scholarly journals Rheological, physical, and mechanical properties of chicken skin gelatin films incorporated with potato starch

2019 ◽  
Vol 3 (1) ◽  
Author(s):  
Syazwani Aqilah Alias ◽  
Norizah Mhd Sarbon

AbstractThe aim of this study was to investigate the rheological, physical, and mechanical properties of chicken skin gelatin film forming solutions (FFSs) and films incorporated with potato starch. Chicken skin gelatin-based FFSs with various potato starch concentrations (0, 2, 4, 6, 8, and 10%, w/w) were prepared via casting technique. The dynamic viscoelastic properties of FFS were measured, and film characterization in terms of physical and mechanical properties was conducted. Potato starch incorporation with chicken skin gelatin-based FFS resulted in improvement of viscous behavior (G″ > G′). As potato starch concentration increased, the tensile strength, elongation at break, and elastic modulus values of chicken skin gelatin-based films also increased (p < 0.05). Additionally, increasing the concentration of potato starch caused incremental changes in water vapor permeability and melting temperatures (Tm), but a reduction in water solubility (p < 0.05). In addition, the surface smoothness and internal structure of composite films improved via potato starch incorporation. The incorporation of potato starch was also found to provide good barrier properties against ultraviolet and visible light, but did not significantly influence the transparency values of composite films. Overall, chicken skin gelatin film with 6% potato starch concentration incorporation was the most promising composite film, since it was found to exhibit optimal performance in terms of physical properties.

Polymers ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 4406
Author(s):  
Anita Kwaśniewska ◽  
Michał Świetlicki ◽  
Adam Prószyński ◽  
Grzegorz Gładyszewski

In the present study, starch/powdered activated carbon composite films were prepared by incorporating various amounts of powdered activated carbon (PAC)—1–5, 10, and 15 %—into a starch matrix, using the solvent casting method. The effect of PAC addition on the biopolymer film was investigated. The mechanical properties were examined by ultra-nanoindentation, nanoscratch, and micro-tensile tests. Since the mechanical properties of biopolymer films are correlated with their structure, the effect of PAC addition was tested using X-ray diffraction. The surface parameters morphology and wettability were analyzed by atomic force microscopy (AFM) and contact angle measurements. The barrier properties were examined by determining water vapor permeability and the water solubility index. The obtained results did not show a monotonic dependence of the mechanical parameters on PAC content, with the exception of the maximum strain, which decreased as the amount of the additive increased. The visible effect of PAC addition was manifested in changes in the adhesive force value and in water vapor permeability (WVP). The barrier properties decreased with the increase of the filler content.


2014 ◽  
Vol 881-883 ◽  
pp. 1153-1156 ◽  
Author(s):  
Yun Bin Zhang ◽  
Jing Wen Wang ◽  
Ping Ping Jiang ◽  
Yue Xia Li ◽  
Xiao Yu Liu

Florida mandarin oil-chitosan composite films were prepared with chitosan (CS), Florida mandarin oil (FMO) by casting-evaporation-alkali leaching method. Influences of FMO to mechanical properties, water contact angle, water-solubility of films were evaluated. The results demonstrated that decrease of film tensile strength was caused by addition of FMO. When FMO content was 4%, elongation at break reached the maximum (2.81±0.01%). Water contact angle and solubility of film increased with increase of FMO content, maximums were 81.80±0.09° and 1.51±0.02 mg/100 g H2O, respectively.


MRS Advances ◽  
2016 ◽  
Vol 2 (1) ◽  
pp. 57-62 ◽  
Author(s):  
Eunice Cunha ◽  
Fernando Duarte ◽  
M. Fernanda Proença ◽  
M. Conceição Paiva

ABSTRACTGraphite nanoplates (GnP) have recently attracted attention as an economically viable alternative for the development of functional and structural nanocomposites. The incorporation of GnP into waterborne polyurethane (WPU) with loadings from 0.1 to 10 wt.% was studied. The mechanical properties of the composite films were assessed by tensile testing showing an increase of the Young’s modulus up to 48%. The electrical conductivity increased by 9 orders of magnitude and the water vapor permeability of the composite films decreased 57% for composites containing 5.0 wt.% of GnP.


