scholarly journals Operating envelope of Haber–Bosch process design for power-to-ammonia

RSC Advances ◽  
2018 ◽  
Vol 8 (61) ◽  
pp. 34926-34936 ◽  
Author(s):  
Izzat Iqbal Cheema ◽  
Ulrike Krewer

The Haber–Bosch process is viable for power-to-ammonia, as it can be operated for a wide range of the operating envelope while maintaining the process variables' operational, hydrogen feed intake and ammonia production flexibilities.

2017 ◽  
Vol 27 (8) ◽  
pp. 707-722 ◽  
Author(s):  
Longfei Chen ◽  
Liuyang Feng ◽  
Zhixin Liu ◽  
Guangze Li ◽  
Yanfei Li ◽  
...  

2021 ◽  
Vol 13 (13) ◽  
pp. 7080
Author(s):  
Steve Kgotlelelo Mahlake ◽  
Caven Mguvane Mnisi ◽  
Cornelia Lebopa ◽  
Cebisa Kumanda

Green tea leaves contain a wide range of active bio-compounds that are essential for sustainable quail intensification; however, its feed value is not known for the Jumbo quail. Therefore, this study evaluated the effect of different levels of green tea leaf powder (GTLP) on physiological and meat quality parameters of the Jumbo quail. One-week-old chicks (n = 350; 56.1 ± 2.12 g live-weight) were evenly distributed to 35 replicate pens and reared on five experimental diets formulated as follows: a standard grower diet with zinc-bacitracin (PosCon), a standard grower diet without zinc-bacitracin (NegCon), and NegCon diet treated with 10 (GT10), 25 (GT25) and 50 g/kg (GT50) of GTLP. Weight gain linearly decreased in week 2 but increased in week 4, whereas feed conversion efficiency linearly declined in weeks 2 and 3 as GTLP levels increased. Overall feed intake, carcass yield, and caecum and colon weights showed a linear increase with GTLP levels. Hematological parameters fell within the normal ranges reported for healthy quail. The GT10 group showed larger liver weights than the PosCon and NegCon groups. It was concluded that dietary inclusion of GTLP enhances overall feed intake and carcass performance but not feed efficiency, hematological and meat quality parameters of Jumbo quail.


2009 ◽  
Vol 2009 ◽  
pp. 1-12 ◽  
Author(s):  
Rolf K. Eckhoff

Right from the early days of the process industries, continuous efforts have been made to develop and improve measures for prevention and mitigation of dust explosions in these industries. Nevertheless this hazard continues to threaten industries that manufacture, use and/or handle powders and dusts of a wide range of combustible materials. To improve methods for predicting explosion development in real industrial plant has been one major challenge. Hence, during the last years comprehensive numerical simulation codes, for addressing this problem, have been developed. Progress has also been made in other areas, for example, ignition source prevention. The importance of adopting inherently safer process design, by building on firm knowledge in powder science and technology, and of systematic education/training of personnel, is also emphasized.


2021 ◽  
Vol 99 (Supplement_3) ◽  
pp. 98-99
Author(s):  
Timothy DelCurto ◽  
Sam Wyffels

Abstract Designing research for beef cattle production in rangeland environments is an ongoing challenge for researchers worldwide. Specifically, creating study designs that mirror actual production environments yet have enough observations for statistical inference is a challenge that often hinders researchers in efforts to publish their observations. Numerous journals will accept “case study” or observational results that lack valid statistical inference. However, these journals are limited in number and often lack impact. Approaches are available to gain statistical inference by creating multiple observations within a common group of animals. Approaches to increasing statistical observations will be discussed in this presentation. Modeling animal behavior and performance on extensive rangeland landscapes is commonly practiced in wildlife ecology and, more recently, has been published in Animal Science journals. Additionally, new technology has made it possible to apply treatments (e.g., supplementation studies) to individual animals on extensive environments where large, diverse herds/flocks of cattle/sheep are managed as a single group. Use of individual animal identification (EID) and feed intake technology has opened a wide range of research possibilities for beef cattle production systems research in rangeland environments. Likewise, global positioning system (GPS) collars and activity monitors have created the opportunity to evaluate animal grazing behavior in remote and extensive landscapes. The use of multiple regression models to evaluate resource use in extensive environments will, in turn, help managers optimize beef cattle production and the sustainable use of forage/rangeland resources. Embracing new technologies such as GPS, activity monitors, EID tags, and feed intake monitors combined with multiple regression modeling tools will aid in designing and publishing beef cattle production research in extensive rangeland environments.


2018 ◽  
Vol 7 (3) ◽  
pp. 50
Author(s):  
Blanca I. Maldonado-Guevara ◽  
Sandra T. Martín del Campo ◽  
Anaberta Cardador-Martínez

In this work, the quality parameters of commercial agave syrups produced in five different Mexican states and with different production process were evaluated. Regulated parameters (pH, Moisture, Ashes, and 5-(hydroxymethyl) furfural), as well as color and aw, were measured on 25 agave syrups, including traditional samples as controls. Traditional and semi-industrial syrups were samples obtained by thermal hydrolysis. Additionally, the semi-industrial process included control of process variables such as pH, °Bx, and temperature. The industrial process is technified. The agave syrups ranged from 70-76 °Bx, pH ranged from 3.2-6.7, and moisture from 20.2-28.6%. The aw values shown a wide variation as well as L* a* and b* color parameters. Some of those parameters shown significant differences in ANOVA analysis; however, most of the samples complied with the norm. General Discriminant Analysis (GDA) made it possible to discriminate between production process by using pH, % Ash, b*, 5-(hydroxymethyl)furfural and a* parameters. Further analysis of a wide range of syrups and the inclusion of non-regulated compounds such as volatile compounds and carbohydrates are needed to get more information for a deeper characterization of agave syrups. 


