Large scale in-situ experiments on sealing constructions in underground disposal facilities for radioactive wastes – Examples of recent BfS- and GRS-activities

2015 ◽  
Vol 84 ◽  
pp. 6-17
Author(s):  
R. Mauke ◽  
H.-J. Herbert
2006 ◽  
Vol 932 ◽  
Author(s):  
Bruno Kursten ◽  
Frank Druyts

ABSTRACTThe underground formation that is currently being considered in Belgium for the permanent disposal of high-level radioactive waste and spent fuel is a 30-million-year-old argillaceous sediment (Boom Clay layer). This layer is located in the northeast of Belgium and extending under the Mol-Dessel nuclear site at a depth between 180 and 280 meter.Within the concept for geological disposal (multibarrier system), the metallic container is the primary engineered barrier. Its main goal is to contain the radioactive waste and to prevent the groundwater from coming into contact with the wasteform by acting as a tight barrier. The corrosion resistance of container materials is an important aspect in ensuring the tightness of the metallic container and therefore plays an important role in the safe disposal of HLW. The metallic container has to provide a high integrity, i.e. no through-the-wall corrosion should occur, at least for the duration of the thermal phase (500 years for vitrified HLW and 2000 years for spent fuel).An extensive corrosion evaluation programme, sponsored by the national authorities and the European Commission, was started in Belgium in the mid 1980's. The main objective was to evaluate the long-term corrosion performance of a broad range of candidate container materials. In addition, the influence of several parameters, such as temperature, oxygen content, groundwater composition (chloride, sulphate and thiosulphate), γ-radiation, … were investigated. The experimental approach consisted of in situ experiments (performed in the underground research facility, HADES), electrochemical experiments, immersion experiments and large scale demonstration tests (OPHELIE, PRACLAY). Degradation modes considered included general corrosion, localised corrosion (pitting) and stress corrosion cracking.This paper gives an overview of the more relevant experimental results, gathered over the past 25 years, of the Belgian programme in the field of container corrosion.


Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1085
Author(s):  
Matheus A. Tunes ◽  
Cameron R. Quick ◽  
Lukas Stemper ◽  
Diego S. R. Coradini ◽  
Jakob Grasserbauer ◽  
...  

Microelectromechanical systems (MEMS) are currently supporting ground-breaking basic research in materials science and metallurgy as they allow in situ experiments on materials at the nanoscale within electron microscopes in a wide variety of different conditions such as extreme materials dynamics under ultrafast heating and quenching rates as well as in complex electro-chemical environments. Electron-transparent sample preparation for MEMS e-chips remains a challenge for this technology as the existing methodologies can introduce contaminants, thus disrupting the experiments and the analysis of results. Herein we introduce a methodology for simple and fast electron-transparent sample preparation for MEMS e-chips without significant contamination. The quality of the samples as well as their performance during a MEMS e-chip experiment in situ within an electron microscope are evaluated during a heat treatment of a crossover AlMgZn(Cu) alloy.


2017 ◽  
Vol 54 (8) ◽  
pp. 1055-1070 ◽  
Author(s):  
O. Nasir ◽  
T.S. Nguyen ◽  
J.D. Barnichon ◽  
A. Millard

Geological disposal of radioactive wastes relies on a multiple barrier system to provide long-term containment and isolation of the wastes. The excavation of the repository creates openings and disturbed zones in the host rock formations that need to be properly sealed. Bentonite-based materials are being considered worldwide as a preferred type of sealing material, since they possess desirable characteristics such as low permeability, high sorption capability, and swelling potential allowing them to close internal cracks and gaps at interfaces with other materials. The French Institute for Radiation Protection and Nuclear Safety (IRSN) has led an experimental program consisting of a series of laboratory and large in situ experiments to assess the hydromechanical behaviour of bentonite seals. The experiments consisted of the forced re-saturation of pre-fabricated blocks of bentonite–sand mixture, with technological voids between bentonite seals and the walls of the steel cell (in the laboratory tests) and between bentonite seals and the host rock (in the in situ experiment). Relative humidity and total stress were monitored during both tests. The Canadian Nuclear Safety Commission (CNSC) collaborated with Geofirma Engineering, IRSN, and Commissariat à l’énergie atomique (CEA) to develop a mathematical model to simulate the experiments. The model was developed within the framework of poromechanics, with the inclusion of partial saturation characteristics and swelling potential to simulate the behaviour of the bentonite-based material. The model results were in good agreement with the experimental measurements for relative humidity and swelling stresses. The model also predicted the closure of technological voids and gaps due to swelling. Although swelling into the technological voids leads to an increase in permeability, that permeability remains low and insignificant from a safety perspective.


