Structural and thermodynamic factors in the adsorption process of anthocyanins from eggplant peel onto a carbon adsorbent

2021 ◽  
Author(s):  
Qiongjie Yang ◽  
Conghui Wang ◽  
Zhuo Zhao ◽  
Wei Wei ◽  
Jing Ma ◽  
...  
Keyword(s):  
Adsorption Process ◽  
Carbon Adsorbent ◽  
Thermodynamic Factors

scholarly journals Adsorption of nitrate, nitrite, and ammonium ions on carbon adsorbents

2017 ◽  
Vol 35 (7-8) ◽  
pp. 721-727 ◽  
Author(s):  
Andrzej Gierak ◽  
Iwona Łazarska
Keyword(s):  
Solid Phase Extraction ◽  
Extraction Method ◽  
Adsorption Process ◽  
Solid Phase ◽  
Carbon Adsorbent ◽  
Carbon Adsorbents ◽  
Phase Extraction ◽  
Ammonium Ions ◽  
Chromatography Method

This work presents the results of the investigations of the adsorption process of nitrate, nitrite, and ammonium ions on carbon adsorbent with the application of the solid phase extraction method to isolate and enrich the investigated ions from aqueous solutions of the concentration below 1 mg/L. For the determination of the concentration of the analyzed ions, we applied the ion chromatography method. The sorption capacity for the tested adsorbents as well as the efficiency of the enrichment of the investigated ions were determined.

scholarly journals Evaluation of Groundwater and Grey Water Contamination with Heavy Metals and Their Adsorptive Remediation Using Renewable Carbon from a Mixed-Waste Source

Water ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1802
Author(s):  
Taghrid S. Alomar ◽  
Mohamed A. Habila ◽  
Zeid A. Alothman ◽  
Najla AlMasoud ◽  
Saad Saeed Alqahtany
Keyword(s):  
Heavy Metals ◽  
Water Samples ◽  
Adsorption Process ◽  
Carbon Adsorbent ◽  
Freundlich Isotherm ◽  
Kinetic Studies ◽  
Ultrasonic Power ◽  
Order Kinetic ◽  
Adsorption Sites ◽  
Mixed Waste

The contamination of water sources with heavy metals is a serious challenge that humanity is facing worldwide. The aim of this work was to evaluate and remediate the metal pollution in groundwater and greywater resources from Riyadh, Saudi Arabia. In addition, we investigated the application of ultrasonic power before adsorption to assess the dispersion of renewable carbon from mixed-waste sources (RC-MWS) as an adsorbent and enhance the water purification process. The renewable carbon adsorbent showed high ability to adsorb Pb(II), Zn(II), Cu(II), and Fe(II) from samples of the actual water under study. The conditions for the remediation of water polluted with heavy metals by adsorptive-separation were investigated, including the pH of the adsorption solution, the concentration of the heavy metal(s) under study, and the competition at the adsorption sites. The enhanced adsorption process exhibited the best performance at a pH of 6 and room temperature, and with a contact time of 60 min. Kinetic studies showed that the pseudo-second-order kinetic model was fitted with the adsorption of Pb(II), Zn(II), Cu(II), and Fe(II) onto the RC-MWS. The adsorption data were well fitted by Langmuir isotherms. The Freundlich isotherm was slightly fitted in the cases of Cu(II), Zn(II), and Fe(II), but not in the cases of Pb(II). The developed adsorption process was successfully applied to actual water samples, including water samples from Deria and Mozahemia and samples from clothes and car washing centers in Riyadh city.

scholarly journals KINETIC STUDIES OF Cu ADSORPTION FROM SASIRANGAN LIQUID WASTE USING RICE HUSK ACTIVATED CARBON

Konversi ◽  
2021 ◽  
Vol 10 (2) ◽  
Author(s):  
Isna Syauqiah ◽  
Desi Nurandini ◽  
Nopi Stiyati Prihatini ◽  
Jamiyaturrasidah Jamiyaturrasidah
Keyword(s):  
Activated Carbon ◽  
Rice Husk ◽  
Adsorption Process ◽  
Chemical Elements ◽  
Chemical Activation ◽  
Liquid Waste ◽  
Carbon Adsorbent ◽  
Aquatic Organisms ◽  
Kinetic Studies ◽  
Physical Activation

