Geopolymer from Industrial Wastes: A Construction Material for 22ndCentury

Author(s):  
Pradeep Kumar Rana ◽  
Radha Raman Dash ◽  
Ratan Indu Ganguly
2018 ◽  
Vol 923 ◽  
pp. 130-134 ◽  
Author(s):  
Ing Kong ◽  
Kay Min Khoo ◽  
Oliver Buddrick ◽  
Abdul Aziz Baharuddin ◽  
Pooria Khalili

The aim of this study was to synthesize the geopolymer composites formed by two industrial wastes, namely red mud (RM) and saw dust (SD). SD was chemically treated with alkali for the removal of lignin and subsequently bleached, before forming composite with acid-modified RM. The composites were then characterized by using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermogravimetic analysis (TGA) and universal testing machine to study the morphology, chemical, thermal and mechanical properties. The FTIR spectrum showed that Si and Al from the raw materials played the major role in forming aluminosilicate geopolymer composites. The SEM images revealed that SD and RM particles aggregated to form fully condensed geopolymer matrices with high compressive strength of 8.3-138 MPa, which were comparable to Portland cement (compressive strength of 9-20.7 MPa).


2009 ◽  
Vol 15 (2) ◽  
pp. 149-157 ◽  
Author(s):  
John Kinuthia ◽  
David Snelson ◽  
Albinas Gailius

This paper reviews one way in which colliery spoil can be utilized in low‐strength concrete. Colliery Spoil (CS) (minestone), a by‐product of coal mining, is abundant in most parts of the world. It has potential as a construction material but it has not been fully appreciated. This is partly because colliery spoil is not easy to utilize, due a number of drawbacks. The major problems identified in attempts to utilize CS in construction include excessive wear, expansive behaviour, leaching of heavy metals and even radioactivity. Thus, to date, the bulk of the CS utilization is limited to isolated cases of highway embankments, backfilling of mines, quarries and other surface tips, or in extreme cases subjected to marine and other disposal. This paper reports on the scope of technological benefits of utilizing colliery spoil (CS) in low to medium strength concrete. There has been intermittent pursuance of the benefits of utilizing colliery spoil in the United Kingdom. However, there is still no well‐accepted and/or positive feedback on any colliery‐based technology and/or construction material, apart from that relating its use for bulk fill. This research was triggered by proximity of large supplies of both CS and slag in South Wales, UK, as well as the authors’ interest in advances in sustainable construction. Two fractions of colliery spoil were mixed in equal proportions and used for concrete where the binder was PC, or novel binders comprising of either Wastepaper Sludge Ash (WSA) or WSA combined in equal proportions with Ground Granulated Blastfurnace Slag (GGBS), themselves industrial wastes or by‐product materials. Compressive strength of compacted cube specimens was monitored for a period of up to 56 days of curing. Results indicate that the performance of systems incorporating CS and WSA were of very poor workability, but the resultant strength was within the low to medium category usable for blinding concrete and or for use in bound granular fill or foundations. Santrauka Anglies kasyklų atliekos yra potenciali ekologiška žaliava statybos dirbiniams gaminti, tačiau iki šiol neištirtos jos savybės ir naudojimo galimybės. Staripsnyje pateikti tyrimų rezultatai rodo, kaip, taikant specialias technologijas, savybes modifikuojančius priedus, kompozicines rišamąsias medžiagas, galima anglies kasyklų atliekas naudoti vidutinio stiprumo tvariam betonui gaminti.


2020 ◽  
Vol 70 (340) ◽  
pp. 234
Author(s):  
A. Beycioğlu ◽  
H. Mis ◽  
E. D. Güner ◽  
H. Güner ◽  
N. Gökçe

This study presents a new approach to the utilization of industrial by-products in construction materials by using fly ash (FA) in the production of glass fiber-reinforced polyester (GRP) pipe. The FA was substituted by 10% and 20% (by weight of sand) in the mixtures to produce GRP pipes of 350 mm in diameter and 6 m in length for testing. Stiffness modulus (SM), axial tensile strength (ATS), and hoop tensile strength (HTS) tests were conducted on the produced GRP pipes and their elasticity modulus (EM) values were also calculated. To observe the microstructure of the GRP pipes and the interfacial transition zone of the layers, SEM and microscopic analyses were performed. Furthermore, a strain-corrosion test was conducted to obtain information about long term-performance of samples. The results showed that the FA-filled GRP pipes were found to meet the requirements of the related standards, and that the use of FA in the GRP pipe industry may be an important alternative approach to the utilization of industrial wastes via effective recycling mechanisms.