2021 ◽  
Vol 9 ◽  
Author(s):  
Rebeca González-Cabaleiro ◽  
Jake A. Thompson ◽  
Laia Vilà-Nadal

Fast and reliable industrial production of ammonia (NH3) is fundamentally sustaining modern society. Since the early 20th Century, NH3 has been synthesized via the Haber–Bosch process, running at conditions of around 350–500°C and 100–200 times atmospheric pressure (15–20 MPa). Industrial ammonia production is currently the most energy-demanding chemical process worldwide and contributes up to 3% to the global carbon dioxide emissions. Therefore, the development of more energy-efficient pathways for ammonia production is an attractive proposition. Over the past 20 years, scientists have imagined the possibility of developing a milder synthesis of ammonia by mimicking the nitrogenase enzyme, which fixes nitrogen from the air at ambient temperatures and pressures to feed leguminous plants. To do this, we propose the use of highly reconfigurable molecular metal oxides or polyoxometalates (POMs). Our proposal is an informed design of the polyoxometalate after exploring the catabolic pathways that cyanobacteria use to fix N2 in nature, which are a different route than the one followed by the Haber–Bosch process. Meanwhile, the industrial process is a “brute force” system towards breaking the triple bond N-N, needing high pressure and high temperature to increase the rate of reaction, nature first links the protons to the N2 to later easier breaking of the triple bond at environmental temperature and pressure. Computational chemistry data on the stability of different polyoxometalates will guide us to decide the best design for a catalyst. Testing different functionalized molecular metal oxides as ammonia catalysts laboratory conditions will allow for a sustainable reactor design of small-scale production.


2019 ◽  
Vol 16 (3) ◽  
pp. 117-123
Author(s):  
Tsung-Ching Huang ◽  
Ting Lei ◽  
Leilai Shao ◽  
Sridhar Sivapurapu ◽  
Madhavan Swaminathan ◽  
...  

Abstract High-performance low-cost flexible hybrid electronics (FHE) are desirable for applications such as internet of things and wearable electronics. Carbon nanotube (CNT) thin-film transistor (TFT) is a promising candidate for high-performance FHE because of its high carrier mobility, superior mechanical flexibility, and material compatibility with low-cost printing and solution processes. Flexible sensors and peripheral CNT-TFT circuits, such as decoders, drivers, and sense amplifiers, can be printed and hybrid-integrated with thinned (<50 μm) silicon chips on soft, thin, and flexible substrates for a wide range of applications, from flexible displays to wearable medical devices. Here, we report (1) a process design kit (PDK) to enable FHE design automation for large-scale FHE circuits and (2) solution process-proven intellectual property blocks for TFT circuits design, including Pseudo-Complementary Metal-Oxide-Semiconductor (Pseudo-CMOS) flexible digital logic and analog amplifiers. The FHE-PDK is fully compatible with popular silicon design tools for design and simulation of hybrid-integrated flexible circuits.


1959 ◽  
Vol 81 (3) ◽  
pp. 207-214 ◽  
Author(s):  
J. Frisch ◽  
E. G. Thomsen

Billets of commercially pure lead, 2 in. diam × 3 in. long were extruded at room temperature through five different die contours at ram speeds up to 50 ipm. It was found that, for the direct and indirect extrusions, with good lubrication (white lead in oil) and with good cylinder-wall finish, the extrusion pressure-displacement diagrams were essentially the same. The concentric and eccentric single-bar and multibar extrusions at constant extrusion ratio required approximately the same pressures when extruded at identical speeds. The extrusion pressures over the wide range of speeds investigated showed approximate linearity when plotted on log-log co-ordinates.


2020 ◽  
Vol 985 ◽  
pp. 91-96
Author(s):  
Krzysztof Zaba ◽  
Sandra Puchlerska ◽  
Tomasz Pieja ◽  
Jaroslaw Pyzik

Inconel 625 is a nickel superalloy, characterized by high fatigue strength. The alloy is resistant to a wide range of corrosive environments, including high-temperature oxidation. For this reason, it is an attractive material for the chemical, shipbuilding and aviation industries. Inconel 625 alloy is designed for plastic working. However, the significant difficulty is the appropriate process design, due to the high deformation resistance. In order to improve the plastic properties of the alloy, processing at elevated temperatures is practiced. In this work, attempts were made to implement rotary forming process of Inconel 625 superalloy. For this purpose, an experiment was designed, investigating the impact of three variables on the process – feed rate, spinning rate and heating. For the tests were used Inconel 625 metal plates in the shape of discs. Axial-symmetrical products were formed, using a spinning machine. The geometry of the products according to selected quality factors was investigated. Optimal process parameters were chosen using multivariate statistical optimization. These parameters will be used to set up processes to obtain product that meets quality requirements.


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