A Simple, Reliable Method for Preparing Perforated Formvar Films

1971 ◽  
Vol 29 ◽  
pp. 460-461
Author(s):  
Paul R. Eisner
Keyword(s):  
Relative Humidity ◽  
Room Temperature ◽  
Reliable Method ◽  
Absolute Methanol ◽  
Ethylene Dichloride ◽  
High Humidity ◽  
Moist Air ◽  
Solvent Treatment ◽  
Cast Films ◽  
Glass Slides

Perforated films used as test specimens for compensation of asymmetry in electron microscope lenses can be made by introducing water or glycerol into a Formvar solution. This can be done by preparing an emulsion or by exposing a thin layer of Formvar solution on the surface of glass to steam or moist air. Consistent production of small, round test holes with smooth edges is difficult. The following method employs solvent treatment for enlarging perforations formed in high humidity. Edge characteristics and hole size can be controlled easily and consistently. Useful holes as small as 0.15μ diameter can be produced.Procedures described by Bradley are used to clean glass slides, dissolve Formvar in ethylene dichloride, cast films on glass, and mount films on grids. In a room or chamber at room temperature (23 C) with 50-70%. relative humidity, the clean glass slides are dipped into a Coplin staining jar containing 0.2-0.4% (w/v) Formvar solution. Figure 1 shows perforations formed during casting in a chamber at 60% relative humidity using a 0.4% Formvar solution. The perforated films are mounted on grids, which are immersed in acetone, absolute methanol, or chloroform-absolute methanol (1:9) contained in compartments of a depression plate.

scholarly journals Corrosion Product Identification and Relative Rates of Corrosion of Candidate Metals in an Irradiated Air-Steam Environment

1989 ◽  
Vol 176 ◽  
Author(s):  
Donald T. Reed ◽  
V. Swayambunathan ◽  
B. S. Tani ◽  
Richard A. Van Konynenburg
Keyword(s):  
Relative Humidity ◽  
Nickel Alloy ◽  
Room Temperature ◽  
Copper Alloys ◽  
General Corrosion ◽  
Moist Air ◽  
Dose Rates ◽  
Corrosion Rates ◽  
Product Identification ◽  
High Nickel

ABSTRACTPreviously reported work by others indicates that dicopper trihydroxide nitrate, Cu2NO3(OH)3, forms on copper and copper alloys subjected to irradiated moist air near room temperature. We have performed experiments over a range of temperature and humidity, and have found that this species is formed at temperatures up to at least 150° C if low to intermediate relative humidities are present. At 150°C and 100% relative humidity, only Cu2O and CuO were observed. The relative general corrosion rates of the copper materials tested in 1-month experiments at dose rates of 0.7 and 2.0 kGy/h were Cu > 70/30 Cu-Ni > Al-bronze. High-nickel alloy 825 showed no observable corrosion.

Porous CeO2 nanospheres for a room temperature triethylamine sensor under high humidity conditions

2018 ◽  
Vol 42 (19) ◽  
pp. 15954-15961 ◽  
Author(s):  
Cecilia A. Zito ◽  
Tarcísio M. Perfecto ◽  
Diogo P. Volanti
Keyword(s):  
Relative Humidity ◽  
Response Time ◽  
Room Temperature ◽  
High Humidity ◽  
Sensing Performance

The porous CeO2 nanospheres showed an enhanced triethylamine sensing performance at 98% of relative humidity in terms of sensitivity, selectivity, repeatability, and response time.

scholarly journals A Study of Moist Air Condensation Characteristics in a Transonic Flow System

Energies ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 4052
Author(s):  
Jie Wang ◽  
Hongfang Gu
Keyword(s):  
Mach Number ◽  
Relative Humidity ◽  
Transonic Flow ◽  
Flow System ◽  
Plane Surface ◽  
Droplet Growth ◽  
Moist Air ◽  
Dry Air ◽  
Hydraulic Equipment ◽  
Non Equilibrium

