acid Functionalization at the Meso-Position of the Bodipy Core and Its Influence on Photovoltaic Performance

Two bodipy dyes with different carboxylic acids on the meso-position of the bodipy core were prepared and used to sensitize TiO2 photoelectrodes. On the basis of spectroscopic characterization, the photoelectrodes were used to fabricate photoelectrochemical cells (PECs) for solar light harvesting. Photovoltaic measurements showed that both bodipy dyes successfully sensitized PECs with short-circuit current densities (JSC) two-fold higher compared to the control. The increase in generated current was attributed to the gain in spectral absorbance due to the presence of bodipy. Finally, the influence of co-sensitization of bodipy and N719 dye was also investigated and photovoltaic device performance discussed.

Analysis of Near-infrared (NIR) spectroscopy for chlorophyll prediction in oil palm leaves

Oil palm nutrient content is investigated with using chlorophyll as a representative factor correlated with NIR spectroscopy spectral absorbance. NIR spectroscopy method of sampling have been tested to overcome time consuming, complex chemical analysis procedure and invasive sampling method in order to identify chlorophyll content in an oil palm tree. Spectral absorbance data from range 900 nm to 1700 nm and chlorophyll data, then tested through five pre-processing methods which is Savitzky-Golay Smoothing (SGS), Multiplicative Scatter Correction (MSC), Single Normal Variation (SNV), First Derivative (1D) and also Second Derivative (2D) using Partial Least Square (PLS) regression prediction model to evaluate the correlation between both data. The overall results show, SGS has the best performance for preprocessing method with the results, the coefficient of determination (R2) values of 0.9998 and root mean square error (RMSE) values of 0.0639. In summary, correlation of NIR spectral absorbance data and chlorophyll can be achieved using a PLS regression model with SGS pre-processing technique. Thus, we can conclude that NIR spectroscopy method can be used to identify chlorophyll content in oil palm with using time saving, simple sampling and non-invasive method.