Reaction between Ferric Oxide and Barium Carbonate in the Solid Phase. Identification of Phases by X-Ray Diffraction1

1946 ◽  
Vol 68 (10) ◽  
pp. 2085-2093 ◽  
Author(s):  
Michael Erchak ◽  
I. Fankuchen ◽  
Roland Ward
Keyword(s):  
Ferric Oxide ◽  
Solid Phase ◽  
Barium Carbonate ◽  
Phase Identification ◽  
X Ray

Stimulation of Wells Damaged by Barite Present in Filter Cake or Scale

SPE Journal ◽  
2021 ◽  
pp. 1-11
Author(s):  
Igor Ivanishin ◽  
Hisham A. Nasr-El-Din ◽  
Dmitriy Solnyshkin ◽  
Artem Klyubin
Keyword(s):  
High Temperature ◽  
Filter Cake ◽  
Ethylenediaminetetraacetic Acid ◽  
Solid Phase ◽  
Barium Carbonate ◽  
Process Analysis ◽  
Drilling Fluid ◽  
Field Application ◽  
X Ray ◽  
Dissolution Efficiency

Summary High-temperature (HT) deep carbonate reservoirs are typically drilled using barite (BaSO4) as a weighting material. Primary production in these tight reservoirs comes from the network of natural fractures, which are damaged by the invasion of mud filtrate during drilling operations. For this study, weighting material and drilling fluid were sampled at the same drillsite. X-ray diffraction (XRD) and X-ray fluorescence analyses confirmed the complex composition of the weighting material: 43.2 ± 3.8 wt% of BaSO4 and 47.8 ± 3.3 wt% of calcite (CaCO3); quartz and illite comprised the rest. The drilling fluid was used to form the filter cake in a high-pressure/high-temperature (HP/HT) filter-press apparatus at a temperature of 300°F and differential pressure of 500 psig. Compared with the weighting material, the filter cake contained less CaCO3, but more nondissolvable minerals, including quartz, illite, and kaolinite. This difference in mineral composition makes the filter cake more difficult to remove. Dissolution of laboratory-grade BaSO4, the field sample of the weighting material, and drilling-fluid filter cake were studied at 300°F and 1,000 to 1,050 psig using an autoclave equipped with a magnetic stirrer drive. Two independent techniques were used to investigate the dissolution process: analysis of the withdrawn-fluid samples using inductively coupled plasma-optical emission spectroscopy, and XRD analysis of the solid material left after the tests. The dissolution efficiency of commercial K5-diethylenetriaminepentaacetic acid (DTPA), two K4-ethylenediaminetetraacetic acid (EDTA), Na4-EDTA solutions, and two “barite dissolvers” of unknown composition was compared. K5-DTPA and K4-EDTA have similar efficiency in dissolving BaSO4 as a laboratory-grade chemical and a component of the calcite-containing weighting material. No pronounced dissolution-selectivity effect (i.e., preferential dissolution of CaCO3) was noted during the 6-hour dissolution tests with both solutions. Reported for the first time is the precipitation of barium carbonate (BaCO3) when a mixture of BaSO4 and CaCO3 is dissolved in DTPA or EDTA solutions. BaCO3 composes up to 30 wt% of the solid phase at the end of the 6-hour reaction, and can be dissolved during the field operations by 5 wt% hydrochloric acid. Being cheaper, K4-EDTA is the preferable stimulation fluid. Dilution of this chelate increases its dissolution efficiency. Compared with commonly recommended solutions of 0.5 to 0.6 M, a more dilute solution is suggested here for field application. The polymer breaker and K4-EDTA solution are incompatible; therefore, the damage should be removed in two stages if the polymer breaker is used.

Phase identification in SiC whisker reinforced Al2O3-R2O3-based composites

1992 ◽  
Vol 50 (1) ◽  
pp. 152-153
Author(s):  
C.M. Sung ◽  
K.J. Ostreicher ◽  
M.L. Huckabee ◽  
S.T. Buljan
Keyword(s):  
Analytical Electron Microscopy ◽  
Phase Identification ◽  
Reinforced Composites ◽  
Ion Milling ◽  
X Ray ◽  
Binary Oxides ◽  
Analytical Electron ◽  
The Matrix ◽  
Second Phases ◽  
Convergent Beam

A series of binary oxides and SiC whisker reinforced composites both having a matrix composed of an α-(Al, R)2O3 solid solution (R: rare earth) have been studied by analytical electron microscopy (AEM). The mechanical properties of the composites as well as crystal structure, composition, and defects of both second phases and the matrix were investigated. The formation of various second phases, e.g. garnet, β-Alumina, or perovskite structures in the binary Al2O3-R2O3 and the ternary Al2O3-R2O3-SiC(w) systems are discussed.Sections of the materials having thicknesses of 100 μm - 300 μm were first diamond core drilled. The discs were then polished and dimpled. The final step was ion milling with Ar+ until breakthrough occurred. Samples prepared in this manner were then analyzed using the Philips EM400T AEM. The low-Z energy dispersive X-ray spectroscopy (EDXS) data were obtained and correlated with convergent beam electron diffraction (CBED) patterns to identify phase compositions and structures. The following EDXS parameters were maintained in the analyzed areas: accelerating voltage of 120 keV, sample tilt of 12° and 20% dead time.

