Effects of temperature on the chemical composition of tars produced from the gasification of coconut and palm kernel shells using downdraft fixed-bed reactor

Fuel ◽  
2020 ◽  
Vol 265 ◽  
pp. 116910 ◽  
Author(s):  
Ahmad Zubair Yahaya ◽  
Mahendra Rao Somalu ◽  
Andanastuti Muchtar ◽  
Shaharin Anwar Sulaiman ◽  
Wan Ramli Wan Daud
Energy ◽  
2019 ◽  
Vol 175 ◽  
pp. 931-940 ◽  
Author(s):  
Ahmad Zubair Yahaya ◽  
Mahendra Rao Somalu ◽  
Andanastuti Muchtar ◽  
Shaharin Anwar Sulaiman ◽  
Wan Ramli Wan Daud

2019 ◽  
Vol 9 (2) ◽  
pp. 79-88 ◽  
Author(s):  
Arnaldo Verdeza-Villalobos ◽  
Yuhan Arley Lenis-Rodas ◽  
Antonio José Bula-Silvera ◽  
Jorge Mario Mendoza-Fandiño ◽  
Rafael David Gómez-Vásquez

This work analyzes the use of palm kernel shells (PKS) produced by the Colombian palm oil mill industry, for purposes of fueling a commercial downdraft fixed bed gasifier (Ankur Scientific WGB- 20) designed to operate with wood chips. Operational parameters such as hopper shaking time, ash removal time, and airflow were varied in order to get the highest gasifier performance, computed as the ratio between producer gas chemical energy over biomass feeding energy. Experiments were carried out following a half fraction experimental design 24-1. Since these parameters affect the equivalence ratio (ER), behavior indicators were analyzed as a function of ER. It was found that the shaking time and airflow had a significant effect on higher-heating-value (HHV) and process efficiency, while the removal time is not significant. The highest performance for palm shell was reached at ER=0.35, where the resulting gas HHV and process efficiencies were 5.04 MJ/Nm3 and 58%, respectively.


2020 ◽  
Vol 24 (1) ◽  
Author(s):  
Daniel Andres Quintero-Coronel ◽  
Edwin Edgardo Espinel-Blanco ◽  
Eder Norberto Flórez-Solano

A chemical equilibrium model for known outlet temperature of the products was carried out on a downdraft fixed bed gasifier. Biomass from oil palm kernel is used with proximate and ultimate analysis; the general gasification reaction takes into account the biomass moisture, the reaction products are formed by CH4, H2O, N2, CO, CO2 and H2. The model is described in detail and the equations are solved using the EES software. The model shows the results obtained for temperature ranges from 500 K to 1500 K and 1.0 atm. The model is validated by direct comparison of the gas composition with the results reported in the literature for similar conditions, obtaining favorable results.


2020 ◽  
Vol 12 (2) ◽  
pp. 304-311 ◽  
Author(s):  
Gaofeng Xu ◽  
Chengxinzhuo Jia ◽  
Zhengjun Shi ◽  
Ruijuan Liang ◽  
Chunhua Wu ◽  
...  

The ex-situ catalytic cracking of camelina oil using nickel loaded MCM-41 as catalyst at 450 °C in fixed bed reactor was studied. Results revealed that the yield, selectivity and chemical composition of the liquid products was improved by nickel loaded MCM-41 without affecting the crystalline structure of MCM-41. Moreover, the loaded nickel onto MCM-41 facilitated the cyclization, alkylation, aromatization, deoxygenation, isomerization and cracking reactions.


Author(s):  
Agus Budianto ◽  
Ayuni Rita Sari ◽  
Yohana Winda Monica ◽  
Erlinda Ningsih ◽  
Esthi Kusdarini

<table class="NormalTable"><tbody><tr><td width="200"><span class="fontstyle0">The development of population growth causes of fuels need increasing. Because of<br />that reason, it necessary to create alternative fuels which are friendly to the<br />environment to meet the fuels need in society. Fossil fuel is a non-renewable fuel.<br />Biofuel as an alternative fuel can be taken as a solution to solve this problem. The<br />reviewd aim was to determine the effect of raw materials used on yield product and<br />the different effects of temperature and catalysts on the yield of special materials<br />(gasoline, diesel, kerosene) biofuel. Biofuel production started from the<br />preparation of raw materials, catalylic, and catalytic cracking process using a<br />fixed bed reactor. Raw materials greatly affected yield product. The highest yield<br />products were being gotten from RBDPS raw materials of 93.29%. Biofuel from<br />used cooking oil and concentration of red sludge catalyst of 15% produced the<br />highest biofuel with gasoline compound of 73.86% and kerosene compound of<br />26.14%. Biofuel from camelina oil with ZSM-5-Zn catalyst concentration of 30%<br />produced the highest gasoline yield of 75.65%.</span></td></tr></tbody></table>


