The formation of desilication products in the presence of kaolinite and halloysite – The role of surface area

2021 ◽  
pp. 105643
Author(s):  
Jose F. Gomes ◽  
Michael Davies ◽  
Peter Smith ◽  
Franca Jones
Keyword(s):  
Surface Area

Elucidating the Origin of the Toxicity of Nano-CeO2 to Chlorella pyrenoidosa：the Role of Specific Surface Area and Chemical Composition

2021 ◽  
Author(s):  
Changjian Xie ◽  
Yuhui Ma ◽  
Peng Zhang ◽  
Junzhe Zhang ◽  
Xiaowei Li ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Aquatic Environment ◽  
Cerium Dioxide ◽  
Environmental Application ◽  
Ecotoxicological Effects

With the increasing environmental application and discharge of nano cerium dioxide (nano-CeO2), it is urgent to fully understand its ecotoxicological effects on the aquatic environment. This study for the first...

scholarly journals Engineering Mesoporous NiO with Enriched Electrophilic Ni3+ and O− toward Efficient Oxygen Evolution

Catalysts ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 310 ◽  
Author(s):  
Xiu Liu ◽  
Zhi-Yuan Zhai ◽  
Zhou Chen ◽  
Li-Zhong Zhang ◽  
Xiu-Feng Zhao ◽  
...  
Keyword(s):  
Surface Area ◽  
Oxygen Evolution ◽  
Low Cost ◽  
Large Surface Area ◽  
Nucleophilic Attack ◽  
Title Reaction ◽  
Highly Active ◽  
Decomposition Of Water ◽  
Uniform Mesopores

Tremendous efforts have been devoted to develop low-cost and highly active electrocatalysts for oxygen evolution reaction (OER). Here, we report the synthesis of mesoporous nickel oxide by the template method and its application in the title reaction. The as-prepared mesoporous NiO possesses a large surface area, uniform mesopores, and rich surface electrophilic Ni3+ and O− species. The overpotential of meso-NiO in alkaline medium is 132 mV at 10 mA cm−1 and 410 mV at 50 mA cm−1, which is much smaller than that of the other types of NiO samples. The improvement in the OER activity can be ascribed to the synergy of the large surface area and uniform mesopores for better mass transfer and high density of Ni3+ and O− species favoring the nucleophilic attack by OH− to form a NiOOH intermediate. The reaction process and the role of electrophilic Ni3+ and O− were discussed in detail. This results are more conducive to the electrochemical decomposition of water to produce hydrogen fuel as a clean and renewable energy.

The important role of surface area in the electrochemical behaviour of RuO2 electrodes

1977 ◽  
Vol 81 (2) ◽  
pp. 391-394 ◽  
Author(s):  
Laurence D. Burke ◽  
Oliver J. Murphy ◽  
John F. O'Neill
Keyword(s):  
Surface Area ◽  
Electrochemical Behaviour

scholarly journals The role of clay content and mineral surface area for soil organic carbon storage in an arable toposequence

2021 ◽  
Author(s):  
Steffen A. Schweizer ◽  
Carsten W. Mueller ◽  
Carmen Höschen ◽  
Pavel Ivanov ◽  
Ingrid Kögel-Knabner
Keyword(s):  
Organic Carbon ◽  
Surface Area ◽  
Agricultural Soils ◽  
Mineral Soil ◽  
Clay Content ◽  
Clay Soils ◽  
Mineral Surface ◽  
Mineral Surface Area ◽  
The Impact

AbstractCorrelations between organic carbon (OC) and fine mineral particles corroborate the important role of the abundance of soil minerals with reactive surfaces to bind and increase the persistence of organic matter (OM). The storage of OM broadly consists of particulate and mineral-associated forms. Correlative studies on the impact of fine mineral soil particles on OM storage mostly combined data from differing sites potentially confounded by other environmental factors. Here, we analyzed OM storage in a soil clay content gradient of 5–37% with similar farm management and mineral composition. Throughout the clay gradient, soils contained 14 mg OC g−1 on average in the bulk soil without showing any systematic increase. Density fractionation revealed that a greater proportion of OC was stored as occluded particulate OM in the high clay soils (18–37% clay). In low clay soils (5–18% clay), the fine mineral-associated fractions had up to two times higher OC contents than high clay soils. Specific surface area measurements revealed that more mineral-associated OM was related to higher OC loading. This suggests that there is a potentially thicker accrual of more OM at the same mineral surface area within fine fractions of the low clay soils. With increasing clay content, OM storage forms contained more particulate OC and mineral-associated OC with a lower surface loading. This implies that fine mineral-associated OC storage in the studied agricultural soils was driven by thicker accrual of OM and decoupled from clay content limitations.

