scholarly journals Effect of intermittent ultrasound on controlling membrane fouling with coagulation pre-treatment: Significance of the nature of adsorbed organic matter

2017 ◽  
Vol 535 ◽  
pp. 168-177 ◽  
Author(s):  
Wenzheng Yu ◽  
Nigel Graham ◽  
Ting Liu
Keyword(s):  
Organic Matter ◽  
Membrane Fouling ◽  
Pre Treatment

Effect of Two Stages Adsorption as Pre-Treatment of Natural Organic Matter Removal in Ultrafiltration Process for Peat Water Treatment

2020 ◽  
Vol 988 ◽  
pp. 114-121 ◽  
Author(s):  
Mahmud ◽  
Muthia Elma ◽  
Erdina Lulu Atika Rampun ◽  
Aulia Rahma ◽  
Amalia Enggar Pratiwi ◽  
...  
Keyword(s):  
Organic Matter ◽  
Natural Organic Matter ◽  
Membrane Fouling ◽  
Optimum Dose ◽  
Operating Pressure ◽  
Filtration Process ◽  
Dead End ◽  
Ultra Filtration ◽  
Pre Treatment ◽  
Two Stages

Natural Organic Matter (NOM) content in peat water is a major problem of membrane fouling in ultrafiltration (UF). For that, two stages adsorption as pre-treatment was employed to minimize the membrane fouling of NOM content. This research was carried out to investigate the effect of two stages adsorption on ultrafiltration performance for NOM removal that remains in peat water. This method was using powdered activated carbon (PAC) dosage of 80, 160, 240, 320, 400, 480, 560, 640, 720, 800, 880 dan 960 mg.L-1. Then, Polysulfone (Psf) material was employed for Ultra filtration process. Membrane was applied in a dead-end mode with various operating pressure (1; 1.5; 2; 2.5; 3 bar). As a results, the optimum dose of PAC was 800 mg L-1 with dosage ratio of 3/4:1/4. Two stages adsorption-UF PSf provided the range from 86.9 to 92.8% of KMnO4 and 74.1-88.1% of UV254. For the experimental condition of 3 bar, the highest flux was achieved up to 39.919 L h-1.m-2.

RO filtration of biologically treated textile and dyeing effluents using ozonation as a pre-treatment

2010 ◽  
Vol 62 (4) ◽  
pp. 751-758 ◽  
Author(s):  
H. Y. Wang ◽  
Y. T. Guan ◽  
T. Mizuno ◽  
H. Tsuno
Keyword(s):  
Organic Matter ◽  
Membrane Fouling ◽  
Quality Parameters ◽  
Dyeing Wastewater ◽  
Improve Performance ◽  
Membrane Cleaning ◽  
Membrane Flux ◽  
Flux Decline ◽  
Pre Treatment ◽  
Water Purity

Bench-scale experiments were conducted to investigate the application of ozonation pre-treatment for biologically treated textile and dyeing wastewater to improve performance of the RO process. Based on ozonation experiments, four specific ozone consumptions (SOC), 0, 0.3, 0.6, 4.0 mg O3/mg DOC0 were chosen for study of the effects of ozonation on the reverse osmosis (RO) process. Membrane flux was recorded. Also, the permeate water quality parameters such as TOC, conductivity were analyzed. In addition, fouled membrane cleaning was studied. The study further examined the nature and mechanisms of membrane fouling using scanning electron microscopy (SEM) and the energy dispersive X-ray spectrometer (EDS). The effect of ozonation on RO filtration was found to depend on SOC. The study revealed that significant improvement can be achieved in the efficiency of RO filtration by employing ozonation with 0.6 mg O3/mg DOC0 SOC. Although the product water purity slightly decreased, the ozonation pre-treatment showed advantages at 0.6 mg O3/mg DOC0 SOC for the following: (i) mitigation of flux decline due to membrane fouling; (ii) improvement in foulants cleanability. In addition, hypotheses were put forward to explain the reasons from the aspect of organic matter characteristics changed by ozonation, such as changing on functional groups and molecular weight of organic matter.