1990 ◽  
Vol 212 ◽  
Author(s):  
B. H. Kjartanson ◽  
M. N. Gray ◽  
B.C.M. Pulles

ABSTRACTAECL Research is carrying out large-scale in situ experiments at its Underground Research Laboratory (URL). The Buffer/Container Experiment is designed principally to investigate the full scale, in situ performance of bentonite-based buffer material in a single emplacement borehole environment. In addition, the response of the rock to excavation and heating will be investigated. The experiment also allows for the development of the technologies needed to demonstrate some of the vault engineering activities proposed in the Canadian nuclear fuel waste disposal concept. These include excavation of large diameter boreholes for waste emplacement and in situ compaction of a bentonite/sand buffer mixture. Although these methodologies developed for the URL have not been optimized for the commercial, full-scale operations needed for a disposal vault, results show that the equipment and methodologies needed for vault operations are a reasonable extrapolation of existing technology.


2021 ◽  
Author(s):  
Diana Avadanii ◽  
Lars Hansen ◽  
Ed Darnbrough ◽  
Katharina Marquardt ◽  
David Armstrong ◽  
...  

<p>The mechanics of olivine deformation play a key role in large-scale, long-term planetary processes, such as the response of the lithosphere to tectonic loading or the response of the solid Earth to tidal forces, and in short-term processes, such as the evolution of roughness on oceanic fault surfaces or postseismic creep within the upper mantle. Many previous studies have emphasized the importance of grain-size effects in the deformation of olivine. However, most of our understanding of the role of grain boundaries in deformation of olivine is inferred from comparison of experiments on single crystals to experiments on polycrystalline samples.</p><p>To directly observe and quantify the mechanical properties of olivine grain boundaries, we use high-precision mechanical testing of synthetic forsterite bicrystals with well characterised interfaces. We conduct nanoindentation tests at room temperature on low-angle (13<sup>o</sup> tilt about [100] on (015)) and high-angle (60<sup>o</sup> tilt about [100] on (011)) grain boundaries. We observe that plasticity is easier to initiate if the grain boundary is within the volume tested. This observation agrees with the interpretation that certain grain-boundary configurations can act as sites for initiating microplasticity.</p><p>As part of continuing efforts, we are also conducting in-situ micropillar compression tests at high-temperature (above 600<sup>o</sup> C) within similar bicrystals. In these experiments, the boundary is contained within the micropillar and oriented at 45<sup>o</sup> to the loading direction to promote shear along the boundary. In these in-situ tests, our hypothesis is that the low-angle grain boundary displays a higher viscosity relative to the high-angle interface. Key advantages of performing in-situ experiments are the direct observation of grain-boundary migration or sliding, simplified kinematics of a single boundary segment, and  potentially changes in style of deformation with different grain-boundary character.</p><p>These small deformation volume experiments allow us to qualitatively explore the differences between the crystal interior and regions containing grain boundaries. Overall, the variation in strain and temperature in our small scale experiments allows the fundamental investigation of the response of well characterised forsterite grain boundaries to deformation. </p>


Author(s):  
D. Loretto ◽  
J. M. Gibson ◽  
S. M. Yalisove ◽  
R. T. Tung

The cobalt disilicide/silicon system has potential applications as a metal-base and as a permeable-base transistor. Although thin, low defect density, films of CoSi2 on Si(111) have been successfully grown, there are reasons to believe that Si(100)/CoSi2 may be better suited to the transmission of electrons at the silicon/silicide interface than Si(111)/CoSi2. A TEM study of the formation of CoSi2 on Si(100) is therefore being conducted. We have previously reported TEM observations on Si(111)/CoSi2 grown both in situ, in an ultra high vacuum (UHV) TEM and ex situ, in a conventional Molecular Beam Epitaxy system.The procedures used for the MBE growth have been described elsewhere. In situ experiments were performed in a JEOL 200CX electron microscope, extensively modified to give a vacuum of better than 10-9 T in the specimen region and the capacity to do in situ sample heating and deposition. Cobalt was deposited onto clean Si(100) samples by thermal evaporation from cobalt-coated Ta filaments.


Author(s):  
Charles W. Allen ◽  
Robert C. Birtcher

The uranium silicides, including U3Si, are under study as candidate low enrichment nuclear fuels. Ion beam simulations of the in-reactor behavior of such materials are performed because a similar damage structure can be produced in hours by energetic heavy ions which requires years in actual reactor tests. This contribution treats one aspect of the microstructural behavior of U3Si under high energy electron irradiation and low dose energetic heavy ion irradiation and is based on in situ experiments, performed at the HVEM-Tandem User Facility at Argonne National Laboratory. This Facility interfaces a 2 MV Tandem ion accelerator and a 0.6 MV ion implanter to a 1.2 MeV AEI high voltage electron microscope, which allows a wide variety of in situ ion beam experiments to be performed with simultaneous irradiation and electron microscopy or diffraction.At elevated temperatures, U3Si exhibits the ordered AuCu3 structure. On cooling below 1058 K, the intermetallic transforms, evidently martensitically, to a body-centered tetragonal structure (alternatively, the structure may be described as face-centered tetragonal, which would be fcc except for a 1 pet tetragonal distortion). Mechanical twinning accompanies the transformation; however, diferences between electron diffraction patterns from twinned and non-twinned martensite plates could not be distinguished.


