scholarly journals Tough metal-ceramic composites with multifunctional nacre-like architecture

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Erik Poloni ◽  
Florian Bouville ◽  
Christopher H. Dreimol ◽  
Tobias P. Niebel ◽  
Thomas Weber ◽  
...  

AbstractThe brick-and-mortar architecture of biological nacre has inspired the development of synthetic composites with enhanced fracture toughness and multiple functionalities. While the use of metals as the “mortar” phase is an attractive option to maximize fracture toughness of bulk composites, non-mechanical functionalities potentially enabled by the presence of a metal in the structure remain relatively limited and unexplored. Using iron as the mortar phase, we develop and investigate nacre-like composites with high fracture toughness and stiffness combined with unique magnetic, electrical and thermal functionalities. Such metal-ceramic composites are prepared through the sol–gel deposition of iron-based coatings on alumina platelets and the magnetically-driven assembly of the pre-coated platelets into nacre-like architectures, followed by pressure-assisted densification at 1450 °C. With the help of state-of-the-art characterization techniques, we show that this processing route leads to lightweight inorganic structures that display outstanding fracture resistance, show noticeable magnetization and are amenable to fast induction heating. Materials with this set of properties might find use in transport, aerospace and robotic applications that require weight minimization combined with magnetic, electrical or thermal functionalities.

2014 ◽  
Vol 602-603 ◽  
pp. 252-257
Author(s):  
Xiao Bo Lu ◽  
Hong Bo Liu ◽  
Yu Fei Zhang

By introducing ZrO2 (4Y) powder into the thermit, the solidified Al2O3-ZrO2 (4Y) ceramic composites with eutectic and hypereutectic microstructures were prepared via combustion synthesis in high gravity field, and the microstructures and mechanical properties of the solidified ceramic composites were discussed. XRD, SEM and EDS showed that the Al2O3-33%ZrO2 (4Y) as the eutectic were composed of random-orientated rod-shaped colonies consisting of a triangular dispersion of orderly submicron-nanometer t-ZrO2 fibers, surrounded by inter-colony regions consisting of spherically-shaped micrometer t-ZrO2 grains, whereas Al2O3-45%ZrO2 (4Y) as the hypereutectic were comprised of spherically-shaped micron-meter t-ZrO2 grains, surround by irregularly-shaped α-Al2O3 grains and a few colonies. Compared to the directionally solidified Al2O3-ZrO2 (Y2O3), the increase in hardness and flexural strength of the eutectic obtained in current experiment was due to high densification, small-size defect and high fracture toughness induced by residual stress toughening and transformation toughening mechanisms; meanwhile, in despite of the moderate decrease in hardness, high flexural strength of the hypereutectic was considered to be a result of small-size defect and high fracture toughness induced by transformation toughening and microcrack toughening mechanisms.


Materials ◽  
2003 ◽  
Author(s):  
N. Orlovskaya ◽  
J. Adams ◽  
M. Chheda ◽  
J. Shih ◽  
S. Yarmolenko ◽  
...  

The paper describes the development of tough boron carbide-silicon carbide ceramic laminates with enhanced ballistic performance for armor application. Laminates with strong interfaces can provide high fracture toughness and damage tolerance along with improved ballistic protection. The enhancement of the mechanical/ballistic performance of laminates is obtained through design of controlled residual stresses in separate layers. The research produced a fundamental knowledge of the interrelationships between processing, residual stresses, and mechanical behavior of boron carbide based multilayered ceramic composites with an enhanced understanding of laminate’s fracture toughness, strength, and Young’s modulus. It was expected that the newly developed laminates would have necessary mechanical properties to increase maximum critical velocity of dwell/penetration transition during impact experiments.


Alloy Digest ◽  
2000 ◽  
Vol 49 (1) ◽  

Abstract Kaiser Aluminum Alloy 7050 has very high mechanical properties including tensile strength, high fracture toughness, and a high resistance to exfoliation and stress-corrosion cracking. The alloy is typically used in aircraft structural parts. This datasheet provides information on composition, physical properties, hardness, tensile properties, and shear strength as well as fracture toughness and fatigue. It also includes information on forming, heat treating, machining, and joining. Filing Code: AL-366. Producer or source: Tennalum, A Division of Kaiser Aluminum.


Alloy Digest ◽  
2018 ◽  
Vol 67 (9) ◽  

Abstract Ferrium M54 was designed to create a cost-effective, ultra high-strength, high-fracture toughness material with a high resistance to stress-corrosion cracking for use in structural applications. This datasheet provides information on composition, hardness, and tensile properties as well asfatigue. Filing Code: SA-822. Producer or source: QuesTek Innovations, LLC.


2015 ◽  
Vol 83 (3) ◽  
Author(s):  
Zhuo Ma ◽  
Xiangchao Feng ◽  
Wei Hong

Consisting of stretchable and flexible cell walls or ligaments, soft elastic foams exhibit extremely high fracture toughness. Using the analogy between the cellular structure and the network structure of rubbery polymers, this paper proposes a scaling law for the fracture energy of soft elastic foam. To verify the scaling law, a phase-field model for the fracture processes in soft elastic structures is developed. The numerical simulations in two-dimensional foam structures of various unit-cell geometries have all achieved good agreement with the scaling law. In addition, the dependences of the macroscopic fracture energy on geometric parameters such as the network connectivity and spatial orientation have also been revealed by the numerical results. To further enhance the fracture toughness, a type of soft foam structures with nonstraight ligaments or folded cell walls has been proposed and its performance studied numerically. Simulations have shown that an effective fracture energy one order of magnitude higher than the base material can be reached by using the soft foam structure.


1998 ◽  
Vol 13 (4) ◽  
pp. 803-811 ◽  
Author(s):  
Philippe Colomban

The problems encountered to tailor simultaneously various specific chemical or physical properties are discussed. Selected polymeric precursors used in association with fine powders allow the control of the nano/microstructure of composites and hence the preparation of functional (FGM) and hierarchical reinforced (HRC) composites, making it possible to combine several kinds of fibers, interphases, and matrices in the same composite (hot microwave absorbent), to control the fiber/matrix interface (long life times composites), to achieve net-shape sintering of 3D composite matrices, and to prepare thick films of metal-ceramic composites with tailored microwave absorption (radar stealthiness).


Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 393
Author(s):  
Kei Maeda ◽  
Kosho Akatsuka ◽  
Gaku Okuma ◽  
Atsuo Yasumori

Fracture behavior via a flexural test for a newly found CaO–Al2O3–SiO2 (CAS) glass-ceramic (GC) was compared with that of enstatite GC and mica GC, which are well-known GCs with high-fracture toughness and machinability, respectively. By focusing on the nonelastic load–displacement curves, CAS GC was characterized as a less brittle material similar to machinable mica GC, compared with enstatite GC, which showed higher fracture toughness, KIC. The microcrack toughening mechanism in CAS GC was supported by the nondestructive observation of microcracks around the Vickers indentation using the X-ray microcomputed tomography technique. The CAS GC also showed higher transparency than mica GC due to its low crystallinity. Moreover, the precursor glass had easy formability due to its low-liquidus temperature.


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