When water vapor in moist air reaches supersaturation in a transonic flow system, non-equilibrium condensation forms a large number of droplets which may adversely affect the operation of some thermal-hydraulic equipment. For a better understanding of this non-equilibrium condensing phenomenon, a numerical model is applied to analyze moist air condensation in a transonic flow system by using the theory of nucleation and droplet growth. The Benson model is adopted to correct the liquid-plane surface tension equation for realistic results. The results show that the distributions of pressure, temperature and Mach number in moist air are significantly different from those in dry air. The dry air model exaggerates the Mach number by 19% and reduces both the pressure and the temperature by 34% at the nozzle exit as compared with the moist air model. At a Laval nozzle, for example, the nucleation rate, droplet number and condensation rate increase significantly with increasing relative humidity. The results also reveal the fact that the number of condensate droplets increases rapidly when moist air reaches 60% relative humidity. These findings provide a fundamental approach to account for the effect of condensate droplet formation on moist gas in a transonic flow system.

scholarly journals Back protection of canvas paintings

2020 ◽  
Vol 8 (1) ◽  
Author(s):  
Tim Padfield ◽  
Nicolas Padfield ◽  
Daniel Sang-Hoon Lee ◽  
Anne Thøgersen ◽  
Astrid Valbjørn Nielsen ◽  
...  
Keyword(s):  
Fluid Dynamics ◽  
Computational Fluid Dynamics ◽  
Relative Humidity ◽  
Temperature Variation ◽  
Room Temperature ◽  
Single Point ◽  
Confined Space ◽  
Constant Wall Temperature ◽  
Back Plate ◽  
Inner Surface

Abstract In this paper different scenarios for back protection of a canvas painting and their effect on the stability of the relative humidity behind the painting are tested. A painting on canvas, stretched on a wooden frame, was fitted with various styles of back protection and then exposed to a cycle of temperature variation at the back, with the front exposed to a constant room temperature. The painting was also exposed to a constant wall temperature and varying room temperature. The space between the canvas and the back board was fitted with temperature and relative humidity (RH) sensors. The sensors were used to provide the essential single-point data of temperature and RH at the given locations. For more comprehensive understanding of the rather confined space, further numerical simulation (computational fluid dynamics) was adopted as part of the investigation. The computational fluid dynamics was used to understand the natural convection within the microclimate through the depictions of temperature distribution, as well as the corresponding airflow. The unprotected painting suffered a large RH variation at its back, because of the varying canvas temperature interacting with the constant room air moisture content. Effective stabilisation of the RH behind the canvas against temperature variation was provided by a shiny aluminium alloy sheet sealed against the frame. The non-absorbent back board experienced a strong variation in RH, because of humidity buffering of the space by the painting canvas at a different temperature. Either a space or insulation between this back plate and the wall reduced the risk of condensation on the inner surface of the back plate. Insulation will however increase the risk of condensation on the wall surface behind the painting. An absorbent back board de-stabilised the RH at the painting canvas surface by providing a competing humidity buffer at a different temperature. To provide protection against moisture exchange with an unsuitable room RH, extra humidity buffer was placed 3 mm behind the painting canvas, kept close to the painting temperature by insulation between this buffer and the back board. This stabilised RH at the canvas surface but increased both the temperature and the RH variation at the back board and thus increased the risk of condensation on the inner surface of the back board. The RH and the temperature in the narrow spaces between the painting canvas and the wooden stretcher frame were always more nearly constant than in the open canvas area, which suggests an explanation for the widely observed better condition of the areas of canvas paintings which lie close over the support structure. Our conclusion is that a non-absorbent, impermeable back plate gives good RH stability against a changing temperature gradient between wall and canvas painting surface.

CLAY-INORGANIC STUDIES. II. HYDROXY ALUMINUM PHOSPHATE–MONTMORILLONITE COMPLEX

1975 ◽  
Vol 55 (2) ◽  
pp. 225-233 ◽  
Author(s):  
H. KODAMA ◽  
M. D. WEBBER
Keyword(s):  
Relative Humidity ◽  
Room Temperature ◽  
Aluminum Phosphate ◽  
Silicate Layer ◽  
Basal Spacing ◽  
Minor Amount ◽  
Chemical Compositions ◽  
A Minor ◽  
Positively Charged ◽  
Water Contents

