Carbon Scaffold with Controllable Small Pore Structure Based on Mask Projection Stereolithography

2021 ◽  
pp. 102694
Author(s):  
Yaning Wang ◽  
Ruomeng Chen ◽  
Xu Chen ◽  
Huiwu Hu ◽  
Tengfei Li ◽  
...  
2011 ◽  
Vol 236-238 ◽  
pp. 1178-1182
Author(s):  
Yan Xin Liu ◽  
Yu Long Wang ◽  
Shen Tao Qin ◽  
Fei Fei Liu

Coating pore structure of low gloss coated paper based on different pigment blends was analyzed using mercury intrusion method in this paper. The results show that pore size of coating layer structure of low gloss coated paper ranges from 20nm-500nm, and the range from 500nm-5000nm is mainly from base paper and interactions between coating color and base paper. Printability of coated paper can be well related with coating pore structure. Print gloss is strongly influenced by pore size and pore volume. Large pore diameters and small pore volume of coating layer structure can improve print gloss. Ink density increases with the increasing of pore diameter while the pore volume is kept constant. The increasing of pore volume of coat layer structure will improve capillary absorption and then improve ink absorption. The control of coating pore structure is very important for producing low gloss coated paper.


2018 ◽  
Vol 174 ◽  
pp. 01014
Author(s):  
Alicja Wieczorek ◽  
Marcin Koniorczyk

The purpose of the study is to understand how the cyclic water freezing (0, 25, 50, 75, 100 and 150 freeze-thaw cycles) impacts microstructure and transport properties of cement-based materials. Tests were conducted on cement mortars with different water/cement ratios (w/c=0.45 and 0.40) and on two types of cement (CEM I and CEM III) without air-entraining admixtures. The changes of pore size distribution and open porosity were investigated by means of mercury intrusion porosimetry. Additionally, the relationship between intrinsic permeability and the water absorption coefficient of cement mortar samples was analysed. The water absorption coefficient and gas permeability were determined using capillary absorption test and the modified RILEMCembureau method. The evolution of transport coefficients with growing number of freeze-thaw cycles were determined on the same sample. It was also established that change of pore structure (a decrease of small pore volume <100nm and increase of larger pores >100nm) induces an increase of water transport parameters such as permeability and water absorption coefficient. The higher gas permeability corresponds to the higher internal damage. In particular, it is associated with the change of cement mortar microstructure, which indicates damage of narrow channels in the pore structure of cement mortars.


2019 ◽  
Vol 11 (1) ◽  
pp. 37-47 ◽  
Author(s):  
Meng Wang ◽  
Zhaomeng Yang ◽  
Changjun Shui ◽  
Zhong Yu ◽  
Zhufeng Wang ◽  
...  

Abstract Different from conventional reservoirs, unconventional tight sand oil reservoirs are characterized by low or ultra-low porosity and permeability, small pore-throat size, complex pore structure and strong heterogeneity. For the continuous exploration and enhancement of oil recovery from tight oil, further analysis of the origins of the different reservoir qualities is required. The Upper Triassic Chang 8 sandstone of the Yanchang Formation from the Maling Oilfield is one of the major tight oil bearing reservoirs in the Ordos Basin. Practical exploration demonstrates that this formation is a typical tight sandstone reservoir. Samples taken from the oil layer were divided into 6 diagenetic facies based on porosity, permeability and the diagenesis characteristics identified through thin section and scanning electron microscopy. To compare pore structure and their seepage property, a high pressure mercury intrusion experiments (HPMI), nuclear magnetic resonance (NMR), andwater-oil relative permeability test were performed on the three main facies developed in reservoir. The reservoir quality and seepage property are largely controlled by diagenesis. Intense compaction leads to a dominant loss of porosity in all sandstones, while different degrees of intensity of carbonate cementation and dissolution promote the differentiation of reservoir quality. The complex pore structure formed after diagenesis determines the seepage characteristics, while cementation of chlorite and illite reduce the effective pore radius, limit fluid mobility, and lead to a serious reduction of reservoir permeability.


2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Fengwen Zhao ◽  
Jianhua Hu ◽  
Dongjie Yang ◽  
Ye Kuang ◽  
Hongxing Xiao ◽  
...  

