Vegetable oils and animal fats as raw materials for the manufacture of commercial lubricants

1992 ◽  
Vol 28 (4) ◽  
pp. 230-237 ◽  
Author(s):  
I. G. Fuks ◽  
A. Yu. Evdokimov ◽  
A. A. Dzhamalov ◽  
A. Luksa
Keyword(s):  
Vegetable Oils ◽  
Raw Materials ◽  
Animal Fats

scholarly journals Using Mustard Oil As an Ecological Additive to Petroleum Diesel Fuel

2016 ◽  
Vol 5 (5) ◽  
pp. 8-21
Author(s):  
Неверова ◽  
V. Neverova ◽  
Марков ◽  
V. Markov ◽  
Бовэнь ◽  
...  
Keyword(s):  
Diesel Engine ◽  
Vegetable Oils ◽  
Diesel Fuel ◽  
Diesel Engines ◽  
Alternative Fuels ◽  
Internal Combustion Engines ◽  
Raw Materials ◽  
Mustard Oil ◽  
Animal Fats ◽  
Alternative Sources

The depletion of oil fields and the deteriorating environmental situation leads to the need for the search of new alternative sources of energy. Actuality of the article due to the need for greater use of the alternative fuels in internal combustion engines is necessary. Fuels produced from vegetable oils and animal fats as advanced alternative fuels for diesel engines are considered. These fuels are produced from renewable raw materials and are characterized by good environmental qualities. Advantages of using fuels of vegetable origin as motor fuels are shown. Experimental research of diesel engine D-245.12S functioning on mixtures of diesel fuel and mustard oil of various percentage is given. One of the most wide spread vegetable oils in Russia is mustard oil. Possible ways of using mustard oil as fuel for a diesel engine are considered. An opportunity of improving characteristics of exhaust gases toxicity by using these mixtures as a fuel for automobile and tractor diesel engines is demonstrated.

scholarly journals Biodiesel Production Processes and Sustainable Raw Materials

Energies ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 4408 ◽  
Author(s):  
Ramos ◽  
Dias ◽  
Puna ◽  
Gomes ◽  
Bordado
Keyword(s):  
Vegetable Oils ◽  
Energy Security ◽  
Cost Reduction ◽  
First Generation ◽  
Raw Materials ◽  
Biodiesel Production ◽  
Environmental Concerns ◽  
Alkyl Esters ◽  
Animal Fats ◽  
Cooking Oils

Energy security and environmental concerns, related to the increasing carbon emissions, have prompted in the last years the search for renewable and sustainable fuels. Biodiesel, a mixture of fatty acids alkyl esters shows properties, which make it a feasible substitute for fossil diesel. Biodiesel can be produced using different processes and different raw materials. The most common, first generation, biodiesel is produced by methanolysis of vegetable oils using basic or acid homogeneous catalysts. The use of vegetable oils for biodiesel production raises serious questions about biodiesel sustainability. Used cooking oils and animal fats can replace the vegetable oils in biodiesel production thus allowing to produce a more sustainable biofuel. Moreover, methanol can be replaced by ethanol being totally renewable since it can be produced by biomass fermentation. The substitution of homogeneous catalyzed processes, nowadays used in the biodiesel industry, by heterogeneous ones can contribute to improve the biodiesel sustainability with simultaneous cost reduction. From the existing literature on biodiesel production, it stands out that several strategies can be adopted to improve the sustainability of biodiesel. A literature review is presented to underline the strategies allowing to improve the biodiesel sustainability.

scholarly journals REPLACEMENT OF HYDROGENATED FATS FOR VEGETABLE OIL IN THE COMPOSITION OF CONFECTIONERY

2019 ◽  
pp. 165-169
Author(s):  
Oksana Gumeniuk ◽  
◽  
Maria Кseniuk ◽  
Olga Denisko ◽  
Alina Kiriy ◽  
...  
Keyword(s):  
Vegetable Oil ◽  
Vegetable Oils ◽  
Raw Materials ◽  
Food Additives ◽  
Negative Effects ◽  
Animal Fats ◽  
Organoleptic Characteristics ◽  
Hydrogenated Fats ◽  
Physico Chemical ◽  
Confectionery Products

