In the presented work, the optical and electrical properties of composite materials (PVA-PEG-Sr2O3) were measured, as the electrical properties were verified at various frequencies in range of 100 Hz-6 MHz. In addition, the experimental results showed that the increase in frequency causes a reduction in the dielectric loss (δ) and dielectric constant (ɛ), and there is an increase in ɛ due to the increase in the content of antimony oxide (Sr2O3). It increases with increasing frequency and decreases with increasing Sr2O3 content in PVA-PEG-Sr2O3 compounds, the result of the optical properties of the nanoparticles (PVA-PEG-Sr2O3) showed that the values transmittance and energy gap were reduced with the increases in the concentrations of Sr2O3 NPs, whereas the values related to extinction coefficient, absorption coefficient, optical conductivity, refractive index, and dielectric constant (imaginary, real) were increased with increase in the concentration of Sr2O3 NPs.