A sustainable approach for removal of microplastics from water matrix using Colloidal Gas Aphrons: New insights on flotation potential and interfacial mechanism

2021 ◽  
pp. 130198
Author(s):  
Priyanka M ◽  
Saravanakumar M P
Keyword(s):  
Water Matrix ◽  
Colloidal Gas Aphrons

scholarly journals Oxidation of Citalopram with Sodium Hypochlorite and Chlorine Dioxide: Influencing Factors and NDMA Formation Kinetics

Molecules ◽  
2019 ◽  
Vol 24 (17) ◽  
pp. 3065
Author(s):  
Juan Lv ◽  
Yan Wang ◽  
Na Li
Keyword(s):  
Sodium Hypochlorite ◽  
Chlorine Dioxide ◽  
Wastewater Treatment Plants ◽  
Ph Value ◽  
High Reactivity ◽  
Secondary Effluent ◽  
Water Matrix ◽  
Formation Kinetics ◽  
Operational Variables ◽  
Two Stages

The highly prescribed antidepressant, citalopram, as one of newly emerging pollutants, has been frequently detected in the aquatic environment. Citalopram oxidation was examined during sodium hypochlorite (NaOCl) and chlorine dioxide (ClO2) chlorination processes since conventional wastewater treatment plants cannot remove citalopram effectively. Citalopram has been demonstrated to form N-nitrosodimethylamine (NDMA) during chlorination in our previous study. Further investigation on NDMA formation kinetics was conducted in the present study. Influences of operational variables (disinfectant dose, pH value) and water matrix on citalopram degradation, as well as NDMA generation, were evaluated. The results indicated high reactivity of citalopram with NaOCl and ClO2. NDMA formation included two stages during CIT oxidation, which were linear related with reaction time. NaOCl was more beneficial to remove CIT, but it caused more NDMA formation. Increasing disinfectant dosage promoted citalopram removal and NDMA formation. However, no consistent correlation was found between citalopram removal and pH. Contrary to the situation of citalopram removal, NDMA generation was enhanced when citalopram was present in actual water matrices, especially in secondary effluent. DMA, as an intermediate of citalopram chlorination, contributed to NDMA formation, but not the only way.

scholarly journals Research on the Performance of Solar Aided Power Generation System Based on Annular Fresnel Solar Concentrator

Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1579
Author(s):  
Heng Zhang ◽  
Na Wang ◽  
Kai Liang ◽  
Yang Liu ◽  
Haiping Chen
Keyword(s):  
Power Generation ◽  
High Efficiency ◽  
Low Cost ◽  
Economic Index ◽  
Partial Replacement ◽  
Solar Concentrator ◽  
Small Disturbance ◽  
Step Size ◽  
Water Matrix ◽  
Cost Utilization

A solar-aided power generation (SAPG) system effectively promotes the high efficiency and low cost utilization of solar energy. In this paper, the SAPG system is represented by conventional coal-fired units and an annular Fresnel solar concentrator (AFSC) system. The annular Fresnel solar concentrator system is adopted to generate solar steam to replace the extraction steam of the turbine. According to the steam–water matrix equation and improved Flugel formula, the variable conditions simulation and analysis of the thermo-economic index were proposed by Matlab. Furthermore, in order to obtain the range of small disturbance, the method of partial replacement is used, that is, the extraction steam of the turbine is replaced from 0 to 100% with a step size of 20%. In this work, a SAPG system is proposed and its thermo-economic index and small disturbance scope are analyzed. The results show that the SAPG system is energy-saving, and the application scope of small disturbance is related to the quantity of the extraction steam and evaluation index.

scholarly journals Performance of Iron-Functionalized Activated Carbon Catalysts (Fe/AC-f) on CWPO Wastewater Treatment

Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 337
Author(s):  
Sara Mesa Medina ◽  
Ana Rey ◽  
Carlos Durán-Valle ◽  
Ana Bahamonde ◽  
Marisol Faraldos
Keyword(s):  
Wastewater Treatment ◽  
Activated Carbon ◽  
Landfill Leachate ◽  
Surface Composition ◽  
Treatment Plant ◽  
Reaction Medium ◽  
Pollutant Removal ◽  
Operating Conditions ◽  
Water Matrix ◽  
The Stability

Two commercial activated carbon were functionalized with nitric acid, sulfuric acid, and ethylenediamine to induce the modification of their surface functional groups and facilitate the stability of corresponding AC-supported iron catalysts (Fe/AC-f). Synthetized Fe/AC-f catalysts were characterized to determine bulk and surface composition (elemental analysis, emission spectroscopy, XPS), textural (N2 isotherms), and structural characteristics (XRD). All the Fe/AC-f catalysts were evaluated in the degradation of phenol in ultrapure water matrix by catalytic wet peroxide oxidation (CWPO). Complete pollutant removal at short reaction times (30–60 min) and high TOC reduction (XTOC = 80 % at ≤ 120 min) were always achieved at the conditions tested (500 mg·L−1 catalyst loading, 100 mg·L−1 phenol concentration, stoichiometric H2O2 dose, pH 3, 50 °C and 200 rpm), improving the results found with bare activated carbon supports. The lability of the interactions of iron with functionalized carbon support jeopardizes the stability of some catalysts. This fact could be associated to modifications of the induced surface chemistry after functionalization as a consequence of the iron immobilization procedure. The reusability was demonstrated by four consecutive CWPO cycles where the activity decreased from 1st to 3rd, to become recovered in the 4th run. Fe/AC-f catalysts were applied to treat two real water matrices: the effluent of a wastewater treatment plant with a membrane biological reactor (WWTP-MBR) and a landfill leachate, opening the opportunity to extend the use of these Fe/AC-f catalysts for complex wastewater matrices remediation. The degradation of phenol spiked WWTP-MBR effluent by CWPO using Fe/AC-f catalysts revealed pH of the reaction medium as a critical parameter to obtain complete elimination of the pollutant, only reached at pH 3. On the contrary, significant TOC removal, naturally found in complex landfill leachate, was obtained at natural pH 9 and half stoichiometric H2O2 dose. This highlights the importance of the water matrix in the optimization of the CWPO operating conditions.