2019 ◽  
Vol 13 (4) ◽  
pp. 5791-5803 ◽  
Author(s):  
R. Ahmad ◽  
M. A. M. Ishak ◽  
K. Ismail ◽  
N. N. Kassim

In this study, microwave irradiation pretreatment of palm kernel shell (PKS) and Mukah Balingian (MB) coal was carried out in a fixed bed reactor. The effect of microwave power and processing time was investigated on pretreated PKS and MB coal characteristic. Then, the co-gasification of microwave pretreated PKS and MB coal was conducted to examine the effect of product yield and gases composition. The results showed that, the characteristics of pretreated sample was improved with increasing microwave power and processing time. The volatile matter, oxygen content and O/C ratio of pretreated sample decreased, while the calorific value, fixed carbon and carbon content of pretreated sample increased with increasing microwave power. The carbon content of pretreated PKS was closed to the untreated MB coal with comparable calorific value was obtained. The microwave power level of 450 W and processing time of 8 min were appropriate to upgrade the PKS and MB coal for co-gasification. The pretreated sample produced higher gas yield and lower tar and char yield than the untreated sample during co-gasification. This result was due to low moisture and oxygenated compound of pretreated feedstock made it appropriate to be converted in co-gasification. Moreover, co-gasification of pretreated sample produced the higher H2+CO and CH4 and lower CO2 composition than untreated sample. Thus, it can be concluded that the microwave irradiation pretreatment on PKS and MB coal performed the significant impact on the product distribution and composition during the co-gasification.


2018 ◽  
Vol 35 (6) ◽  
pp. 515-524 ◽  
Author(s):  
Yean-Ouk Jeong ◽  
Se-Won Park ◽  
Sang-Yeop Lee ◽  
Gun-Ho Han ◽  
Won-Seok Yang ◽  
...  

2011 ◽  
Vol 25 (11) ◽  
pp. 5242-5249 ◽  
Author(s):  
Xi Zeng ◽  
Yin Wang ◽  
Jian Yu ◽  
Shisheng Wu ◽  
Jiangze Han ◽  
...  

2019 ◽  
Vol 85 ◽  
pp. 106-120 ◽  
Author(s):  
G. Vonk ◽  
B. Piriou ◽  
P. Felipe Dos Santos ◽  
D. Wolbert ◽  
G. Vaïtilingom

Author(s):  
Taye Stephen Mogaji ◽  
Emmanuel O. Moses ◽  
Emmanuel Tolulope Idowu ◽  
Tien-Chien Jen

Biochar has been proved to be effective in soil amelioration applications, carbon sequestration and also reduce GHG emissions which causes global warming. Biomass stands a greater chance of prevailing as a good source for the production of biochar, which in turn can be a solution for waste management. However, pyrolysis conditions for biochar production, together with feedstock characteristics largely control the physical and chemical properties of the yield biochar product. In this study, investigation on thermal degradation conditions effects on biochar production is carried out. Bio-char was produced using 35.3 litres fixed bed reactor from pyrolysis of Corn Cob (CC), Palm Kernel Shell (PKS) and Sugarcane Bagasse (SB) at temperatures ranging from 100°C to 500°C. The feedstock was also blended in ratio to each other and pyrolyzed to 250°C and 400°C. The analyzed results showed that higher pyrolysis temperatures resulted in lower bio-char mass recovery, higher ash contents, decreased fixed carbon and moisture content. Product characterization also showed that the produced biochar, independent of biomass waste type contained negligible amount of Sulphur (S) and Nitrogen which resulted in lower emission of SO2 and NO2 during the combustion process, this behaviour is observed to be more pronounced with the blended biochar samples investigated in this study as a result, the obtained bio-char product can be used directly for heating purposes. ANOVA test results for both volatile matter and Ash content of the produced biochar revealed that the P-value is greater than 0.01 independent of the biochar samples considered whereas for the fixed carbon of the same bio-char samples, P-value less than 0.01 is attained. These results show how control of biomass pyrolysis conditions can improve biochar chemical properties consequently biochar produced from biomass wastes could be a suitable candidate for alternative energy fuels in terms of quality and environment concern.


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