scholarly journals MiR-26a-5p inhibits GSK3β expression and promotes cardiac hypertrophy in vitro

PeerJ ◽  
2020 ◽  
Vol 8 ◽  
pp. e10371
Author(s):  
Liqun Tang ◽  
Jianhong Xie ◽  
Xiaoqin Yu ◽  
Yangyang Zheng
Keyword(s):  
Cell Surface ◽  
Cardiac Hypertrophy ◽  
Surface Area ◽  
Myocardial Cell ◽  
Immunofluorescence Staining ◽  
Cell Surface Area ◽  
Direct Target

Background The role of miR-26a-5p expression in cardiac hypertrophy remains unclear. Herein, the effect of miR-26a-5p on cardiac hypertrophy was investigated using phenylephrine (PE)-induced cardiac hypertrophy in vitro and in a rat model of hypertension-induced hypertrophy in vivo. Methods The PE-induced cardiac hypertrophy models in vitro and vivo were established. To investigate the effect of miR-26a-5p activation on autophagy, the protein expression of autophagosome marker (LC3) and p62 was detected by western blot analysis. To explore the effect of miR-26a-5p activation on cardiac hypertrophy, the relative mRNA expression of cardiac hypertrophy related mark GSK3β was detected by qRT-PCR in vitro and vivo. In addition, immunofluorescence staining was used to detect cardiac hypertrophy related mark α-actinin. The cell surface area was measured by immunofluorescence staining. The direct target relationship between miR-26a-5p and GSK3β was confirmed by dual luciferase report. Results MiR-26a-5p was highly expressed in PE-induced cardiac hypertrophy. MiR-26a-5p promoted LC3II and decreased p62 expression in PE-induced cardiac hypertrophy in the presence or absence of lysosomal inhibitor. Furthermore, miR-26a-5p significantly inhibited GSK3β expression in vitro and in vivo. Dual luciferase report results confirmed that miR-26a-5p could directly target GSK3β. GSK3β overexpression significantly reversed the expression of cardiac hypertrophy-related markers including ANP, ACTA1 and MYH7. Immunofluorescence staining results demonstrated that miR-26a-5p promoted cardiac hypertrophy related protein α-actinin expression, and increased cell surface area in vitro and in vivo. Conclusion Our study revealed that miR-26a-5p promotes myocardial cell autophagy activation and cardiac hypertrophy by regulating GSK3β, which needs further research.

scholarly journals Numerical analysis of the chemical kinetic mechanisms of ozone depletion and halogen release in the polar troposphere

2013 ◽  
Vol 13 (9) ◽  
pp. 24171-24222 ◽  
Author(s):  
L. Cao ◽  
H. Sihler ◽  
U. Platt ◽  
E. Gutheil
Keyword(s):  
Boundary Layer ◽  
Surface Area ◽  
Ozone Depletion ◽  
Reaction Rates ◽  
The Arctic ◽  
Strong Impact ◽  
Reactive Surface ◽  
A Value ◽  
Halogen Species

Abstract. In recent years, the role of halogen species (e.g. Br, Cl) in the troposphere of polar regions is investigated after the discovery of their importance for boundary layer ozone destruction in the polar spring. Halogen species take part in an auto-catalytic chemical cycle including key self reactions. In this study, several chemical reaction schemes are investigated, and the importance of specific reactions and their rate constants is identified by a sensitivity analysis. A category of heterogeneous reactions related to HOBr activate halogen ions from sea salt aerosols, fresh sea ice or snow pack, driving the "bromine explosion". In the Arctic, a small amount of NOx may exist, which comes from nitrate contained in the snow, and this NOx may have a strong impact on ozone depletion. The heterogeneous reaction rates are parameterized by considering the aerodynamic resistance, a reactive surface ratio, β, i.e. ratio of reactive surface area to total ground surface area, and the boundary layer height, Lmix. It is found that for β = 1, the ozone depletion process starts after five days and lasts for 40 h for Lmix = 200 m. Ozone depletion duration becomes independent of the height of the boundary layer for about β≥20, and it approaches a value of two days for β=100. The role of nitrogen and chlorine containing species on the ozone depletion rate is studied. The calculation of the time integrated bromine and chlorine atom concentrations suggests a value in the order of 103 for the [Br] / [Cl] ratio, which reveals that atomic chlorine radicals have minor direct influence on the ozone depletion. The NOx concentrations are influenced by different chemical cycles over different time periods. During ozone depletion, the reaction cycle involving the BrONO2 hydrolysis is dominant. A critical value of 0.002 of the uptake coefficient of the BrONO2 hydrolysis reaction at the aerosol and saline surfaces is identified, beyond which the existence of NOx species accelerate the ozone depletion event – for lower values, deceleration occurs.