Urgency of the research. One of the trends in the development of the global confectionery market, which is linked to the care of consumers health, is the development of confectionery that do not contain hydrogenated fats. Their source in confectionery are margarines and confectionery fats, which are made on the basis of vegetable oils, in particular, palm and coconut or low-quality animal fats, which are waste meat and fish processing enterprises. A direct relationship between the increased content of trans-isomers in the products and diseases of the cardiovascular system, impaired metabolic processes, in turn, provokes the development of various diseases has been established. Therefore, search for alternative raw materials to replace the hydrogenated fats in the confectionery composition is a need. Target setting. In the process of searching for these types of raw materials, developers are faced with the problem of stabilizing the properties and quality of confectionery containing vegetable oils, namely, the binding and content of oil in dough and finished products. Most often, for this purpose, food additives of a stabilizing action based on high-molecular compounds - polysaccharides and proteins are used. The use of such additives leads to a departure from the traditional formulation of products, adding to the list of ingredients on the packaging of finished products is often in no way understandable to the consumer by E-codes and names. Actual scientific researches and issues analysis. The latest publications have been reviewed, which disclose the mechanisms of negative effects of trans-fatty acids on human health, which also indicate the need to limit the content of trans fats in food products and which suggest alternative sources of fatty materials for confectionery. Uninvestigated parts of general matters defining. Remains relevant search for ways to stabilize the structure of confectionery products, which contain vegetable oil in its composition, without the use of polysaccharides and protein stabilizers. The research objective. The aim of the study is the development of confectionery recipe without the use of hydrogenated fats. The statement of basic materials. Refined sunflower oil as an alternative to hydrogenated fats in the confectionery was used. To stabilize the dough and finished products, as well as to improve their organoleptic characteristics, potassium bitartrate was introduced into the formulation. The physico-chemical and organoleptic properties of finished products manufactured according to the developed recipe were studied. Conclusions. The proposed prescription composition of the confectionery with the use of vegetable oil in its composition allows to obtain finished products with good physico-chemical and organoleptic quality indicators.

Diesel Biofuels - Preparation, Characterization and Testing

2008 ◽  
Vol 59 (11) ◽  
Author(s):  
Cristina Dusescu ◽  
Anca Borcea ◽  
Vasile Matei ◽  
Ion Popa ◽  
Irina Gabriela Radulescu
Keyword(s):  
Vegetable Oils ◽  
Sunflower Oil ◽  
Raw Materials ◽  
Chemical Properties ◽  
Soya Bean ◽  
Production Unit ◽  
Physical And Chemical Properties ◽  
Physical And Chemical ◽  
And Chemical Properties

The present paper studies biodiesel samples preparation by transesterification and compares their physical and chemical properties (biofuels prepared from different raw materials - vegetable oils: sunflower oil, crocus oil and soya bean oil) and the biodegradability degree, as well as the possibilities of the integration of such production unit in industrial diagram of auto fuels production.

scholarly journals CERTIFICATION OF VEGETABLE OILS AND QUALITY CONTROL IN THE TECHNOLOGICAL PROCESS OF PRODUCTION

2019 ◽  
Vol 2019 (4) ◽  
pp. 119-126
Author(s):  
CH Bekmurotov ◽  
Keyword(s):  
Quality Control ◽  
Technological Process ◽  
Vegetable Oils ◽  
Raw Materials ◽  
Cottonseed Oil ◽  
Product Classification ◽  
Cotton Seeds ◽  
The Cost

The article reviewed the certification and quality control of the technological process for the production of vegetable oil. There is a procedure for packaging, quality control of products, determination of quality indicators and quality control of finished products. The procedure for using refined cottonseed oil and its varieties, the requirements for placement and storage of vegetable oils, as specified in the regulatory documents, the quality control of vegetable oils and other solutions for cottonseed oil are provided. The gas analyzer shows a solution for measuring the amount of solution by painting the tubes of a mixture of gas and air in oil. Detailed information on the production of vegetable oils, the cost of raw materials, the level of fat content of cotton seeds and the methods used to produce oil from cotton seeds. Methods for certification of vegetable oils, types of quality control, methods of testing and quality determination are presented. It was shown that the procedure for refined production of cottonseed oils and their types, as well as the state of the product classification of products based on the method of producing vegetable oils for consumer purposes, analysis of the sequence of refined oils and refining processes.

scholarly journals ANÁLISE DE PESTICIDAS ORGANOCLORADOS EM ÓLEOS VEGETAIS POR CROMATOGRAFIA GASOSA DE ALTA RESOLUÇÃO (HRGC)

2018 ◽  
Vol 35 (3) ◽  
pp. 189
Author(s):  
Eudécio Bonfim dos Santos Dias ◽  
Eliane Da Costa Vilela ◽  
Fernando Mauro Lanças
Keyword(s):  
Solid Phase Extraction ◽  
Vegetable Oil ◽  
Vegetable Oils ◽  
Concentration Level ◽  
Solid Phase ◽  
Agricultural Products ◽  
Phase Extraction ◽  
Human Diet ◽  
Animal Fats ◽  
Chemical Products