Author(s):  
Kenneth S. Vecchio ◽  
John A. Hunt

In-situ experiments conducted within a transmission electron microscope provide the operator a unique opportunity to directly observe microstructural phenomena, such as phase transformations and dislocation-precipitate interactions, “as they happen”. However, in-situ experiments usually require a tremendous amount of experimental preparation beforehand, as well as, during the actual experiment. In most cases the researcher must operate and control several pieces of equipment simultaneously. For example, in in-situ deformation experiments, the researcher may have to not only operate the TEM, but also control the straining holder and possibly some recording system such as a video tape machine. When it comes to in-situ fatigue deformation, the experiments became even more complicated with having to control numerous loading cycles while following the slow crack growth. In this paper we will describe a new method for conducting in-situ fatigue experiments using a camputer-controlled tensile straining holder.The tensile straining holder used with computer-control system was manufactured by Philips for the Philips 300 series microscopes. It was necessary to modify the specimen stage area of this holder to work in the Philips 400 series microscopes because the distance between the optic axis and holder airlock is different than in the Philips 300 series microscopes. However, the program and interfacing can easily be modified to work with any goniometer type straining holder which uses a penrmanent magnet motor.


1998 ◽  
Vol 37 (2) ◽  
pp. 137-144 ◽  
Author(s):  
Elisa Garvey ◽  
John E. Tobiason ◽  
Michael Hayes ◽  
Evelyn Wolfram ◽  
David A. Reckhow ◽  
...  

This paper reports on field studies and model development aimed at understanding coliform fate and transport in the Quabbin Reservoir, an oligotrophic drinking water supply reservoir. An investigation of reservoir currents suggested the importance of wind driven phenomena, and that both lateral and vertical circulation patterns exist. In-situ experiments of coliform decay suggested dependence on light intensity and yielded an appropriate decay coefficient to be used in CE-QUAL-W2, a two-dimensional hydrodynamic and water quality model. Modeling confirmed the sensitivity of reservoir outlet concentration to vertical variability within the reservoir, meteorological conditions, and location of coliform source.


2018 ◽  
Vol 23 (suppl_1) ◽  
pp. e16-e16
Author(s):  
Ahmed Moussa ◽  
Audrey Larone-Juneau ◽  
Laura Fazilleau ◽  
Marie-Eve Rochon ◽  
Justine Giroux ◽  
...  

Abstract BACKGROUND Transitions to new healthcare environments can negatively impact patient care and threaten patient safety. Immersive in situ simulation conducted in newly constructed single family room (SFR) Neonatal Intensive Care Units (NICUs) prior to occupancy, has been shown to be effective in testing new environments and identifying latent safety threats (LSTs). These simulations overlay human factors to identify LSTs as new and existing process and systems are implemented in the new environment OBJECTIVES We aimed to demonstrate that large-scale, immersive, in situ simulation prior to the transition to a new SFR NICU improves: 1) systems readiness, 2) staff preparedness, 3) patient safety, 4) staff comfort with simulation, and 5) staff attitude towards culture change. DESIGN/METHODS Multidisciplinary teams of neonatal healthcare providers (HCP) and parents of former NICU patients participated in large-scale, immersive in-situ simulations conducted in the new NICU prior to occupancy. One eighth of the NICU was outfitted with equipment and mannequins and staff performed in their native roles. Multidisciplinary debriefings, which included parents, were conducted immediately after simulations to identify LSTs. Through an iterative process issues were resolved and additional simulations conducted. Debriefings were documented and debriefing transcripts transcribed and LSTs classified using qualitative methods. To assess systems readiness and staff preparedness for transition into the new NICU, HCPs completed surveys prior to transition, post-simulation and post-transition. Systems readiness and staff preparedness were rated on a 5-point Likert scale. Average survey responses were analyzed using dependent samples t-tests and repeated measures ANOVAs. RESULTS One hundred eight HCPs and 24 parents participated in six half-day simulation sessions. A total of 75 LSTs were identified and were categorized into eight themes: 1) work organization, 2) orientation and parent wayfinding, 3) communication devices/systems, 4) nursing and resuscitation equipment, 5) ergonomics, 6) parent comfort; 7) work processes, and 8) interdepartmental interactions. Prior to the transition to the new NICU, 76% of the LSTs were resolved. Survey response rate was 31%, 16%, 7% for baseline, post-simulation and post-move surveys, respectively. System readiness at baseline was 1.3/5,. Post-simulation systems readiness was 3.5/5 (p = 0.0001) and post-transition was 3.9/5 (p = 0.02). Staff preparedness at baseline was 1.4/5. Staff preparedness post-simulation was 3.3/5 (p = 0.006) and post-transition was 3.9/5 (p = 0.03). CONCLUSION Large-scale, immersive in situ simulation is a feasible and effective methodology for identifying LSTs, improving systems readiness and staff preparedness in a new SFR NICU prior to occupancy. However, to optimize patient safety, identified LSTs must be mitigated prior to occupancy. Coordinating large-scale simulations is worth the time and cost investment necessary to optimize systems and ensure patient safety prior to transition to a new SFR NICU.


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