The industry of sasirangan – traditional fabric of Banjar Tribe – has been one of prime commodities of South Kalimantan. The coloring process  in sasirangan production used a lot of chemical elements containing heavy metals  and its waste potentially pollute the environment. One of the heavy metal waste contained is copper (Cu) which is toxic to aquatic organisms and humans. The treatment for sasirangan liquid waste can be done by adsorption process using activated carbon as adsorbent. This study aims to determine the appropriate kinetic model for adsorption of Cu metal from sasirangan liquid waste using activated carbon adsorbent made from rice husks.The process was conducted by batch system with chemical and physical activation. Chemical activation was done by soaking the activated carbon of rice husk with HCl solution for 24 hours. While physical activation was carried out by burning in a furnace at 500̊C for 2 hours. The adsorption treatment was given on sasirangan waste samples with variations on contact time (30, 60 and 120 minutes). The results of kinetics study showed that the adsorption process of Cu from sasirangan liquid waste onto rice husk activated carbon adsorbent followed first-order reaction kinetics with a correlation coefficient value (R2) of 0.96 and adsorption rate constant (k1) of 0.0044 min-1.

scholarly journals Utilization of a novel activated carbon adsorbent from press mud of sugarcane industry for the optimized removal of methyl orange dye in aqueous solution

2019 ◽  
Vol 9 (8) ◽  
Author(s):  
Dominic Justine G. Rondina ◽  
Deanne V. Ymbong ◽  
Macvon Jovy M. Cadutdut ◽  
Jhon Ray S. Nalasa ◽  
Jonas B. Paradero ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Activated Carbon ◽  
Contact Time ◽  
Active Sites ◽  
Adsorption Process ◽  
Carbon Adsorbent ◽  
Press Mud ◽  
Methyl Orange Dye ◽  
Adsorbent Dose ◽  
Sugarcane Industry

Abstract In this study, a novel activated carbon adsorbent from the press mud of a sugarcane industry was used to remove methyl orange dye (MOD) from aqueous solution and was optimized via response surface methodology using the central composite design. The adsorbent was characterized by FTIR and SEM analysis and showed the presence of functional groups such as alcohols, nitriles, amides, alkane, alkyl halides, and alkenes, and it also showed fibrous surface morphological appearance. The factors affecting MOD adsorption, such as initial concentration, adsorbent dose, and contact time were examined, and optimal pH 2.0 to remove MOD in an aqueous solution that is found in various studies is also utilized. The results showed maximum MOD removal rate of 98.68% when the initial concentration, adsorbent dose, and contact time were optimally set as 24.17 mg/L, 0.5 g, and 20 min, respectively. The analysis of the equilibrium data revealed that MOD adsorption using press mud activated carbon best fitted the Langmuir isotherm (R2 = 0.96103) which implies monolayer adsorption process. Also, the kinetics of MOD adsorption using press mud activated carbon followed a pseudo-first-order model (R2 = 0.96096) which means that the active sites are proportional to the non-active sites during the adsorption process.

scholarly journals Removal of selected phthalates from aqueous solution by mesoporous-ordered carbon adsorbent

2017 ◽  
Vol 35 (7-8) ◽  
pp. 744-750 ◽  
Author(s):  
Katarzyna Jedynak ◽  
Dariusz Wideł ◽  
Jerzy Oszczudłowski
Keyword(s):  
Carbon Material ◽  
Solid Phase Microextraction ◽  
Adsorption Process ◽  
Solid Phase ◽  
Water Solution ◽  
Carbon Adsorbent ◽  
Static Method ◽  
Spectrometry Method ◽  
Templating Method ◽  
Mesoporous Carbon Material

In the present work adsorption of selected phthalates from the water samples on mesoporous carbon material was investigated. Carbon material was obtained by soft-templating method in the presence of citric acid. Adsorption process of phthalates was carried out from water solution using static method with sonication for process acceleration. Phthalates extraction from water phase, after adsorption on carbon material, was carried out using solid phase microextraction method. Extracted samples were analyzed using gas chromatography coupled with mass spectrometry method. Considering obtained experimental results it can be indicated that almost 100% of phthalates were adsorbed from water solutions. The efficiency of adsorption decreases with increasing molecular weight of phthalates.