Two specimens of hydroxy aluminum phosphate interlayer materials in montmorillonite clay were prepared with 7.20 meq Al and 11.29 meq H3PO4/g clay and with 14.40 meq Al and 22.58 meq H3PO4/g clay, and the resulting complexes studied by chemical and mineralogical methods. Both interlayer materials were slightly positively charged and except for different water contents their chemical compositions were almost identical. They contained Al, PO4 and H2O and a minor amount of Ca and approximated hydrous AlPO4∙nH2O. The mole ratios of Al:Ca:PO4:OH were 1.00:0.08:0.92:0.24 and 1.00:0.05:0.91:0.24, respectively. The interlayer materials appeared to be loosely packed and distributed sparsely in interspaces of the montmorillonite. The degree of packing was greater for the preparation with the larger amount of interlayer material. The materials increased the montmorillonite basal spacing to 23.3 Å under air-dry condition (30–40% relative humidity) but did not affect the lateral dimensions. The basal spacing varied somewhat with relative humidity at room temperature and decreased markedly as water was driven off by heating. Heat treatments between room temperature and 300 C sharply reduced the d001 spacings to 16.7 Å which persisted up to 700 C. It is postulated that the large basal spacings occur because the hydrated interlayer materials have a framework structure with tunnels along the c-axis. This being so, changes in the spacings with different humidities might result from the movement of water molecules among interstitial spaces existing around and between the loosely distributed molecules of interlayer material. The 16.7 Å spacing for the dehydrated phase corresponds to the sum of 7.0 Å, the edge dimension of an orthorhombic anhydrous AlPO4 and 9.7 Å, the silicate layer thickness.

Preparation and Characterization of Modified PVDF-g-PSSA Membrane

2010 ◽  
Vol 152-153 ◽  
pp. 44-50 ◽  
Author(s):  
Gui Bao Guo ◽  
Er Ding Han ◽  
Sheng Li An
Keyword(s):  
Relative Humidity ◽  
Sodium Silicate ◽  
Room Temperature ◽  
Proton Exchange Membrane ◽  
Vinylidene Fluoride ◽  
Proton Exchange ◽  
Poly Vinylidene Fluoride ◽  
Relative Humidity Range ◽  
Exchange Membrane

A new method based on a solution graft technique was used to prepare poly (vinylidene fluoride) grafted polystyrene sulfonated acid (PVDF-g-PSSA) proton exchange membrane. Polystyrene is grafted into PVDF modified by plain sodium silicate (Na4SiO4). There is a linear relationship between the degree of grafting and the content of Na4SiO4. Fourier transform infrared spectroscopy is used to characterize changes of the membrane's microstructures after grafting and sulfonation. The morphology of the membrane's microstructures after grafting and sulfonation is studied by scanning electrolytic microscope (SEM). The effect of plain sodium silicate (Na4SiO4) concentration and relative humidity on the conductivity of the electrolyte was investigated by the impedance at room temperature. The results show that the styrene has been grafted into PVDF. The conductivity of PVDF-g-PSSA electrolyte doped 10% plain sodium silicate (Na4SiO4) is 0.016 S/cm at room temperature. The conductivity of the electrolyte changes slightly at a relative humidity range of 20%-70%. The weightlessness of PVDF-g-PSSA electrolyte heated to 40°C was less than 2%, which indicated that water capacity was good.

Stability of extemporaneously prepared rosuvastatin oral suspension

2017 ◽  
Vol 74 (19) ◽  
pp. 1579-1583 ◽  
Author(s):  
Abdel Naser Zaid ◽  
Rania Shtayah ◽  
Ayman Qadumi ◽  
Mashour Ghanem ◽  
Rawan Qedan ◽  
...  
Keyword(s):  
Relative Humidity ◽  
High Performance ◽  
Room Temperature ◽  
Microbial Contamination ◽  
Active Pharmaceutical Ingredient ◽  
Storage Conditions ◽  
Dissolution Profile ◽  
Stability Studies ◽  
Organoleptic Properties ◽  
The Stability