2015 ◽  
Vol 16 (3) ◽  
pp. 528-533
Author(s):  
G. Martinyuk ◽  
O. Aksimentyeva ◽  
N. Skoreiko ◽  
V. Zakordonskyi

We investigated the processes of water absorption, chemical stability and microhardness of films of epoxy composites that contained as the polymer matrix the epoxy resin UP-655 and mineral fillers: graphite, mica, aluminum oxide at their content (0 - 30 % mass). It found that introduction of mineral fillers significantly affects on all complex of operating characteristics of the films. Increase of filler content, especially mica, to 20 %, resulting in slower process and reducing the quantity of absorbed moisture by films. In the study of physical and mechanical properties of filled epoxy composites was established that the introduction of mineral filler significantly affects their microhardness, and the nature of the exposure is determined by the type and filler content.


Author(s):  
Jie Liu ◽  
Yanchun Liu ◽  
Eleanor M. Brown ◽  
Zhengxin Ma ◽  
Cheng-Kung Liu

The leather industry generates considerable amounts of solid waste and raises many environmental concerns during its disposal. The presence of collagen in these wastes provides a potential protein source for the fabrication of bio-based value-added products. Herein, a novel composite film was fabricated by incorporating vegetable-tanned collagen fiber (VCF), a mechanically ground powder-like leather waste, into a chitosan matrix and crosslinked with genipin. The obtained composite film showed a compact structure and the hydrogen bonding interactions were confirmed by FTIR analysis, indicating a good compatibility between chitosan and VCF. The optical properties, water absorption capacity, thermal stability, water vapor permeability and mechanical properties of the composite films were characterized. The incorporation of VCF into chitosan led to significant decreases in opacity and solubility of the films. At the same time, the mechanical properties, water vapor permeability and thermal stability of the films were improved. The composite film exhibited antibacterial activity against food-borne pathogens. Results from this research indicated the potential of the genipin-crosslinked chitosan/VCF composites for applications in antimicrobial packaging. 


2020 ◽  
Vol 26 (8) ◽  
pp. 666-675
Author(s):  
Zahra Moradi

Considering environmental pollution caused by the non-biodegradable polymers used in food packaging, developing and enhancing the properties of biodegradable films seem to be necessary. For this aim, in the present study, kefiran-whey protein isolate bionanocomposite films were prepared and the impact of different concentrations (1, 3 and 5% w/w) of Al2O3 (alumina) nanoparticles on their physical, morphological, thermal and mechanical properties was studied. Based on the obtained results, an increase in the nanoparticles content led to a significant decrease (p < 0.05) in the water vapor permeability, moisture absorption, moisture content, and water solubility. Scanning electron microscope images showed a homogeneous structure, confirming the good dispersion of alumina nanoparticles with smooth surface up to concentration of 3%. In addition, both thermal stability and mechanical properties of the films were improved by the increased concentrations of alumina. The results of X-ray diffraction indicated that the intensity of the crystalline peaks of film increased with the addition of Al2O3 to kefiran-whey protein isolate matrix. By considering all results, the concentration of 3% was proposed as the appropriate concentration of Al2O3 for the nano-reinforcement of kefiran-whey protein isolate bionanocomposites.


Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1091 ◽  
Author(s):  
Eftihia Barnes ◽  
Jennifer A. Jefcoat ◽  
Erik M. Alberts ◽  
Mason A. McKechnie ◽  
Hannah R. Peel ◽  
...  

Cellulose nanofibrils (CNFs) are high aspect ratio, natural nanomaterials with high mechanical strength-to-weight ratio and promising reinforcing dopants in polymer nanocomposites. In this study, we used CNFs and oxidized CNFs (TOCNFs), prepared by a 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation process, as reinforcing agents in poly(vinylidene fluoride) (PVDF). Using high-shear mixing and doctor blade casting, we prepared free-standing composite films loaded with up to 5 wt % cellulose nanofibrils. For our processing conditions, all CNF/PVDF and TOCNF/PVDF films remain in the same crystalline phase as neat PVDF. In the as-prepared composites, the addition of CNFs on average increases crystallinity, whereas TOCNFs reduces it. Further, addition of CNFs and TOCNFs influences properties such as surface wettability, as well as thermal and mechanical behaviors of the composites. When compared to neat PVDF, the thermal stability of the composites is reduced. With regards to bulk mechanical properties, addition of CNFs or TOCNFs, generally reduces the tensile properties of the composites. However, a small increase (~18%) in the tensile modulus was observed for the 1 wt % TOCNF/PVDF composite. Surface mechanical properties, obtained from nanoindentation, show that the composites have enhanced performance. For the 5 wt % CNF/PVDF composite, the reduced modulus and hardness increased by ~52% and ~22%, whereas for the 3 wt % TOCNF/PVDF sample, the increase was ~23% and ~25% respectively.


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