Improving the shape stability and enhancing the properties of layer dependent material extruded biodegradable polylactic acid for thin implants

Purpose This paper aims to establish an appropriate annealing method, which is necessary for shape stability and to evaluate their potential degradation performance of 1-, 3- and 5-layer material extruded polylactic-acid specimens by enhancing their thermal and mechanical properties. Design/methodology/approach The distortion of each layered printed specimen subjected to degradation was calculated in x- and y-direction. Each layered specimen was subjected to annealing at 70°C, 80°C and 90°C for 2 h and at 80°C for 1, 4, 8 and 16 h. Thermal, molecular weight and mechanical properties were calculated using, differential scanning calorimetry, gel permeation chromatography and tensile testing machine, respectively. Findings In the x-direction, distortion was 16.08 mm for one-layer non-annealed printed specimens and decreased by 73% and 83% for 3- and 5-layer, respectively, while each layered non-annealed specimen subjected to degradation at 37°C for one month. Within the outlined study, annealing treatment enhances properties such as the degree of crystallinity (%χ) up to 34%, Young’s modulus (E) by 30% and ultimate tensile strength by 20% compared to the non-annealed specimens. Practical implications The future research accomplishments will be concentrated on the design, development and optimisation of degraded biomedical implants using material extrusion thin films including drug delivery system and fixation plates. Originality/value The printed thin specimens subjected to degradation were investigated. This research developed a new understanding of the effect of the annealing temperature and time on the mechanical, thermal and molecular weight properties for each layered specimen.

Dynamic ESPI Evaluation of Deformation and Fracture Mechanism of 7075 Aluminum Alloy

The deformation and fracture mechanism in 7075 aluminum alloy is discussed based on a field theoretical approach. A pair of peak-aged and overaged plate specimens are prepared under the respective precipitation conditions, and their plastic deformation behaviors are visualized with two-dimensional electronic speckle pattern interferometry (ESPI). The in-plane velocity field caused by monotonic tensile loading is monitored continuously via the contour analysis method of ESPI. In the plastic regime, the peak-aged specimen exhibits a macroscopically uniform deformation behavior, while the annealed specimen exhibits non-uniform deformation characterized by a localized shear band. The occurrence of the shear band is explained by the transition of the material’s elastic resistive mechanism from the longitudinal force dominant to shear force dominant mode. The shear force is interpreted as the frictional force that drives mobile dislocations along the shear band. The dynamic behavior of the shear band is explained as representing the motion of a solitary wave. The observed decrease in the solitary wave’s velocity is accounted for by the change in the acoustic impedance with the advancement of plastic deformation.

Direct Characterization of the Relation between the Mechanical Response and Microstructure Evolution in Aluminum by Transmission Electron Microscopy In Situ Straining

Transmission electron microscopy in situ straining experiments of Al single crystals with different initial lattice defect densities have been performed. The as-focused ion beam (FIB)-processed pillar sample contained a high density of prismatic dislocation loops with the <111> Burgers vector, while the post-annealed specimen had an almost defect-free microstructure. In both specimens, plastic deformation occurred with repetitive stress drops (∆σ). The stress drops were accompanied by certain dislocation motions, suggesting the dislocation avalanche phenomenon. ∆σ for the as-FIB Al pillar sample was smaller than that for the post-annealed Al sample. This can be considered to be because of the interaction of gliding dislocations with immobile prismatic dislocation loops introduced by the FIB. The reloading process after stress reduction was dominated by elastic behavior because the slope of the load–displacement curve for reloading was close to the Young’s modulus of Al. Microplasticity was observed during the load-recovery process, suggesting that microyielding and a dislocation avalanche repeatedly occurred, leading to intermittent plasticity as an elementary step of macroplastic deformation.

An Investigation of Friction Coefficient on Microstructure and Texture Evolution of Interstitial-Free Steel during Warm Rolling and Subsequent Annealing

A Ti bearing interstitial-free steel was finishing rolled in the ferrite region with and without lubrication and microstructures, mechanical properties and textures evolution during warm rolling and subsequent annealing were investigated by OM, SEM, tensile test and ODF. The results show that the surface microstructure of the as-rolled specimen without lubrication is composed of dense shear bands, while the microstructures of the central layer of the as-rolled specimen without lubrication and the whole cross section of the as-rolled specimen with lubrication are elongated ferrite. Short-time annealing can make the non-lubricated rolling sample recrystallize, but the lubricated rolling sample cannot. After complete recrystallization, the microstructure of the surface layer of the as-annealed specimen without lubrication is finer than that of the center layer of the as-annealed specimen without lubrication and the whole section of the as-annealed specimen with lubrication. The mechanical properties of as-annealed sample without lubrication change significantly in the initial annealing stage, while that of as-annealed sample with lubrication remain unchanged until the end stage of annealing. The surface layers of the as-rolled samples have strong Goss component and weak γ fibre components, while the central layers have strong γ fibre components and moderate rotated cubic components. As annealing proceeds, the Goss components of the surface layer decrease and the γ fibre components increase. The rotated cubic components in the central layer are gradually transformed into γ texture.