scholarly journals CHANGE OF THERMODYNAMIC CHARACTERISTICS OF THE CARBON ADSORBENT FAS-3 AT ADSORPTION OF BENZENE

2020 ◽  
pp. 190-199
Author(s):  
Андрей Викторович Твардовский ◽  
Дмитрий Сергеевич Зайцев ◽  
Анатолий Алексеевич Фомкин
Keyword(s):  
Internal Energy ◽  
Adsorption Isotherms ◽  
Adsorption Process ◽  
Thermodynamic Characteristics ◽  
Carbon Adsorbent ◽  
Microporous Carbon ◽  
Equilibrium Conditions ◽  
Microporous Carbon Adsorbent ◽  
Adsorption Deformation ◽  
First Time

Впервые проведены комплексные исследования адсорбционной деформации - сорбострикции микропористого углеродного адсорбента ФАС-3 при адсорбции паров бензола из потока газа-носителя - азота в неравновесных условиях. Изучены изотермы адсорбции паров бензола микропористым углеродным адсорбентом ФАС-3 в равновесных условиях. Были представлены формулы и проведены расчеты изменений энтропии и внутренней энергии адсорбента в адсорбционном процессе. For the first time, complex studies were carried out on adsorption deformation - sorbostriction of the microporous carbon adsorbent FAS-3 at adsorption of benzene vapors from the flow of carrier gas - nitrogen in non-equilibrium conditions. Adsorption isotherms of benzene vapors by the microporous carbon adsorbent FAS-3 under equilibrium conditions has been studied. Calculations of changes in the entropy and internal energy of the adsorbent in the adsorption process were performed.

Purification of water contaminated with heavy metals by example of lead as promising material based on graphene nanostructures

2020 ◽  
pp. 34-43
Author(s):  
N. R. Memetov ◽  
◽  
A. V. Gerasimova ◽  
A. E. Kucherova ◽  
◽  
...  
Keyword(s):  
Adsorption Process ◽  
Phenol Formaldehyde ◽  
Phenol Formaldehyde Resin ◽  
Formaldehyde Resin ◽  
Parameter Estimates ◽  
Maximum Adsorption Capacity ◽  
Ecological Situation ◽  
Characteristic Parameters ◽  
Purification Of Water ◽  
Graphene Nanostructures

The paper evaluates the effectiveness of the use of graphene nanostructures in the purification of lead (II) ions to improve the ecological situation of water bodies. The mechanisms and characteristic parameters of the adsorption process were analyzed using empirical models of isotherms at temperatures of 298, 303, 313 and 323 K, which correspond to the following order (based on the correlation coefficient): Langmuir (0.99) > Temkin (0.97) > Dubinin – Radushkevich (0.90). The maximum adsorption capacity of the material corresponds to the range from 230 to 260 mg/g. We research the equilibrium at the level of thermodynamic parameter estimates, which indicates the spontaneity of the process, the endothermic nature and structure change of graphene modified with phenol-formaldehyde resin during the adsorption of lead (II) ions, leading to an increase in the disorder of the system.

Surface interaction of sweet potato peels (Ipomoea batata) with Cd(II) and Pb(II) ions in aqueous medium

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Aqueous Medium ◽  
Sweet Potato ◽  
Adsorption Process ◽  
Low Cost ◽  
Correlation Coefficients ◽  
Order Kinetic ◽  
Thermodynamic Evaluation ◽  
Dissociative Mechanism ◽  
Pseudo Second Order ◽  
Potato Peels

The removal of Cd(II) and Pb(II) ions from aqueous medium was studied using potato peels biomass. The adsorption process was evaluated using Atomic Absorption Spectrophotometer (AAS). The Vibrational band of the potato peels was studied using Fourier Transform Infrared Spectroscopy (FTIR). The adsorption process was carried out with respect to concentration, time, pH, particle size and the thermodynamic evaluation of the process was carried at temperatures of 30, 40, 50 and 60(0C), respectively. The FTIR studies revealed that the potato peels was composed of –OH, -NH, –C=N, –C=C and –C-O-C functional groups. The optimum removal was obtained at pH 8 and contact time of 20 min. The adsorption process followed Freundlich adsorption and pseudo second-order kinetic models with correlation coefficients (R2) greater than 0.900. The equilibrium adsorption capacity showed that Pb(II) ion was more adsorbed on the surface of the potato peels biomass versus Cd (II) ion (200.91 mg/g > 125.00 mg/g). The thermodynamic studies indicated endothermic, dissociative mechanism and spontaneous adsorption process. This study shows that sweet potato peels is useful as a low-cost adsorbent for the removal of Cd(II) and Pb(II) ions from aqueous medium.

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