scholarly journals Preparation of a novel nano-TiO2 photocatalytic composite using insoluble wood flour as bio-carrier and dissolved components as accelerant

2020 ◽  
Vol 9 (5) ◽  
pp. 11255-11262
Author(s):  
Judi Ye ◽  
Chen Chao ◽  
Jianguo Hong
Arena Tekstil ◽  
2013 ◽  
Vol 28 (1) ◽  
Author(s):  
Maya Komalasari ◽  
Bambang Sunendar

Partikel nano TiO2 berbasis air dengan pH basa telah berhasil disintesis dengan menggunakan metode sol-gel dan diimobilisasi pada kain kapas dengan menggunakan kitosan sebagai zat pengikat silang. Sintesis dilakukan  dengan prekursor TiCl4 pada konsentrasi 0,3 M, 0,5 M dan 1 M, dan menggunakan templat kanji dengan proses kalsinasi pada suhu 500˚C selama 2 jam. Partikel nano TiO2 diaplikasikan ke kain kapas dengan metoda pad-dry-cure dan menggunakan kitosan sebagai crosslinking agent. Berdasarkan hasil Scanning Electron Microscope (SEM),diketahui bahwa morfologi partikel TiO2 berbentuk spherical dengan ukuran nano (kurang dari 100 nm). Karakterisasi X-Ray Diffraction (XRD) menunjukkan adanya tiga tipe struktur kristal utama, yaitu (100), (101) dan (102) dengan fasa kristal yang terbentuk adalah anatase dan rutile. Pada karakterisasi menggunakan SEM terhadap serbuk dari TiO2 yang telah diaplikasikan ke permukaan kain kapas, terlihat adanya imobilisasi partikel nano TiO2 melalui ikatan hidrogen silang dengan kitosan pada kain kapas. Hasil analisa tersebut kemudian dikonfirmasi dengan FTIR (Fourier Transform Infra Red) yang hasilnya memperlihatkan puncak serapan pada bilangan gelombang 3495 cm-1, 2546 cm-1, dan 511 cm-1,  yang masing-masing diasumsikan sebagai adanya vibrasi gugus fungsi O-H, N-H dan Ti-O-Ti. Hasil SEM menunjukkan pula bahwa kristal nano yang terbentuk diantaranya adalah fasa rutile , yang berdasarkan literatur terbukti dapatberfungsi sebagai anti UV.


2020 ◽  
Vol 1 (1) ◽  
pp. 38-42
Author(s):  
Jun Yan

Cu-supported nano-TiO2 catalyst was prepared by forced hydrolysis method under mild condition. The morphology, composition and optical absorption properties of the samples were characterized by means of scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and UV-Vis diffuse reflectance spectroscopy (UV-VIS DRS). Visible photocatalytic activity of the samples was investigated by photocatalytic degradation experiment on methyl orange. The results indicated that nano-TiO2 was about 20nm in size with the main form of anatase, and photo response range was significantly broadened after it was loaded on the surface of Cu. The sample possessed high visible light catalytic activity, with the degradation rate of methyl orange reaching 94% under simulated natural light.


2021 ◽  
pp. 118221
Author(s):  
Rakibul Hossain ◽  
Mehdi Tajvidi ◽  
Douglas Bousfield ◽  
Douglas J. Gardner

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2553
Author(s):  
Yu Tu ◽  
Weihua Ao ◽  
Chunhong Wang ◽  
Tianyu Ren ◽  
Lijuan Zhang ◽  
...  

Modified microspheres (SiO2-M) were obtained by the hydrolytic modification of silicon dioxide (SiO2) microspheres with Na2SiO3, and then, SiO2-M was used as a carrier to prepare a composite photocatalyst (SiO2-M/TiO2) using the sol-gel method; i.e., nano-TiO2 was loaded on the surface of SiO2-M. The structure, morphology, and photocatalytic properties of SiO2-M/TiO2 were investigated. Besides, the mechanism of the effect of SiO2-M was also explored. The results show that the hydrolytic modification of Na2SiO3 coated the surface of SiO2 microspheres with an amorphous SiO2 shell layer and increased the quantity of hydroxyl groups. The photocatalytic performance of the composite photocatalyst was slightly better than that of pure nano-TiO2 and significantly better than that of the composite photocatalyst supported by unmodified SiO2. Thus, increasing the loading capacity of nano-TiO2, improving the dispersion of TiO2, and increasing the active surface sites are essential factors for improving the functional efficiency of nano-TiO2. This work provides a new concept for the design of composite photocatalysts by optimizing the performance of the carrier.


Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2487
Author(s):  
Geeta Pokhrel ◽  
Yousoo Han ◽  
Douglas J. Gardner

The generation of secondary processing mill residues from wood processing facilities is extensive in the United States. Wood flour can be manufactured utilizing these residues and an important application of wood flour is as a filler in the wood–plastic composites (WPCs). Scientific research on wood flour production from mill residues is limited. One of the greatest costs involved in the supply chain of WPCs manufacturing is the transportation cost. Wood flour, constrained by low bulk densities, is commonly transported by truck trailers without attaining allowable weight limits. Because of this, shipping costs often exceed the material costs, consequently increasing raw material costs for WPC manufacturers and the price of finished products. A bulk density study of wood flour (190–220 kg/m3) and wood pellets (700–750 kg/m3) shows that a tractor-trailer can carry more than three times the weight of pellets compared to flour. Thus, this study focuses on exploring the utilization of mill residues from four wood species in Maine to produce raw materials for manufacturing WPCs. Two types of raw materials for the manufacture of WPCs, i.e., wood flour and wood pellets, were produced and a study of their properties was performed. At the species level, red maple 40-mesh wood flour had the highest bulk density and lowest moisture content. Spruce-fir wood flour particles were the finest (dgw of 0.18 mm). For all species, the 18–40 wood flour mesh size possessed the highest aspect ratio. Similarly, on average, wood pellets manufactured from 40-mesh particles had a lower moisture content, higher bulk density, and better durability than the pellets from unsieved wood flour. Red maple pellets had the lowest moisture content (0.12%) and the highest bulk density (738 kg/m3). The results concluded that the processing of residues into wood flour and then into pellets reduced the moisture content by 76.8% and increased the bulk density by 747%. These material property parameters are an important attempt to provide information that can facilitate the more cost-efficient transport of wood residue feedstocks over longer distances.


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