Expansive soil deposits mostly appear in arid and semi-arid areas of the world and they pose severe difficulties to engineering constructions as they possess higher tendency to heave in the course of moist season and shrink at summer season. Construction in such highly expansive strata can be done by adopting ground modification techniques like soil stabilization, Vertical drains, inducing reinforcement in to soil etc., On the other hand with rapid industrial growth more quantity of industrial waste will be generated which will trigger several environmental issues when it is dumped in to environment. Utilization of industrial waste in construction industry without compromising in strength criteria is the best possible option for the engineers as the waste is used as construction material there will be no need for dumping yards, biodiversities can be protected, strength properties of the soil can be enhanced and hydraulic properties can also be modified by treating soil with industrial wastes. As the river sand can be partially replaced by some of the industrial wastes requirement for natural sand can be reduced which will not only economise the construction cost but also preserves the natural resources. The present study was carried out to assess the behaviour of coir pith treated black cotton soils. Due to increase in the natural fibres in many industries the waste produced from the coir industry is increasing, if proper care is not taken these waste may create severe effects on environment .To avoid disposal of this waste directly into environment it is better to use the waste in construction industry is a better option. But before adopting such practices proper studies are to be done to check whether these materials are suitable for treating the soils are not .In the present study by adding various proportions of coir pith Swell, strength characteristics of soil where compared for obtaining the optimum Replacement percentage


Author(s):  
Eti Tirumala Chakrapani ◽  
◽  
A M N Kashyap ◽  
G Anjaneyulu ◽  
M R Manikanta ◽  
...  

Concrete might be the maximum substantially used construction material in the global with approximately six billion tones being produced each year. It is best subsequent to water in phrases of in keeping with-capita consumption. However, environmental sustainability is at stake both in terms of damage due to the extraction of raw material and CO2 emission all through cement manufacture. This brought pressures on researchers for the discount of cement intake by means of partial substitute of cement by using supplementary materials. These materials may be obviously happening, industrial wastes or by way of-products that are less energy extensive. Fly ash and Ground Granulated Burnt Slag (GGBS) are selected specifically based totally on the standards of fee and their long lasting qualities., Not best this, Environmental pollution also can be decreased to a point due to the fact the emission of dangerous gases like carbon monoxide & carbon dioxide are very restricted. These substances (referred to as pozzalonas) when combined with calcium hydroxide, reveals cementitious compositions. Most commonly used pozzalonas are fly ash, silica fume, met kaolin, ground granulated blast furnace slag (GGBS). This wishes to look at the admixtures performance whilst combined with concrete so as to ensure a discounted existence cycle fee. The present research consists of three phases and reports the specializes in investigating characteristics of M35grade concrete .In the 1st phase the behavior of standard and SCM concrete (7.5%FA and 7.5%GGBS) of M35 grade specimens with different percentages of chemical admixtures curing with acids such as HCL. 2nd phase the same grade of specimens curing with Alkaline such as NaOH and in the 3rd phase the same grade of specimens curing with sulphate solution MgSO4 and finally assess the losses of mechanical properties and durability considerations of the concrete due to these conditions were reported.


2018 ◽  
Vol 934 ◽  
pp. 200-205
Author(s):  
Teewara Suwan ◽  
Boontarika Paphawasit ◽  
Xiang Ming Zhou ◽  
Pitiwat Wattanachai

In construction and building material sector, Lightweight Cement (LWC) has been receiving much more attention due to some of its advantages compared to other lightweight materials e.g. wood, foam and plastic. The method of incorporating tiny air bubbles into cementitious matrix for lightweight cement production is widely used as it could achieve good engineering properties with efficient production process. Conventional methods, Autoclaved Aerated Cement (AAC) and Portland cement-Cellular Lightweight Cement (CLC), use Portland cement as a main material which could lead to a huge disturbance to natural sources as well as release massive amount of carbon dioxide (CO2) to the atmosphere during its calcination. To achieve green construction material scheme, an attempt to utilize industrial wastes (by-products) as raw starting materials have been developing. One among those value-added approaches is OPC-less alkaline-activated cement from by-products, called Geopolymer technique. The main aim of this paper is to develop lightweight cement by using geopolymer technique with (CLC) method, called GP-CLC system, in order to optimize both economical aspects and engineering properties. The preliminary results show that the compressive strength of GP-CLC cannot reach that level of AAC system, but the strength was higher than the conventional OPC-CLC. The main challenge is that unit CO2 emission can be significantly reduce by using GP-CLC system as OPC consumption is replaced by by-product, fly ash.


2018 ◽  
Vol 53 (5) ◽  
pp. 603-611 ◽  
Author(s):  
Coraquetzali Magdaleno-López ◽  
José de Jesús Pérez-Bueno ◽  
Juan Carlos Flores-Segura ◽  
José Luis Reyes-Araiza ◽  
Maria Luisa Mendoza-López ◽  
...  