Impact of Rutile Fraction on TiO2 Visible-Light Absorption and Visible-Light-Induced Photocatalytic Activity

2018 ◽  
Author(s):  
David Maria Tobaldi ◽  
Luc Lajaunie ◽  
ana caetano ◽  
nejc rozman ◽  
Maria Paula Seabra ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Light Absorption ◽  
Solid Phase ◽  
Diffraction Method ◽  
Band Alignment ◽  
Quantitative Phase Analysis ◽  
Transmission Microscopy ◽  
Visible Light Absorption ◽  
X Ray

<div>Titanium dioxide is by far the most utilised semiconductor material for photocatalytic applications. Still, it is transparent to visible-light. Recently, it has been proved that a type-II band alignment for the rutile−anatase mixture would improve its visible-light absorption.</div><div>In this research paper we thoroughly characterised the real crystalline and amorphous phases of synthesised titanias – thermally treated at different temperatures to get distinct ratios of anatase-rutile-amorphous fraction – as well as that of three commercially available photocatalytic nano-TiO2. </div><div>The structural characterisation was done via advanced X-ray diffraction method, namely the Rietveld-RIR method, to attain a full quantitative phase analysis of the specimens. The microstructure was also investigated via an advanced X-ray method, the whole powder pattern modelling. These methods were validated combining advanced aberration-corrected scanning transmission microscopy and high-resolution electron energy-loss spectroscopy. The photocatalytic activity was assessed in the liquid- and gas-solid phase (employing rhodamine B and 4-chlorophenol, and isopropanol, respectively, as the organic substances to degrade) using a light source irradiating exclusively in the visible-range.</div><div>Optical spectroscopy showed that even a small fraction of rutile (2 wt%) is able to shift to lower energies the apparent optical band gap of an anatase-rutile mixed phase. But is this enough to attain a real photocatalytic activity promoted by merely visible-light?</div><div>We tried to give a reply to that question.</div><div>Photocatalytic activity results in the liquid-solid phase showed that a high surface hydroxylation led to specimen with superior visible light-induced catalytic activity (i.e. dye and ligand-to-metal charge transfer complexes sensitisation effects). That is: not photocatalysis <i>sensu-strictu</i>.</div><div>On the other hand, the gas-solid phase results showed that a higher amount of the rutile fraction (around 10 wt%), together with less recombination of the charge carriers, were more effective for an actual photocatalytic oxidation of isopropanol.</div>

scholarly journals Preliminary Study of the Targeted Cleaning of an Artificial Gypsum Layer on White Marble

Coatings ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 37
Author(s):  
Yan Liu ◽  
Taoling Dong ◽  
Kun Zhang ◽  
Fuwei Yang ◽  
Liqin Wang
Keyword(s):  
Electron Microscopy ◽  
Barium Carbonate ◽  
Color Difference ◽  
X Ray Diffraction ◽  
White Marble ◽  
Capillary Suction ◽  
Sulfate Ions ◽  
X Ray ◽  
Preliminary Study ◽  
Scanning Electron

Targeting cleaning of the artificial gypsum layer on white marble was studied. It was conducted by means of the specific depletion of the calcium and sulfate ions by the barium carbonate scavenger, which led to the continuous dissolution and clearance of gypsum layer. The cleaning effect was evaluated by scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDX), X-ray diffraction (XRD), capillary suction, and color difference measurement. By this method, only the gypsum layer was cleared away and the carbonate substrate of marble was left intact at the same time. This method will be highly useful for the conservation of marble relics from surface weathering.

Control of trace elements content in solid-phase extraction sorbent by x-ray fluorescence analysis

2020 ◽  
Author(s):  
E. V. Kochergina ◽  
A. O. Vagina ◽  
A. O. Taukin ◽  
A. V. Abramov ◽  
G. M. Bunkov ◽  
...  
Keyword(s):  
Trace Elements ◽  
Solid Phase Extraction ◽  
Solid Phase ◽  
Fluorescence Analysis ◽  
Phase Extraction ◽  
X Ray

scholarly journals An Insight into Chemistry and Structure of Colloidal 2D-WS2 Nanoflakes: Combined XPS and XRD Study

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1969
Author(s):  
Riccardo Scarfiello ◽  
Elisabetta Mazzotta ◽  
Davide Altamura ◽  
Concetta Nobile ◽  
Rosanna Mastria ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Xrd Analysis ◽  
Crystal Habit ◽  
Phase Identification ◽  
X Ray Diffraction ◽  
X Ray ◽  
Morphological Evaluation ◽  
Rational Understanding ◽  
Structural Inspection