Removal of algogenic organic matter by magnetic ion exchange resin pre-treatment and its effect on fouling in ultrafiltration

2011 ◽  
Vol 11 (1) ◽  
pp. 15-22 ◽  
Author(s):  
C. Liu ◽  
W. Chen ◽  
V. M. Robert ◽  
Z. G. Han
Keyword(s):  
Organic Matter ◽  
Ion Exchange ◽  
Membrane Fouling ◽  
Exchange Resin ◽  
Ion Exchange Resin ◽  
Major Barrier ◽  
Treated Water ◽  
Fouling Control ◽  
Pre Treatment ◽  
Magnetic Ion

Natural organic matter (NOM) fouling continues to be the major barrier to efficient application of ultrafiltration (UF) in drinking water treatment. Algogenic organic matter (AOM), the main contributor to total NOM levels in raw waters characterised by elevated algae levels, is currently the subject of much investigation. In this study, the effect of AOM on fouling of ultrafiltration and the effectiveness of magnetic ion exchange resin (MIEX®) pre-treatment for AOM removal and membrane fouling control was evaluated. The results showed that, the main species of algae in raw water were Chlorella vulgaris, which accounted for 80% of total algae. AOM was predominantly hydrophilic (50% or more) with a low SUVA (1.7 Lm−1 mg−1). Coagulation alone could not remove AOM effectively (less than 20%), however, when combined with magnetic ion exchange resin pre-treatment, more than 60% of AOM was be removed; pre-treatment followed by coagulation was observed to be very effective in controlling membrane fouling by AOM. The application of magnetic ion exchange resin technology at a bed volume treatment rate (BVTR) of 800 was observed to effectively eliminate fouling of UF membrane. Careful analyses of the molecular weight (MW) distribution of AOM and UV absorbance of treated water revealed that the effectiveness in membrane fouling control was the result of the changes in AOM molecular characteristics in treated water, namely a change in MW due to the preferential removal of high molecular proteins by coagulation and magnetic ion exchange resin pre-treatment. The results demonstrate that magnetic ion exchange resin followed by coagulation might be a new membrane pre-treatment option for UF membrane fouling control.

A study on membrane fouling due to algal deposition

2000 ◽  
Vol 41 (10-11) ◽  
pp. 327-335 ◽  
Author(s):  
S. Babel ◽  
S. Takizawa
Keyword(s):  
Organic Matter ◽  
Membrane Fouling ◽  
Cell Lysis ◽  
Chemical Cleaning ◽  
Membrane Cleaning ◽  
Treatment Techniques ◽  
Ozone Pretreatment ◽  
Extensive Cell ◽  
Pre Treatment ◽  
Physical And Chemical

Batch filtration experiments in dead-end mode were carried out to investigate the membrane fouling phenomenon due to Chlorella deposition and to analyse the effectiveness of pretreatment techniques to control membrane fouling. Experiments were also conducted to identify efficient and effective physical and chemical methods for cleaning the membrane. For both cellulose acetate and PVDF membranes, the effect of algal concentration was found similar. Initially when the deposition was less, the flux was high and the resistance was very low or negligible. As the deposition increased, the resistance increased exponentially. With further increase in deposition, the resistance increases linearly at a constant rate. Among the three pre-treatment techniques studied, coagulation with alum and ozonation were effective in controlling the fouling of membrane. Chlorine pretreatment was not effective in reducing the algal cake resistance because it brought about an extensive cell lysis. Photographs taken by Scanning Electron Microscope (SEM) showed damage to the cell surface architecture and release of organic matter to the medium after chlorination. Ozone pretreatment was more effective than chlorine in disintegrating only the extracelluar organic matter (EOM) without causing cell lysis, thus bringing down the algal cake resistance. Cleaning experiments after algal filtration without pre-treatment showed that physical cleaning was less effective than chemical cleaning. All four chemicals tested for membrane cleaning could reduce the cake resistance by more than 99%.