Vegetable oil were introduced in human diet in the last decade to change the use of animal fats. The chemical products althrought utilized in correct manner can cause residues in food bring to healt there be a necessity of a constant monitoring of the concentration level the several agricultural products. The answer to this necessity has motivated the development of several of a methodology for simultaneous analysis of aldrin, dieldrin, endrin and endosulfanin vegetable oils by HRGC, using solid phase extraction (SPE) using silica and XAD-2. The recovery was 70-110%.

scholarly journals Phenolation of vegetable oils

2011 ◽  
Vol 76 (4) ◽  
pp. 591-606 ◽  
Author(s):  
Mihail Ionescu ◽  
Zoran Petrovic
Keyword(s):  
Fatty Acids ◽  
Oleic Acid ◽  
Double Bond ◽  
Vegetable Oils ◽  
Raw Materials ◽  
Complex Mixture ◽  
Double Bonds ◽  
Triflic Acid ◽  
Model Compounds ◽  
Phenol Alkylation

Novel bio-based compounds containing phenols suitable for the synthesis of polyurethanes were prepared. The direct alkylation of phenols with different vegetable oils in the presence of superacids (HBF4, triflic acid) as catalysts was studied. The reaction kinetics was followed by monitoring the decrease of the double bond content (iodine value) with time. In order to understand the mechanism of the reaction, phenol was alkylated with model compounds. The model compounds containing one internal double bond were 9-octadecene and methyl oleate and those with three double bonds were triolein and high oleic safflower oil (82% oleic acid). It was shown that the best structures for phenol alkylation are fatty acids with only one double bond (oleic acid). Fatty acids with two double bonds (linoleic acid) and three double bonds (linolenic acid) lead to polymerized oils by a Diels Alder reaction, and to a lesser extent to phenol alkylated products. The reaction product of direct alkylation of phenol with vegetable oils is a complex mixture of phenol alkylated with polymerized oil (30-60%), phenyl esters formed by transesterification of phenol with triglyceride ester bonds (<10 %) and unreacted oil (30%). The phenolated vegetable oils are new aromatic-aliphatic bio-based raw materials suitable for the preparation of polyols (by propoxylation, ethoxylation, Mannich reactions) for the preparation of polyurethanes, as intermediates for phenolic resins or as bio-based antioxidants.

scholarly journals Pre-Treatment of Waste Frying Oils for Biodiesel Production

2015 ◽  
Vol 9 (7) ◽  
pp. 99 ◽  
Author(s):  
Nyoman Puspa Asri ◽  
Diah Agustina Puspita Sari
Keyword(s):  
Raw Materials ◽  
Batch Reactor ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
High Price ◽  
Composite Catalyst ◽  
Frying Oils ◽  
Animal Fats ◽  
Waste Frying Oils ◽  
Pre Treatment

Synthesis of biodiesel is a strategic step in overcoming energy scarcity and the environmental degradationcaused by the continuous use of the petroleum based energy. Biodiesel as an alternative fuel for diesel engine isproduced from renewable resources such as vegetable oils and animal fats. The main obstacle in the biodieselproduction is the high price of the raw materials, resulting in the price of biodiesel is not competitive comparedto the petroleum diesel. Therefore, the use of waste frying oils (WFO) is one way to reduce the cost of biodieselproduction, because of its availability and low price. In the present work, WFO from California Fried chicken(CFC) restaurants in Surabaya were used as feed stock for the biodiesel production. The experiments wereconducted using three steps of processes: pre-treatment of WFO, preparation of alumina based compositecatalyst CaO/KI/γ-Al2O3 and transesterification of treated WFO. WFO was treated by several types and variousamounts of activated adsobents. The treated WFO was transesterified in three neck glass batch reactor withrefluxed methanol using CaO/KI/γ-Al2O3. The results reveal that the best method for treating WFO is using 7.5%(wt. % to WFO) of coconut coir. Alumina based composite catalyst CaO/KI/γ-Al2O3 was very promising fortransesterification of WFO into biodiesel. The yield of biodiesel was 83% and obtained at 65ºC, 5 h of reactiontime, 1:18 of molar ratio WFO to methanol and 6% amount of catalyst.