Research on the Temperature Changes of 20CrNiMoH Steel during Turning Process

Material cutting properties can be judged by turning temperature and chip shape. A new method that can measure turning temperature more accurately was discussed in this paper. Compared with the traditional method, results show that turning temperature can be accurately measured through a new method in turning process. Turning temperature become stable and will not jump after 20s later. In addition, the higher the hardness, the higher the energy is needed, leading to the higher turning temperature. The average turning temperature of the quenched specimen, normalized specimen and annealed specimen measured through the new method is 100°C,70°Cand 60°C, respectively. And the chip morphologies of quenched specimen, normalized specimen and annealed specimen are irregular band chips, spiral debris chips and C-shaped chips, respectively.

Effects of magnetic field intensity on carbon diffusion coefficient in pure iron in γ-Fe temperature region

Effects of magnetic field intensity on carbon diffusion coefficient in pure iron in the γ- Fe temperature region were investigated using carburizing technology. The carbon penetration profiles from the iron surface to interior were measured by field emission electron probe microanalyzer. The carbon diffusion coefficient in pure iron carburized with different magnetic field intensities was calculated according to the Fick's second law. It was found that the magnetic field intensity could obviously affect the carbon diffusion coefficient in pure iron in the γ- Fe temperature region, and the carbon diffusion coefficient decreased obviously with the enhancement of magnetic field intensity, when the magnetic field intensity was higher than 1 T, the carbon diffusion coefficient in field annealed specimen was less than half of that of the nonfield annealed specimen, further enhancing the magnetic field intensity, the carbon diffusion coefficient basically remains unchanged. The stiffening of lattice due to field-induced magnetic ordering was responsible for an increase in activation barrier for jumping carbon atoms. The greater the magnetic field intensity, the stronger the inhibiting effect of magnetic field on carbon diffusion.

Effect of Heat Treatment on Corrosion Behavior of Alloy 690 and Alloy 693 in Simulated Nuclear High-Level Waste Medium

Nickel-based alloys are being considered as candidate materials for the storage of high-level waste generated from the reprocessing of spent nuclear fuel. In the present investigation, Alloy 690 (UNS N06690) and Alloy 693 (UNS N06693) were assessed using the potentiodynamic anodic polarization technique for the corrosion behavior in the solution-annealed and sensitized conditions, in 3 M nitric acid (HNO3) and simulated high-level waste (HLW) at 25°C and 50°C. From the results of the investigation, it was found that the polarization curves for the solution-annealed specimens were characterized by a long passive range and low passivation current density, at 25°C. Increasing solution temperature to 50°C led to a corresponding increase in corrosion potential as well as passivation current density. The solution-annealed specimen showed improved corrosion resistance compared to the sensitized specimen in both media, for both alloys. Double-loop electrochemical potentiokinetic reactivation (DL-EPR) test was carried out for both solution-annealed and sensitized Alloy 690 and Alloy 693 in 0.5 M sulfuric acid (H2SO4) containing 0.0001 M potassium thiocyanate (KSCN), to measure the degree of sensitization (DOS). Microstructural examination was carried out by optical microscopy and scanning electron microscopy (SEM) after electrolytic etching. The results of the present investigation are discussed in the paper.

Effect of Bell-Type Annealing Process on Properties of SPCC Cold-Rolled Steel Sheet

This study simulated Bell-type annealing technology under laboratory conditions, and researched the effect of annealing time on the mechanical properties of SPCC cold-rolled steel sheet. The results indicate that the yield strength decreased with the extending of time; the plastic strain increases with the elongation of annealing time till a given time, and then decreased with the time extending; the cold-rolled specimen brittle fractured in tension while the annealed specimen shear fractured. Key words: microstructure mechanical properties Bell-type annealing SPCC cold-rolled steel sheet

Effect of Dissolved Hydrogen on the SCC Susceptibility of SUS316L Stainless Steel

The SSRT behavior in hydrogen dissolved hot water was investigated for cold worked SUS316L at a strain rate of 5 x 10-7/sec. The cold work to 75% thickness reduction of the as-annealed steel resulted in the hardness increase from 150 HV to 420 HV. The tensile yield stress of the cold worked specimens (CW=75%) was about 1000 MPa and the total tensile elongation was significantly reduced from 0.8% of annealed specimen to 0.14% of the 75%CW specimen. The results of EPR tests on SUS316L steel indicated that the EPR-DOS increased with increasing sensitization period at 700°C and decreased with increasing degree of cold work or reduction in thickness. In the water with hydrogen dissolution of 0.4 ppm, many IGSCC type cracks were nucleated on the specimen side surfaces, while the fractured surface was almost TGSCC. No such a SCC as observed in hydrogen dissolved water was observed after the test in oxygen dissolved water. The susceptibility to SCC increased with increasing hydrogen content in hot water. Cold work caused the reduction of the number of surface cracks and disappearance of IGSCC.

Residual Microstress of Austenitic Stainless Steel Due to Tensile Deformation

Material of the specimen was austenitic stainless steel (SUS316L). The specimens were given tensile plastic strains from 0% to 55%. The Vickers hardness of the specimen corresponded to the plastic strain. The residual macrostress was measured by Mn-Kα radiations. The residual macrostress of the annealed specimen had a small compression and changed into a tension after ten- sile plastic deformation. The specimen with 1% plastic strain showed the maximum tensile residual stress. To examine the dependency of the residual stress on the lattice plane, the residual microstress for each lattice plane was measured by hard synchrotron X-rays. The residual microstress was related with Young’s modulus which was calculated by Kro¨ ner model. A new method, 2θ-cos2 χ method, was proposed to solve the problem of coarse grains and it was excellent in comparison with the sin2 ψ method.