To control pores in the backfill, the air-entraining agents (AEAs) are used as an admixture to realize the pore structure changes under artificial action and explore the effect of pore structure on strength. Two AEAs at different dosages were added to the backfill. The relationship was then analyzed between them from the macro- and mesoscopic aspects. The results indicate that AEA can regulate pore structure changes of AEACPB. With the increase in AEA content, the total pore volume of different pore sizes in AEACPB increases, in which the proportion of big and medium pore gradually increases while the proportion of small pore gradually decreases. The AEACPB’s UCS is linearly negatively correlated with the porosity and pore percentage, which is the primary factor affecting the AEACPB of the pore structure. When the total pores’ volume in the AEACPB is constant, the influence of different pore structures differs. A higher proportion of small pores leads to a linear increase in strength; a higher proportion of medium pores leads to a linear decrease in strength; and a higher proportion of big pores leads to an exponential decrease in strength. And the fractal dimension has a linear negative correlation with the UCS by fractal theory analysis.


Lithosphere ◽  
2021 ◽  
Vol 2021 (Special 1) ◽  
Author(s):  
Xiangye Kong ◽  
Jianhui Zeng ◽  
Xianfeng Tan ◽  
Xianglu Gao ◽  
Yu Peng ◽  
...  

Abstract The Xiagou Formation is the main tight oil reservoir in Qingxi Sag of Jiuquan Basin. Given the poor physical properties and other factors restricting tight oil exploitation and production in this area, studies should focus on microscopic pore structure characteristics. In this study, a nano-CT scanner, a SEM, and an NMR were used to study the pore structure characteristics of a tight carbonate reservoir in Qingxi Sag, Jiuquan Basin. The Xiagou Formation reservoir mainly consists of gray argillaceous dolomite and dolomitic mudstone. The pore categories are mainly elliptic, irregular, intergranular, and intragranular and mostly filled with clay and carbonate cement. Pore space is small, the intergranular or organic pores are mostly separated, and pore-throat is weakly connected. The throats mostly develop with lamellar and tube bundle-like characteristics and with poor seepage ability. The pore-throats mostly span from nanometer to micrometer sizes, and pore diameters are mainly concentrated in the range of 0.01–0.1 and 1–10 μm. It is a unimodal pattern mainly composed of micropores, or a bimodal regular allocation dominated by micropores supplemented by macropores. The relationship between micropore (&lt;0.1 μm) and macropore (&gt;1 μm) content allocation and mean pore diameter strongly controls the permeability of reservoir rocks. When macropore content reaches more than 85%, or when pore content totals less than 3%, the permeability of a reservoir remarkably increases. At a higher ratio of the average finest throat sectional area and throat-pore of reservoir rock, the throat radius lies closer to the connecting pore radius, pore and throat connectivity improves, and reservoir seepage ability becomes stronger. Based on reservoir capacity and seepage ability, pore structures of the tight carbonate reservoirs in study area are classified into type I (small-pore–thin-throat), type II (thin-pore–thin-throat), and type III (microporous-microthroat) with rock permeability&gt;0.1 mD, 0.05–0.1 mD, and &lt;0.05 mD, respectively. The type I pore structure reservoir should be regarded as an indicator of tight oil “sweet spots” reservoir in the study area.


Energies ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 4102
Author(s):  
Juncheng Qiao ◽  
Xianzheng Zhao ◽  
Jianhui Zeng ◽  
Guomeng Han ◽  
Shu Jiang ◽  
...  

