Glass forming ability and continuous-cooling-transformation (CCT) diagrams of Vitreloy 105 as function of cooling rate and oxygen concentration

2020 ◽  
Vol 528 ◽  
pp. 119762 ◽  
Author(s):  
N.D. Campos Neto ◽  
C. Soares ◽  
F.S. Pereira ◽  
V. Bergamaschi ◽  
S.G. Antonio ◽  
...  
2015 ◽  
Vol 17 (9) ◽  
pp. 6495-6500 ◽  
Author(s):  
Katsuyoshi Kato ◽  
Atsunobu Masuno ◽  
Hiroyuki Inoue

The continuous cooling transformation (CCT) diagrams of the SrO–Al2O3 binary system under containerless conditions using an aerodynamic levitation furnace provide a slight difference in glass-forming ability at the edge of the glass-forming region.


Author(s):  
Chun-Yu Ou ◽  
C. Richard Liu

Abstract Additive manufacturing (AM) is a manufacturing method that can build high-strength materials layer-by-layer to form complex geometries. Previous studies have reported large variations in the mechanical properties of materials made by this process. One of the key factors that may contribute to variations within and among parts made by this process is a difference in the material's microstructural phase and composition. A continuous cooling transformation (CCT) diagram is a useful tool that can be used with a thermal model for microstructure design and manufacturing process control. However, traditional CCT diagrams are developed based on slow and monotonic cooling processes such as furnace cooling and air cooling, which are greatly different from the repetitive heating and cooling processes in AM. In this study, a new general methodology is presented to create CCT diagrams for materials fabricated by AM. We showed that the effect of the segmented duration within the critical temperature range, which induced precipitate formation, could be cumulative. As multiple cooling processes occurred in a short time, and the temperature drops at a high cooling rate, a constant average cooling rate was assumed when constructing the CCT diagram. Inconel 718 parts fabricated by selective laser melting were analyzed. The key factor contributing to phase transformation was identified as the accumulated duration within the critical temperature range. The presented methodology demonstrated the capability of combining a thermal model and experimental observation to quantitatively predict phase transformation and could be used to design microstructures and control AM processes.


Author(s):  
Jyrki Miettinen ◽  
Sami Koskenniska ◽  
Mahesh Somani ◽  
Seppo Louhenkilpi ◽  
Aarne Pohjonen ◽  
...  

AbstractNew continuous cooling transformation (CCT) equations have been optimized to calculate the start temperatures and critical cooling rates of phase formations during austenite decomposition in low-alloyed steels. Experimental CCT data from the literature were used for applying the recently developed method of calculating the grain boundary soluble compositions of the steels for optimization. These compositions, which are influenced by solute microsegregation and precipitation depending on the heating/cooling/holding process, are expected to control the start of the austenite decomposition, if initiated at the grain boundaries. The current optimization was carried out rigorously for an extended set of steels than used previously, besides including three new solute elements, Al, Cu and B, in the CCT-equations. The validity of the equations was, therefore, boosted not only due to the inclusion of new elements, but also due to the addition of more low-alloyed steels in the optimization. The final optimization was made with a mini-tab tool, which discarded statistically insignificant parameters from the equations and made them prudently safer to use. Using a thermodynamic-kinetic software, IDS, the new equations were further validated using new experimental CCT data measured in this study. The agreement is good both for the phase transformation start temperatures as well as the final phase fractions. In addition, IDS simulations were carried out to construct the CCT diagrams and the final phase fraction diagrams for 17 steels and two cast irons, in order to outline the influence of solute elements on the calculations and their relationship with literature recommendations.


2019 ◽  
Vol 946 ◽  
pp. 341-345
Author(s):  
Mikhail V. Maisuradze ◽  
Maksim A. Ryzhkov

Three medium carbon Cr-Mn-Mo structural steels with different content of alloying elements were studied. The austenite transformation during continuous cooling was investigated using dilatometer and metallographic analysis. The CCT diagrams were plotted showing the effect of the increased alloying elements content and B and Nb micro-alloying on the hardenability of the studied steels. The hardness dependences on the cooling rate were obtained.