Vegetable oils – raw materials for producing biodiesel

2021 ◽  
Vol 80 (2) ◽  
pp. 286-292
Author(s):  
T. Mamilov ◽  
◽  
G.S. Aitkaliyeva ◽  
A.B. Ismailova ◽  
M.A. Yelubay ◽  
...  
Keyword(s):  
Functional Groups ◽  
Vegetable Oils ◽  
Raw Materials ◽  
Chemical Properties ◽  
Biodiesel Fuel ◽  
Physical And Chemical Properties ◽  
Sunflower Oils ◽  
Transesterification Method ◽  
Physical And Chemical ◽  
And Chemical Properties

This paper presents the results of a study of the physical and chemical properties of samples of vegetable oils (sunflower, rapeseed, olive). It has been shown that the viscosity of oils varies from 41.4 to 61.7 cSt at a temperature of 40 ° C for olive and sunflower oils, respectively. The acid numbers of the oil samples were also determined, it was found that the lowest indicator is characteristic of sunflower oil. Pour points of oils also range from -3 to -16 ° C for olive and sunflower oils, respectively. Using the method of IR spectroscopy, functional groups in the composition of samples of vegetable oils were studied and it was shown that the composition of oils contains carbonyl and hydroxyl functional groups, indicating the presence of carboxylic acids. Based on studies of the physical and chemical properties of vegetable oils, it was found that sunflower, olive and rapeseed oils can serve as raw materials for the synthesis of biofuels based on them, since they contain free fatty acids. To obtain biodiesel fuel based on vegetable oils, it is planned to use the transesterification method in the presence of various catalysts (alkaline, acidic, and complex).

Modern methods for vegetable oils from various raw materials identification

2021 ◽  
pp. 56-59
Author(s):  
Лев Арсенович Оганесянц ◽  
Александр Львович Панасюк ◽  
Елена Ивановна Кузьмина ◽  
Дмитрий Александрович Свиридов ◽  
Михаил Юрьевич Ганин
Keyword(s):  
Fatty Acid Composition ◽  
Fatty Acid ◽  
Acid Composition ◽  
Vegetable Oils ◽  
Raw Materials ◽  
Research Approach ◽  
Gas Liquid Chromatography ◽  
The European Union ◽  
Depth Analysis ◽  
Modern Methods

Продукты масложировой промышленности играют важную роль в формировании рациона питания человека. При этом особое внимание отводится растительным маслам ввиду их высокой физиологической ценности. На сегодняшний день достаточно остро стоит вопрос о способах их идентификации. В связи с тем, что стоимость растительного масла в значительной степени обуславливается выбором сырья, наиболее распространенным видом фальсификации является внесение недобросовестными производителями в готовую продукцию более дешевых видов масел. Приведен анализ современных способов идентификации растительных масел из различного сырья. До настоящего времени метод газожидкостной хроматографии являлся основным при выявлении примесей посторонних жиров в продукции по ее жирнокислотному составу. Также для выявления фальсификатов могут быть использованы такие инструментальные методы, как ЯМР-спектроскопия, ИК-спектроскопия, а также метод изотопной масс-спектрометрии, который является наиболее перспективным. Особый научный интерес представляет идентификация растительных масел по их географическому месту происхождения. Основываясь на анализе литературы, показано, что наибольшее распространение при установлении региональной принадлежности масел получили исследования, направленные на изучение изотопных характеристик углерода (13С/12С), кислорода (18O/16O) и водорода (2H/1H) элементов, входящих в состав продукта, а также его жирнокислотного состава. Описаны преимущества комплексного подхода исследований, включающего в себя создание массива данных, состоящего из значений различных показателей, и его глубокий анализ с использованием статистических методов анализа. Математическая модель может быть усилена данными элементного профиля масла, изотопных характеристик отдельно взятых жирных кислот или содержанием фенольных соединений. Products of the fat and oil industry play an important role in shaping human diet. At the same time, special attention is paid to vegetable oils in view of their high physiological value. Today, the question of how to identify them is quite acute. Due to the fact that the cost of vegetable oil is largely determined by the choice of raw materials, the most common falsification type is the introduction of cheaper oils types into finished products by unscrupulous manufacturers. The authors provide an analysis of modern methods for identifying vegetable oils from various raw materials. It has been shown that the gas-liquid chromatography method is the main one in identifying products by their fatty acid composition and makes it possible to establish the presence of foreign fats impurities. Also, methods of isotope mass spectrometry, NMR spectroscopy, IR spectroscopy and electrophysical methods of analysis can be used to detect counterfeits. Of particular scientific interest is the vegetable oils identification by their geographical place of origin, which is very important for some countries of the European Union. Based on the analysis of literature, it has been shown that the most widespread in the regional oils affiliation establishing are researches aimed at researching the isotopic characteristics of carbon (13C/12C), oxygen (18O/16O) and hydrogen (2H/1H) of the elements that make up the product, and also its fatty acid composition. The advantages of an integrated research approach are described, including the creation of a data array consisting of the values of various indicators and its in-depth analysis using statistical analysis methods. The mathematical model can be strengthened by data on the elemental profile of the oil, isotopic characteristics of individual fatty acids, or the content of phenolic compounds.

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