Blue and green food webs respond differently to elevation and land use

While aquatic (blue) and terrestrial (green) food webs are parts of the same landscape, it remains unclear whether they respond similarly to shared environmental gradients. We use empirical community data from hundreds of sites across Switzerland, and show that blue and green food webs have different structural and ecological properties along elevation as a temperature proxy, and among various land-use types. Specifically, in green food webs, their modular structure increases with elevation and the overlap of consumers' diet niche decreases, while the opposite pattern is observed in blue food webs. Such differences between blue and green food webs are particularly pronounced in farmland-dominated habitats, indicating that anthropogenic habitat modification moderates the climatic effects on food webs but differently in blue versus green systems. These findings indicate general structural differences between blue and green food webs and suggest their potential divergent future alterations through land use or climatic changes.

Induced Polarization as a Tool to Assess Alteration in Geothermal Systems: A Review

The mineral alteration patterns in high- to low-temperature geothermal fields affect the induced polarization (electrical conductivity and chargeability) properties of volcanic rocks. Indeed, these properties are sensitive to the cation exchange capacity and the porosity of the rock, which are both dependent on the alteration path, temperature, and depth of burial. Therefore induced polarization tomography appears as a powerful non-intrusive geophysical method to investigate alteration patterns in geothermal fields. Among clay minerals, the production of smectite through prograde reactions occurs progressively in volcanic rocks up to 220 °C. The presence of smectite dominates the induced polarization response of the volcanic rocks because of its very large cation exchange capacity. It follows that induced polarization can be used as a non-intrusive temperature proxy up to 220 °C for both active and inactive geothermal fields, recording the highest temperatures reached in the past. The influence of magnetite and pyrite, two semi-conductors, also has a strong influence regarding the induced polarization properties of volcanic rocks. Various field examples are discussed to show how induced polarization can be used to image volcanic conduits and smectite-rich clay caps in volcanic areas for both stratovolcanoes and shield volcanoes.

Isotopes of molecular nitrogen, oxygen, and argon in the South Pole ice core document local and global climate change through the last deglaciation.

<p>Ice core gas records are an invaluable paleoclimatic archive. The three most abundant gases in air, nitrogen (N<sub>2</sub>), oxygen (O<sub>2</sub>), and argon (Ar), provide paleoclimatic information about both global and regional processes including tropical rainfall patterns and local surface temperature changes. We present a large dataset of elemental and isotopic ratios of N<sub>2</sub>, O<sub>2</sub>, and Ar (O<sub>2</sub>/N<sub>2</sub>, Ar/N<sub>2</sub>, δ<sup>15</sup>N, δ<sup>18</sup>O, & δ<sup>40</sup>Ar) from the South Pole Ice Core between 0 – 52,000 yr BP, with a focus on high precision δ<sup>15</sup>N and δ<sup>40</sup>Ar measurements between 5,000 – 32,000 yr BP. The unprecedented precision of our measurements allows us to use δ<sup>15</sup>N<sub>excess </sub>(= δ<sup>15</sup>N - δ<sup>40</sup>Ar/4) to reconstruct past temperature change at the South Pole. Although this proxy has been widely applied in Greenland, this is the first time it has been successfully applied to Antarctic ice and provides a valuable independent check on the more traditional water isotopes temperature proxy. We find good agreement between the two during the relatively stable climate of the glacial period and the Holocene. However the temperature reconstructions diverge during the deglaciation. We present several hypotheses that could explain the discrepancy and look to other emerging ice core temperature proxies to support our interpretation.</p>

Temperature-induced microstructural changes in shells of laboratory-grown Arctica islandica (Bivalvia)

Bivalve shells are increasingly used as archives for high-resolution paleoclimate analyses. However, there is still an urgent need for quantitative temperature proxies that work without knowledge of the water chemistry–as is required for δ18O-based paleothermometry–and can better withstand diagenetic overprint. Recently, microstructural properties have been identified as a potential candidate fulfilling these requirements. So far, only few different microstructure categories (nacreous, prismatic and crossed-lamellar) of some short-lived species have been studied in detail, and in all such studies, the size and/or shape of individual biomineral units was found to increase with water temperature. Here, we explore whether the same applies to properties of the crossed-acicular microstructure in the hinge plate of Arctica islandica, the microstructurally most uniform shell portion in this species. In order to focus solely on the effect of temperature on microstructural properties, this study uses bivalves that grew their shells under controlled temperature conditions (1, 3, 6, 9, 12 and 15°C) in the laboratory. With increasing temperature, the size of the largest individual biomineral units and the relative proportion of shell occupied by the crystalline phase increased. The size of the largest pores, a specific microstructural feature of A. islandica, whose potential role in biomineralization is discussed here, increased exponentially with culturing temperature. This study employs scanning electron microscopy in combination with automated image processing software, including an innovative machine learning–based image segmentation method. The new method greatly facilitates the recognition of microstructural entities and enables a faster and more reliable microstructural analysis than previously used techniques. Results of this study establish the new microstructural temperature proxy in the crossed-acicular microstructures of A. islandica and point to an overarching control mechanism of temperature on the micrometer-scale architecture of bivalve shells across species boundaries.

Numerical experiments on firn isotope diffusion with the Community Firn Model

Advances in analytical methods have made it possible to obtain high-resolution water isotopic data from ice cores. Their spectral signature contains information on the diffusion process that attenuated the isotopic signal during the firn densification process. Here, we provide a tool for estimating firn-diffusion rates that builds on the Community Firn Model. Our model requires two main inputs, temperature and accumulation, and it calculates the diffusion lengths for δ17O, δ18O and δD. Prior information on the isotopic signal of the precipitation is not a requirement. In combination with deconvolution techniques, diffusion lengths can be used in order reconstruct the pre-diffusion isotopic signal. Furthermore, the temperature dependence of the isotope diffusion and firn densification makes the diffusion length an interesting candidate as a temperature proxy. We test the model under steady state and transient scenarios and compare four densification models. Comparisons with ice core data provide an evaluation of the four models and indicate that there are differences in their performance. Combining data-based diffusion length estimates with information on past accumulation rates and ice flow thinning, we reconstruct absolute temperatures from three Antarctic ice core sites.