scholarly journals Development of a Water Matrix Certified Reference Material for Volatile Organic Compounds Analysis in Water

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4370
Author(s):  
Liping Fang ◽  
Linyan Huang ◽  
Gang Yang ◽  
Yang Jiang ◽  
Haiping Liu ◽  
...  
Keyword(s):  
Volatile Organic Compounds ◽  
Reference Material ◽  
Organic Compounds ◽  
Certified Reference Material ◽  
Pure Water ◽  
Term Stability ◽  
Long Term Stability ◽  
Water Matrix ◽  
Volatile Organic

Water matrix certified reference material (MCRM) of volatile organic compounds (VOCs) is used to provide quality assurance and quality control (QA/QC) during the analysis of VOCs in water. In this research, a water MCRM of 28 VOCs was developed using a “reconstitution” approach by adding VOCs spiking, methanol solution into pure water immediately prior to analysis. The VOCs spiking solution was prepared gravimetrically by dividing 28 VOCs into seven groups, then based on ISO Guide 35, using gas chromatography-mass spectrometry (GC-MS) to investigate the homogeneity and long-term stability. The studies of homogeneity and long-term stability indicated that the batch of VOCs spiking solution was homogeneous and stable at room temperature for at least 15 months. Moreover, the water MCRM of 28 VOCs was certified by a network of nine competent laboratories, and the certified values and expanded uncertainties of 28 VOCs ranged from 6.2 to 17 μg/L and 0.5 to 5.3 μg/L, respectively.

Modeling of iron activated persulfate oxidation treating reactive azo dye in water matrix

2011 ◽  
Vol 172 (1) ◽  
pp. 109-121 ◽  
Author(s):  
Hrvoje Kusic ◽  
Igor Peternel ◽  
Sime Ukic ◽  
Natalija Koprivanac ◽  
Tomislav Bolanca ◽  
...  
Keyword(s):  
Azo Dye ◽  
Persulfate Oxidation ◽  
Water Matrix ◽  
Activated Persulfate

A novel rhodamine-based colorimetric and fluorescent sensor for Hg2+ in water matrix and living cell

2016 ◽  
Vol 232 ◽  
pp. 28-36 ◽  
Author(s):  
Miaomiao Hong ◽  
Xiangyu Lu ◽  
Yuhua Chen ◽  
Dongmei Xu
Keyword(s):  
Living Cell ◽  
Fluorescent Sensor ◽  
Water Matrix

Cellular and Chemical Events During Enamel Maturation

1998 ◽  
Vol 9 (2) ◽  
pp. 128-161 ◽  
Author(s):  
C.E. Smith
Keyword(s):  
Crystal Growth ◽  
Driving Forces ◽  
Morphological Changes ◽  
Matrix Proteins ◽  
Secretory Product ◽  
Water Matrix ◽  
Mineralized Tissues ◽  
Progressive Growth ◽  
Chemical Events ◽  
Protein Rich

This review focuses on the process of enamel maturation, a series of events associated with slow, progressive growth in the width and thickness of apatitic crystals. This developmental step causes gradual physical hardening and transformation of soft, newly formed enamel into one of the most durable mineralized tissues produced biologically. Enamel is the secretory product of specialized epithelial cells, the ameloblasts, which make this covering on the crowns of teeth in two steps. First, they roughly "map out" the location and limits (overall thickness) of the entire extracellular layer as a protein-rich, acellular, and avascular matrix filled with thin, ribbon-like crystals of carbonated hydroxyapatite. These initial crystals are organized spatially into rod and interrod territories as they form, and rod crystals are lengthened by Tomes' processes in tandem with appositional movement of ameloblasts away from the dentin surface. Once the full thickness of enamel has been formed, ameloblasts initiate a series of repetitive morphological changes at the enamel surface in which tight junctions and deep membrane infoldings periodically appear (ruffle-ended), then disappear for short intervals (smooth-ended), from the apical ends of the cells. As this happens, the enamel covered by these cells changes rhythmically in net pH from mildly acidic (ruffle-ended) to near-physiologic (smooth-ended) as mineral crystals slowly expand into the "spaces" (volume) formerly occupied by matrix proteins and water. Matrix proteins are processed and degraded by proteinases throughout amelogenesis, but they undergo more rapid destruction once ameloblast modulation begins. Ruffle-ended ameloblasts appear to function primarily as a regulatory and transport epithelium for controlling the movement of calcium and other ions such as bicarbonate into enamel to maintain buffering capacity and driving forces optimized for surface crystal growth. The reason ruffle-ended ameloblasts become smooth-ended periodically is unknown, although this event seems to be crucial for sustaining long-term crystal growth.

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