Abstract Purpose The stability of an extemporaneously prepared rosuvastatin suspension stored over 30 days under various storage conditions was evaluated. Methods Rosuvastatin suspension was extemporaneously prepared using commercial rosuvastatin tablets as the source of active pharmaceutical ingredient. The organoleptic properties, dissolution profile, and stability of the formulation were investigated. For the stability studies, samples of the suspension were stored under 2 storage conditions, room temperature (25 °C and 60% relative humidity) and accelerated stability chambers (40 °C and 75% relative humidity). Viscosity, pH, organoleptic properties, and microbial contamination were evaluated according to the approved specifications. High-performance liquid chromatography was used for the analysis and quantification of rosuvastatin in selected samples. Microbiological investigations were also conducted. Results The prepared suspension showed acceptable organoleptic properties. It showed complete release of rosuvastatin within 15 minutes. The pH of the suspension was 9.8, which remained unchanged during the stability studies. The microbiological investigations demonstrated that the preparation was free of any microbial contamination. In addition, the suspension showed stability within at least the period of use of a 100-mL rosuvastatin bottle. Conclusion Extemporaneously prepared rosuvastatin 20-mg/mL suspension was stable for 30 days when stored at room temperature.

scholarly journals Limiting the Oxidation of WS2 Nanostructures by Oleylamine Surface Passivation for Room Temperature NH3 Sensing

2020 ◽  
Author(s):  
Siziwe Gqoba ◽  
Rafael Rodrigues ◽  
Sharon Lerato Mphahlele ◽  
Zakhele Ndala ◽  
Mildred Airo ◽  
...  
Keyword(s):  
Relative Humidity ◽  
Room Temperature ◽  
Surface Passivation ◽  
Electrical Response ◽  
Prolonged Incubation ◽  
P Type ◽  
2D Nanosheets ◽  
Type Response ◽  
And Diffusion ◽  
Hierarchical Morphology

Oleylamine capped WS2 nanostructures were successfully formed at 320 °C via a relatively simple colloidal route. SEM and TEM analyses showed that the 3D nanoflowers that were initially formed disintegrated into 2D nanosheets after prolonged incubation. XPS and XRD analyses confirmed oxidation of WS2 into WO3. Sensors based on these oleylamine capped WS2 nanoflowers and nanosheets still showed a change in electrical response towards various concentrations of NH3 vapour at room temperature in a 25% relative humidity background despite the oxidation. The nanoflowers exhibited n-type response while the nanosheets displayed a p-type response towards NH3 exposure. The nanoflower based sensors showed better response to NH3 vapour exposure than the nanosheets. The sensors showed a good selectivity towards NH3 relative to acetone, ethanol, chloroform and toluene. Meanwhile, a strong interference of humidity to the NH3 response was displayed at high relative humidity levels. The results demonstrated that oleylamine limited the extent of oxidation of WS2 nanostructures. The superior sensing performance of the nanoflowers can be attributed to their hierarchical morphology which enhances the surface area and diffusion of the analyte.

STUDIES OF THE AGING OF CONIDIA OF MONILINIA FRUCTICOLA (WINT.) HONEY: I.GERMINATION RATES AND LONGEVITY

1957 ◽  
Vol 35 (5) ◽  
pp. 635-645 ◽  
Author(s):  
S. H. Z. Naqvi ◽  
H. M. Good
Keyword(s):  
Relative Humidity ◽  
Storage Temperature ◽  
Potato Dextrose Agar ◽  
Monilinia Fructicola ◽  
High Humidity ◽  
Percentage Germination ◽  
Low Humidity ◽  
Nutrient Solutions

Conidia of Monilinia fructicola (Wint.) Honey were stored 1–10 months at temperatures of 5°, 25°, and 35 °C. and at constant relative humidities approximating 0, 15, 45, 75, and 90%. The germination of these spores was tested on potato dextrose agar containing 6% glucose, and curves of the percentage germination against time are given for representative samples.A pronounced delay in germination developed under all conditions of storage. The rate at which this delay developed was virtually independent of the storage temperature. All spore samples gave 100% germination after 3 months but only those at 5 °C. gave; any germination after 10 months. Storage in a relative humidity of 75% gave the best preservation of spore vigor, there being evidence in other conditions of either high humidity or low humidity injury. Of the nutrient solutions tested, glucose was the only one which gave substantially better germination than water, the effect being most marked on spores stored for some months at high humidity. With glucose, such spores sometimes germinated faster than those stored at intermediate humidities.

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