2013 ◽  
Vol 652-654 ◽  
pp. 947-951
Author(s):  
Hui Li ◽  
Yun Li Feng ◽  
Da Qiang Cang ◽  
Meng Song

The static continuous cooling transformation (CCT)curves of 3.15 Si-0.036 C-0.21 Mn-0.008 S-0.008 N-0.022 Al are measured on Gleeble-3500 thermal mechanical simulator, the evolution of microstructure and the tendency of hardness are investigated by optical microscope (OM) and hardness tester. The results show that there is no evident change in microstructure which mainly are ferrite and little pearlite under different cooling rates, but the transition temperature of ferrite is gradually reduced with the increase of cooling rate. When the cooling rate is increased from 0.5°C/s to 20°C/s, the ending temperatures of phase transformation are decreased by 118°C, when cooling rate reaches to 10, Widmanstatten ferrite appears. The hardness of the steel turns out gradual upward trend with the increase of cooling rate.


2022 ◽  
Vol 905 ◽  
pp. 83-87
Author(s):  
Lu Lu Feng ◽  
Wei Wen Qiao ◽  
Jian Sun ◽  
De Fa Li ◽  
Ping Ping Li ◽  
...  

The continuous cooling transformation behavior of high-carbon pearlitic steel was studied by employing optical microscopy, scanning electron microscopy, and the Vickers hardness test. The results show that the microstructure of the test steel is composed of proeutectoid cementite and lamellar pearlite in the cooling rate range of 0.05–2 °C/s and lamellar pearlite in the range of 2–5 °C/s. Further, martensite appears at 10 °C/s. With the increase in the cooling rate, the Vickers hardness of the test steel first decreases and then increases. In the industrial production of high-carbon pearlite steel, the formation of proeutectoid cementite at a low cooling rate needs to be avoided, and at the same time, the formation of martensite and other brittle-phase at a high cooling rate needs to be avoided.


2012 ◽  
Vol 1485 ◽  
pp. 83-88 ◽  
Author(s):  
G. Altamirano ◽  
I. Mejía ◽  
A. Hernández-Expósito ◽  
J. M. Cabrera

ABSTRACTThe aim of the present research work is to investigate the influence of B addition on the phase transformation kinetics under continuous cooling conditions. In order to perform this study, the behavior of two low carbon advanced ultra-high strength steels (A-UHSS) is analyzed during dilatometry tests over the cooling rate range of 0.1-200°C/s. The start and finish points of the austenite transformation are identified from the dilatation curves and then the continuous cooling transformation (CCT) diagrams are constructed. These diagrams are verified by microstructural characterization and Vickers micro-hardness. In general, results revealed that for slower cooling rates (0.1-0.5 °C/s) the present phases are mainly ferritic-pearlitic (F+P) structures. By contrast, a mixture of bainitic-martensitic structures predominates at higher cooling rates (50-200°C/s). On the other hand, CCT diagrams show that B addition delays the decomposition kinetics of austenite to ferrite, thereby promoting the formation of bainitic-martensitic structures. In the case of B microalloyed steel, the CCT curve is displaced to the right, increasing the hardenability. These results are associated with the ability of B atoms to segregate towards austenitic grain boundaries, which reduce the preferential sites for nucleation and development of F+P structures.


Metals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 1055
Author(s):  
Hannah Schönmaier ◽  
Bernd Loder ◽  
Thomas Fischer ◽  
Fred Grimm ◽  
Ronny Krein ◽  
...  

The transformation behavior and microstructural evolution during continuous cooling within the heat affected zone between the weld beads of a 2.25Cr-1Mo-0.25V all-weld metal and the corresponding 2.25Cr-1Mo-0.25V base metal were investigated by means of dilatometer measurements, optical and scanning electron microscopy. Furthermore, macro-hardness measurements were conducted and the ferrite phase fraction was analyzed from optical microscopic images using an imaging processing program. Thereupon a continuous cooling transformation (CCT) diagram for the 2.25Cr-1Mo-0.25V base metal and three welding CCT diagrams with different peak temperatures were constructed to realistically simulate the temperature profile of the different regions within the heat affected zones between the weld beads of the multi-layer weld metal. The microstructural constituents which were observed depending on the peak temperature and cooling parameters are low quantities of martensite, high quantities of bainite and in particular lower bainite, coalesced bainite and upper bainite as well as ferrite for the welding CCT diagrams. Regarding the base metal CCT diagram, all dilatometer specimens exhibited a fully bainitic microstructure consisting of lower bainite, coalesced bainite and upper bainite. Only the slowest cooling rate with a cooling parameter of 50 s caused a ferritic transformation. Nevertheless, it has to be emphasized that the distinction between martensite and bainite and the various kinds of bainite was only possible at higher magnification using scanning electron microscopy.


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