Foulant characterization of the NF membranes with and without pretreatment of biologically treated wastewater

2005 ◽  
Vol 51 (6-7) ◽  
pp. 277-284 ◽  
Author(s):  
H.K. Shon ◽  
S. Vigneswaran ◽  
H.H. Ngo ◽  
In S. Kim ◽  
R. Ben Aim
Keyword(s):  
Organic Matter ◽  
Small Molecules ◽  
Membrane Fouling ◽  
Operating Conditions ◽  
Treated Wastewater ◽  
Treated Sewage ◽  
Pre Treatment ◽  
Treated Sewage Effluent ◽  
Selection Of

In this study, different pretreatment methods such as ferric chloride (FeCl3) flocculation and powdered activated carbon (PAC) adsorption were evaluated in terms of their capability in removing effluent organic matter (EfOM) and the characteristics of the foulants on the NF membranes. A detailed experiment was conducted with two NF membranes (NTR 729HF with MWCO 700 daltons and LF 10 with MWCO 200 daltons). With pretreatment, the concentration of organic matter on the membranes decreased to 5.671×10−3 (NTR 729HF) and 4.940×10−3 (LF 10) mg EfOM/cm2 of membrane from 6.372×10−3 (NTR 729HF) and 4.979×10−3 (LF 10) mg EfOM/cm2 of membrane. The MW of the solute fraction of biologically treated sewage effluent (BTSE) ranged from 250 daltons to about 3573 (the most important being 250–520 daltons). The weight-averaged MW values of the foulants on the NTR 729HF membrane reduced from 304 daltons without pre-treatment to 208 daltons with pretreatment. In the case of EfOM, the small molecules (MW 300 to 500 daltons) are mainly responsible for the membrane fouling. Thus, the MW distribution of organic matter in the effluent and in the foulant can be used as a representative tool to evaluate the efficiency of pretreatment and NF and in the selection of their operating conditions.

Assessment of water treatment processes: detailed organic matter characterisation and membrane fouling indices at the Loddon Water Treatment Plant, Victoria, Australia

2011 ◽  
Vol 11 (3) ◽  
pp. 274-280 ◽  
Author(s):  
C. Khorshed ◽  
S. Vigneswaran ◽  
J. Kandasamy ◽  
R. Aryal ◽  
D. Dharmapalan
Keyword(s):  
Organic Matter ◽  
Water Treatment ◽  
Ion Exchange ◽  
Membrane Fouling ◽  
Treatment Plant ◽  
Water Treatment Plant ◽  
Treatment Methods ◽  
Wide Range ◽  
Exchange Adsorption ◽  
Pre Treatment

Recent advances in membrane technology have led to its broad application, and reverse osmosis (RO) systems now represent the fastest growing segment of the desalination market. Its performance is hindered by membrane fouling. In this study pre-treatment methods to reduce RO fouling were investigated including flocculation, adsorption and ion exchange. Detailed organic characterisations were made in terms of florescence spectroscopy excitation emission matrix (EEM), UV254 absorbance and liquid chromatography-organic carbon detection (LCOCD). The different pre-treatment methods were assessed in terms of the fouling potential. This was quantified in terms of the modified fouling index measured using a dead-end cell micro-filtration (MF) unit. The existing pre-treatment of granular activated carbon (GAC) filter led to a good organic removal. Among the pre-treatment methods tested in the laboratory, purolite ion exchange/adsorption was found to be better than FeCl3 flocculation in terms of the amount as well as the wide range of organics removal. A pre-treatment of flocculation with Poly-ferric-silicate (PFSi) as flocculent gave a higher removal of organic matter compared to other pre-treatments tested. DOC was reduced from 11.5 to 4.25 mg/L, and it removed mostly the humic type substances.

scholarly journals Biological filtration with and without prior in-line coagulation to reduce UF fouling by secondary effluent

2017 ◽  
Vol 8 (2) ◽  
pp. 176-191 ◽  
Author(s):  
Samia A. Aly ◽  
William B. Anderson ◽  
Peter M. Huck
Keyword(s):  
Organic Matter ◽  
Humic Substances ◽  
Membrane Fouling ◽  
Loading Rate ◽  
Pilot Scale ◽  
Secondary Effluent ◽  
Biological Filtration ◽  
Treatment Processes ◽  
Pre Treatment ◽  
Fouling Reduction