The surface and structural characterization techniques of three atom-thick bi-dimensional 2D-WS2 colloidal nanocrystals cross the limit of bulk investigation, offering the possibility of simultaneous phase identification, structural-to-morphological evaluation, and surface chemical description. In the present study, we report a rational understanding based on X-ray photoelectron spectroscopy (XPS) and structural inspection of two kinds of dimensionally controllable 2D-WS2 colloidal nanoflakes (NFLs) generated with a surfactant assisted non-hydrolytic route. The qualitative and quantitative determination of 1T’ and 2H phases based on W 4f XPS signal components, together with the presence of two kinds of sulfur ions, S22− and S2−, based on S 2p signal and related to the formation of WS2 and WOxSy in a mixed oxygen-sulfur environment, are carefully reported and discussed for both nanocrystals breeds. The XPS results are used as an input for detailed X-ray Diffraction (XRD) analysis allowing for a clear discrimination of NFLs crystal habit, and an estimation of the exact number of atomic monolayers composing the 2D-WS2 nanocrystalline samples.

Wide angle X-ray diffraction study of the solid-phase chlorinated poly(ethylene)

Polymer ◽  
2004 ◽  
Vol 45 (18) ◽  
pp. 6341-6348 ◽  
Author(s):  
S. Stoeva ◽  
A. Popov ◽  
R. Rodriguez
Keyword(s):  
Diffraction Study ◽  
Solid Phase ◽  
Wide Angle ◽  
X Ray Diffraction ◽  
X Ray ◽  
Poly Ethylene

scholarly journals Characterization of Spent Ni-MH Batteries

2012 ◽  
Vol 730-732 ◽  
pp. 569-574
Author(s):  
Marta Cabral ◽  
Fernanda Margarido ◽  
Carlos A. Nogueira
Keyword(s):  
Quantitative Analysis ◽  
Electrode Materials ◽  
Phase Identification ◽  
Recycling Process ◽  
X Ray ◽  
Leaching Experiments ◽  
Plastic Components ◽  
Definition Of ◽  
Physical And Chemical

Spent Ni-MH batteries are not considered too dangerous for the environment, but they have a considerable economical value due to the chemical composition of electrodes which are highly concentrated in metals. The present work aimed at the physical and chemical characterisation of spent cylindrical and thin prismatic Ni-MH batteries, contributing for a better definition of the recycling process of these spent products. The electrode materials correspond to more than 50% of the batteries weight and contain essentially nickel and rare earths (RE), and other secondary elements (Co, Mn, Al). The remaining components are the steel parts from the external case and supporting grids (near 30%) containing Fe and Ni, and the plastic components (<10%). Elemental quantitative analysis showed that the electrodes are highly concentrated in metals. Phase identification by X-ray powder diffraction combined with chemical analysis and leaching experiments allowed advancing the electrode materials composition. The cathode is essentially constituted by 6% metallic Ni, 66% Ni(OH)2, 4.3% Co(OH)2 and the anode consists mainly in 62% RENi5 and 17% of substitutes and/or additives such as Co, Mn and Al.

PREPARATION OF ANTIMONY-PLATINUM SURFACE ALLOY ELECTRODE BY ATOM DIFFUSION IN THE SOLID PHASE

2006 ◽  
Vol 20 (25n27) ◽  
pp. 3999-4004
Author(s):  
HIROSHI MATSUI ◽  
KAZUFUMI WATANABE
Keyword(s):  
Diffraction Pattern ◽  
Low Temperatures ◽  
Solid Phase ◽  
Electrochemical Measurement ◽  
X Ray Diffraction ◽  
Platinum Surface ◽  
X Ray ◽  
Atom Diffusion ◽  
Heat Treated ◽  
Titanium Substrates

Antimony-platinum bilayers were prepared on titanium substrates by the two-step electrodeposition in the usual baths, and then surface alloys were formed by the atom diffusion in the solid phase. The simple antimony layer was little influenced by the substrate in both the measurements of X-ray diffraction and the i - E characteristic in a sulfuric acid solution. Regarding the bilayers, the catalytic activity in hydrogen evolution reaction was very sensitive to the presence of platinum, while the hydrogen adsorbability was quite insensitive. An interaction between antimony and platinum was confirmed by the appearance of a new dissolution wave in the electrochemical measurement and the occurrence of a new diffraction in the X-ray diffraction pattern after the heat-treatment of about 400°C. Although the new diffraction disagreed with any of the reported alloys, clear diffraction pattern of PtSb 2 alloy was observed, when the bilayers were heat-treated at about 600°C for one hour. Considering the penetration depth of X-ray, the alloying of antimony and platinum seems to occur also at low temperatures at least at the top surface.

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