scholarly journals Role of intertidal wetlands for tidal and storm tide attenuation along a confined estuary: a model study

2015 ◽  
Vol 3 (5) ◽  
pp. 3181-3224 ◽  
Author(s):  
S. Smolders ◽  
Y. Plancke ◽  
S. Ides ◽  
P. Meire ◽  
S. Temmerman
Keyword(s):  
Surface Area ◽  
Wave Attenuation ◽  
Spring Tide ◽  
Storm Surges ◽  
High Water ◽  
Water Levels ◽  
Storm Tide ◽  
Flood Risks ◽  
Model Study

Abstract. Coastal lowlands and estuaries are subjected to increasing flood risks during storm surges due to global and regional changes. Tidal wetlands are increasingly valued as effective natural buffers for storm surges by dissipating wave energy and providing flood water storage. While previous studies focused on flood wave attenuation within and behind wetlands, this study focuses on the effects of estuarine wetland properties on the attenuation of a storm tide that propagates along the length of an estuary. Wetland properties including elevation, surface area, and location within the estuary were investigated using a numerical model of the Scheldt estuary (Belgium, SW Netherlands). For a spring tide lower wetland elevations result in more attenuation of high water levels along the estuary, while for a higher storm tide higher elevations provide more attenuation compared to lower wetland elevations. For spring and storm tide a arger wetland surface area results in a better attenuation along the estuary up to a threshold wetland size for which larger wetlands do not further contribute to more attenuation. Finally a wetland of the same size and elevation, but located more upstream in the estuary, can store a larger proportion of the local flood volume and therefore has a larger attenuating effect on upstream high water levels. With this paper we aim to contribute towards a better understanding and wider implementation of ecosystem-based adaptation to increasing estuarine flood risks associated with storms.

Comparison of gastrointestinal absorption between human and rat: the role of intestinal absorptive surface area and unstirred aqueous layer

2002 ◽  
Vol 40 (11) ◽  
pp. 1727-1728
Author(s):  
Ta C Wu ◽  
Chien Ma ◽  
Hyunyoung Jeong ◽  
Hsuan-Ming Yao ◽  
Win L Chiou
Keyword(s):  
Surface Area ◽  
Gastrointestinal Absorption ◽  
Aqueous Layer

Role of ZnO Nanoparticles for improvement of Antibacterial Activity in Food Packaging

2021 ◽  
pp. 128-131
Author(s):  
Saira Sehar ◽  
Amiza Amiza ◽  
I. H Khan
Keyword(s):  
Antimicrobial Activity ◽  
Particle Size ◽  
Surface Area ◽  
Zno Nanoparticles ◽  
Food Packaging ◽  
Antimicrobial Agents ◽  
Uv Light ◽  
Zno Nps ◽  
Long Time

Nanotechnology advancement leads to development of antimicrobial agents like ZnO nanoparticles. These nanoparticle have their main applications in food packaging. when these nanoparticles incorporate into the food surface, it will kill all bacterias residing on the surface and food become free of bacteria. In this way, food can be stored for a long time because its shelf life is improved. Antimicrobial activity of ZnO nanoparticles can be improved by increasing surface area, reducing particle size and large concentration of ZnO –NPS. Antimicrobial activity increases by increasing intensity of UV light. As UV light fall on ZnO nanoparticles, it increases ZnO surface area and hence anrtimicrobial activity will be increased. Exact mechanism of Antimicrobial activity is still unknown but some processes have been presented.

Sign in / Sign up

Export Citation Format

Share Document