Abstract The objectives of this research were to investigate biofiltration prior to ultrafiltration (UF) for treatment of secondary effluent. Biofiltration with and without prior in-line coagulation was assessed for UF membrane fouling reduction. Two parallel pilot-scale biofilters, each with different media (sand vs. anthracite), were operated under identical conditions at a hydraulic loading rate of 0.75 m/h. A component of this investigation included the in-line application of a 1.0 mg/L dose of ferric sulfate prior to an anthracite biofilter. All UF membrane fouling experiments were conducted at bench-scale at a constant flux of 32 L/m2h (LMH). The sand (BF1) and anthracite biofilters (BF2) removed on average 25 and 20%, respectively, of the biopolymer fraction of the effluent organic matter. Humic substances were less well removed at about 10%, while biofilter influent turbidity was reduced by 75 and 70% through BF1 and BF2, respectively. Feeding the UF membrane with biofilter effluent (no prior coagulant addition) substantially reduced both hydraulically reversible and irreversible membrane fouling by up to 60 and 80%, respectively. Hydraulically reversible and irreversible fouling were further reduced (up to 69 and 87%, respectively) by the integration of the in-line coagulation/biofiltration pre-treatment processes compared to biofiltration alone.

Membrane filtration of surface water in the presence of ozone

2001 ◽  
Vol 1 (5-6) ◽  
pp. 141-150 ◽  
Author(s):  
S. Sawada ◽  
I. Sumida ◽  
K. Matsumoto
Keyword(s):  
Organic Matter ◽  
Activated Carbon ◽  
Humic Acid ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Membrane Surface ◽  
Dominant Factor ◽  
Stable Operation ◽  
Raw Water ◽  
Pre Treatment

The preliminary study investigated the effect of pre-ozonation of synthetic raw water (bentonite and humic acid) on membrane fouling. The results showed that humic acid, not bentonite, was the dominant factor in membrane fouling. When the synthetic raw water was pre-treated using ozone and activated carbon, stable operation was possible at twice the flux of membrane filtration without pre-treatment. Thus, ozone and activated carbon reduced the concentration of organic matter (humic acid), leading to an increase in flux. Secondly, an MF membrane filtration device with ozone tolerance was attached downstream of the ozone reactor so that residual ozone could reach the membrane surface. When water was treated with MF membrane filtration in the presence of ozone, the flux was stable at 4 m/d. The membrane filtration resistance increased when ozone was not injected, and decreased when it was injected. This phenomenon was repeatable. In the presence of ozone, organic matter that could accelerate fouling as decomposed and converted to less fouled materials, resulting in a suppression of fouling as well as facilitating removal of the fouling layer during back washing.

Evaluation of a bench-scale membrane fouling protocol to determine fouling propensities of membranes during full-scale water reuse applications

2010 ◽  
Vol 62 (5) ◽  
pp. 1198-1204
Author(s):  
C. L. Bellona ◽  
A. Wuertle ◽  
P. Xu ◽  
J. E. Drewes
Keyword(s):  
Organic Matter ◽  
Membrane Fouling ◽  
Water Reuse ◽  
Membrane System ◽  
Full Scale ◽  
Effluent Organic Matter ◽  
Bench Scale ◽  
Testing Protocol ◽  
Pre Treatment ◽  
Wastewater Effluents

There is increasing interest in recycling wastewater effluents for augmentation of existing water supplies. The treatment of wastewater effluents by an integrated membrane system, such as microfiltration pre-treatment followed by reverse osmosis, is the industry standard for groundwater recharge or reservoir augmentation projects. Membrane fouling, especially effluent organic matter fouling, is a major challenge for water reuse applications employing high-pressure membranes. While fouling control through pre-treatment is an important aspect in membrane system design and operation, selecting low fouling membranes is an equally important aspect. Although recent research has begun to elucidate fouling mechanisms, little work has been performed to develop methods to pre-determine the effluent organic matter fouling propensities of high-pressure membranes so that low-fouling membranes can be pre-selected for reuse applications. The purpose of this study was to utilize a bench-scale testing protocol to test the relative effluent organic matter fouling propensities of commercially available NF and RO membranes when treating wastewater effluents. Bench-scale fouling test results were then compared to operational data generated during pilot- and full-scale membrane testing. Pilot- and full-scale testing using recycled water demonstrated that membranes foul at significantly different rates and that the extent of fouling could be estimated utilizing the proposed bench-scale testing protocol.

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