The uncertainties between reservoir quality and gas migration and accumulation in tight sandstone gas reservoirs are intrinsically attributed to complex microscopic pore structures. Integrated analysis including the physical simulation experiment of gas migration and accumulation, X-ray computed tomography (X-CT), and casting thin section (CTS) were conducted on core plug samples collected from the Upper Paleozoic Permian Lower Shihezi and Shanxi tight sandstone of the Daniudi area in the Ordos Basin to investigate the impacts of pore structure on the gas migration and accumulation. Physical simulation suggested that the gas flows in migration in tight sandstone reservoirs were characterized by deviated-Darcy linear flow and non-linear flow regimes. Minimum and stable migration pressure square gradients determined by application of apparent permeability were employed as key parameters to describe gas flow. Pore structure characterization revealed that the tight sandstone reservoir was characterized by wide pore and throat size distributions and poor pore-throat connectivity. The pore–throat combinations could be divided into three types, including the macropore and coarse throat dominant reservoir, full-pore and full-throat form, and meso-small pore and fine throat dominant form. Comparative analyses indicated that pore and throat radii determined the gas flow regimes by controlling the minimum and stable migration pressure gradients. Gas accumulation capacity was dominated by the connected effective porosity, and the gas accumulation process was controlled by the cumulative effective porosity contribution from macropores to micropores. Variations in pore structures resulted in differences in gas migration and accumulation of tight sandstone reservoirs. The macropore and coarse throat-dominant and the full-pore and full-throat reservoirs exhibited greater gas migration and accumulation potentials than the small pore and fine throat dominate form.


Fractals ◽  
2018 ◽  
Vol 26 (02) ◽  
pp. 1840008 ◽  
Author(s):  
JIJUN LI ◽  
ZHAO LIU ◽  
JUNQIAN LI ◽  
SHUANGFANG LU ◽  
TONGQIAN ZHANG ◽  
...  

Samples from seven major exploration wells in Biyang Depression of Henan Oilfield were compared using low-temperature nitrogen adsorption and shale oil adsorption experiments. Comprehensive analysis of pore development, oiliness and shale oil flowability was conducted by combining fractal dimension. The results show that the fractal dimension of shale in Biyang Depression of Henan Oilfield was negatively correlated with the average pore size and positively correlated with the specific surface area. Compared with the large pore, the small pore has great fractal dimension, indicating the pore structure is more complicated. Using S1 and chloroform bitumen A to evaluate the relationship between shale oiliness and pore structure, it was found that the more heterogeneous the shale pore structure, the higher the complexity and the poorer the oiliness. Clay minerals are the main carriers involved in crude oil adsorption, affecting the mobility of shale oil. When the pore complexity of shale was high, the content of micro- and mesopores was high, and the high specific surface area could enhance the adsorption and reduce the mobility of shale oil.


2008 ◽  
Vol 55-57 ◽  
pp. 529-532
Author(s):  
K. Kraiwattanawong ◽  
P. Kitchaiya ◽  
Arthit Neramittagapong ◽  
P. Praserthdam ◽  
H. Tamon

Resorcinol and formaldehyde (RF) carbon cryogels are prepared by sol-gel polycondensation by using sodium carbonate (C) as a catalyst with water (W) as solvent, immersed in acid solution, hydrochloric acid (HCl), dried by freeze-drying technique and then carbonized under inert atmosphere, respectively. Compared with their carbon precursors, both Vmes and mesopore size distributions of all carbon cryogels can be developed since the pore shrinkage is the crucial role in the change of pore structure of carbon gels. HCl may promote the strength of small pore structure and increase the pore shrinkage of large pore structure. Consequently, the treatment of HCl does not only enhance the partial collapse of large pore structure, the treatment also increases the strength of small pore structure to inhibit the shrinkage of this structure during carbonization as well.


2021 ◽  
Author(s):  
ying lang ◽  
xin dai ◽  
lin zhao ◽  
Hong-Kang wei ◽  
chang-an wang

Abstract Porous YSZ ceramics with different pore structure were prepared by volume limiting foaming technology. Accurate porosity could achieve by this technology[1], so all samples were adjusted to density of 1g/m3 (porosity of about 82.6%). For the same density, the influence of porosity change on the strength was excluded. The effects of different pore structure on mechanical properties (compressive strength, strength-deformation curve and Young's modulus) were studied. The results showed that for porous ceramics with uniform pores the larger the pore size was, the smaller the Young's modulus and the lower the strength was. In addition, for samples with mix pores (large pore and small pore), when the volume fraction of macropores is large, the strength is the same as that of porous ceramics with uniform small pore size structure; when the volume fraction of small pores is large, the strength is the same as that of porous ceramics with uniform large pore size structure.


2017 ◽  
Vol 100 (12) ◽  
pp. 5502-5511 ◽  
Author(s):  
Wenlong Huo ◽  
Shu Yan ◽  
Jia-Min Wu ◽  
Jingjing Liu ◽  
Yugu Chen ◽  
...  

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