In this work, the development of a composite material with geopolymer and a high content of rice husks without heat treatment was investigated to create and characterize a low-cost composite made with agro-industrial wastes. The ratio used was about 12/88 wt./% of sol–gel and metakaolin related to rice husks. This kind of composite geopolymer was designed as both a construction material for load or aesthetic finishing. X-ray diffraction studies reveal that the composite has an amorphous phase and a crystalline one, which is typical of geopolymeric materials. The scanning electron microscopy showed that the geopolymeric matrix completely wrapped the rice husks. The composite material has a compressive strength close to some mortars with a value of about 110 kg/cm2 (10.8 MPa). Laser scanning confocal microscopy reveals that there is a difference of emission in the visible spectrum between the inner and outer sides of the rice husks, which corroborates that they have a different chemical composition. Differential scanning calorimetry analysis confirmed that the composite material has combined characteristics of its raw materials. X-ray diffraction studies show that metakaolin with sol–gel solutions had temperature-dependent interactions besides that, after the dehydroxylation, the composite material is mostly amorphous. The material of high content of rice husk bound by geopolymer could be applicable in various areas of the construction industry and finishing.


This research work presents the overview of geopolymer mortar application into the ferro cement panel with the incorporation of crumb rubber and Nano fly ash. The geopolymer mortar is prepared by using industrial wastes as a base material such as fly ash and ground granulated blast furnace slag (GGBFS) which generally helps to reduce the level of CO2 emission. Also, the recycled tyre crumb rubber is utilized as a sustainable innovative construction material which is used a partial substitution for sand upto 5% for enhancing the ductility without any strength degradation. These reduces land fill problems and ground water quality degradation problems. Crumb rubber has the ideal capacity to absorb energy from static and other kind of loads. The geopolymer binder preparation is done by utilizing material such as fly ash, GGBFS, alkaline liquid made of NaOH and Na2SiO3 , Nano fly ash. The Nano fly ash is used as an additive which helps in increasing the strength and durability of the element by its pore filling capability. This project aims to enhance the strength of fly ash based geopolymer mortar with the help of GGBFS incorporation. The molarity of alkaline activator, solution to binder ratio and silicate to hydroxide ratio is fixed as 12, 0.4 and 1.5 throughout the process. The mortar cubes and panels were heat cured under hot air oven at 80ᵒ C for 48 hours. The mechanical behavior of geopolymer mortar is assessed by compressive strength test water absorption test. The panel is made of high strength geopolymer mortar and expanded metal mesh with chicken mesh for obtaining higher energy absorption capacity with good deforming ability and less crack pronouncement. The investigation involves finding the initial crack load, ultimate failure load and residual flexural strength ratio. The results show that the tyre inclusion enhances the flexural strength of the ferro geopolymer panel by means of its ductile enhancing capacity


2021 ◽  
Vol 1 (2) ◽  
pp. 1-4
Author(s):  
Eti tirumala Chakrapani* ◽  
A M N Kashyap ◽  
Anjaneyulu, G ◽  
Manikanta M R

Concrete might be the maximum substantially used construction material in the global with approximately six billion tones being produced each year. It is best subsequent to water in phrases of in keeping with-capita consumption. However, environmental sustainability is at stake both in terms of damage due to the extraction of raw material and CO2 emission all through cement manufacture. This brought pressures on researchers for the discount of cement intake by means of partial substitute of cement by using supplementary materials. These materials may be obviously happening, industrial wastes or by way of-products that are less energy extensive. Fly ash and Ground Granulated Burnt Slag (GGBS) are selected specifically based totally on the standards of fee and their long lasting qualities., Not best this, Environmental pollution also can be decreased to a point due to the fact the emission of dangerous gases like carbon monoxide & carbon dioxide are very restricted. These substances (referred to as pozzalonas) when combined with calcium hydroxide, reveals cementitious compositions. Most commonly used pozzalonas are fly ash, silica fume, met kaolin, ground granulated blast furnace slag (GGBS). This wishes to look at the admixtures performance whilst combined with concrete so as to ensure a discounted existence cycle fee. The present research consists of three phases and reports the specializes in investigating characteristics of M35grade concrete .In the 1st phase the behavior of standard and SCM concrete (7.5%FA and 7.5%GGBS) of M35 grade specimens with different percentages of chemical admixtures curing with acids such as HCL. 2nd phase the same grade of specimens curing with Alkaline such as NaOH and in the 3rd phase the same grade of specimens curing with sulphate solution MgSO4 and finally assess the losses of mechanical properties and durability considerations of the concrete due to these conditions were reported.


Sign in / Sign up

Export Citation Format

Share Document