scholarly journals The Correlation Analysis of TOC and CODCr in Urban Sewage Treatment

2019 ◽  
Vol 136 ◽  
pp. 06010 ◽  
Author(s):  
Xi Tian ◽  
Chunling Zhao ◽  
Xiaona Ji ◽  
Tiezhu Feng ◽  
Ying Liu ◽  
...  

Total organic carbon (TOC) and chemical oxygen demand (CODCr) are indicators of the degree of organic pollution in water. At present, CODCr is mainly used as an evaluation index in China, and the detection method of CODCr is more complicated and time-consuming than TOC. In this paper, it uses the Micro-Pressure Inner-Loop Bioreactor (MPR) to treat urban sewage, studies the treatment effect of MPR on organic pollutants, and further analyzes the correlation between TOC and CODCr. TOC and CODCr of municipal wastewater and MPR treated effluent were measured by total organic carbon analyzer and dichromate method respectively, and the degree of organic pollution of water samples was analyzed. The results showed that the average removal rates of TOC and CODCr in municipal wastewater were 83.54% and 90.81%, respectively. The theoretical correlation coefficient between TOC and CODCr in experimental raw water was only 0.7322. After MPR treatment, the correlation coefficient increased to 0.9534. For water samples with fixed contaminants and stable contents, TOC can be used to calculate water CODCr by linear fitting relationship.

2021 ◽  
Author(s):  
Min Wang ◽  
Yujue Zhou ◽  
Lin Xiang ◽  
Xiaoyang Ke ◽  
Hui Zhang ◽  
...  

Abstract Previous studies have shown that wetland plants can treat wastewater in a cost-effective and sustainable way, however, the studies on the performance of ornamental wetland plant diversity in treating urban sewage were scarce. Therefore, this study was conducted to assess and select wetland polyculture combination that was effective in urban sewage treatment in subtropical areas. We formed five combinations out of six ornamental wetland plant species including Thalia dealbata, Cyperus alternifolius, Iris pseudacorus, Lythrum sastlicaria, Nymphaea tetragona, and Zantedeschia aethiopica. The growth state and removal effects of each plant combination were systematically measured and assessed. The results indicated all the combinations exhibited remarkable total nitrogen (TN), total phosphorus (TP), ammonium nitrogen (NH­4+-N), and chemical oxygen demand chromium (CODcr) removal rate of 70.75%-77.67%, 63.86%-73.71%, 69.73%-76.85%, and 57.28%-75.69%, respectively. Additionally, pH was reduced to 7.54-8.00 in the sewage. The purification effect reached the best during 30-36th day. The comprehensive assessment showed the mixture of Thalia dealbata + Cyperus alternifolius, closely followed by Thalia dealbata + Cyperus alternifolius+ Lythrum sastlicaria, was highly effective at extracting various pollutants, and both of them could be used as favorable combinations to convert eutrophication and purify municipal wastewater. Linear regression showed that TP, TP, NH­4+-N, and CODcr. were significantly related to plant biomass, indicating that plant biomass essential indicator for screening purification plants. Our study highlighted the importance of plant diversity in biological wastewater treatment, however the competition between plants was suggested to take into consideration in future studies.


2017 ◽  
Vol 10 (2) ◽  
pp. 61-68 ◽  
Author(s):  
Céline Assmann ◽  
Amanda Scott ◽  
Dondra Biller

Abstract. Organic measurements, such as biological oxygen demand (BOD) and chemical oxygen demand (COD) were developed decades ago in order to measure organics in water. Today, these time-consuming measurements are still used as parameters to check the water treatment quality; however, the time required to generate a result, ranging from hours to days, does not allow COD or BOD to be useful process control parameters – see (1) Standard Method 5210 B; 5-day BOD Test, 1997, and (2) ASTM D1252; COD Test, 2012. Online organic carbon monitoring allows for effective process control because results are generated every few minutes. Though it does not replace BOD or COD measurements still required for compliance reporting, it allows for smart, data-driven and rapid decision-making to improve process control and optimization or meet compliances. Thanks to the smart interpretation of generated data and the capability to now take real-time actions, municipal drinking water and wastewater treatment facility operators can positively impact their OPEX (operational expenditure) efficiencies and their capabilities to meet regulatory requirements. This paper describes how three municipal wastewater and drinking water plants gained process insights, and determined optimization opportunities thanks to the implementation of online total organic carbon (TOC) monitoring.


1996 ◽  
Vol 34 (11) ◽  
pp. 25-32 ◽  
Author(s):  
P. Chudoba ◽  
R. Pujol

Most of municipal activated sludge plants located in wine production regions receive winery wastewaters during the grape harvest period which lasts usually only a few weeks. A drastic increase in organic pollution (COD, BOD) during this period generates a temporary overloading, resulting very often in biological problems such as decreased sludge settleability, sludge floc disintegration, increased SS concentration in treated effluent and in the worst case a complete plant failure. In order to work satisfactorily even during those temporary overloading periods, the plant has to be oversized. This strategy is rather costly, because such a plant has to run below its nominal capacity during a major part of the year. An original solution has been proposed and successfully tested at a municipal wastewater treatment plant in Eguisheim, France. The proposed technique is based on the addition of a mineral material with a low particle size, whose presence positively influences the physical behaviour of the sludge and will allow the nominal capacity of the plant to be surpassed without any important modification. The modification of the sludge structure around the added powdered material improved significantly the sludge settleability (DSVI< 160 ml/g) and enabled the plant to treat organic pollution several times higher than the nominal level.


2019 ◽  
Vol 32 ◽  
pp. 153-162
Author(s):  
Nada M. Al-Baghdadi ◽  
Abdulaziz M. Abdullah ◽  
Entisar N. Sultan

The current study has evaluated Shatt Al-Arab water using organic pollution index. The study included three stations, the first Al-Sharash, the second Al-Salhiya and the third area Al-Dweab. Water samples were monthly collected from December 2017 to November 2018. Five environmental parameters were used to calculate the organic pollution index (OPI) including Biological Oxygen Demand (BOD), Chemical Oxygen Demand (COD), Active nitrate (NO3), Ammonium ion (NH4) and Total Phosphate (TP). The highest biological oxygen demand was 9 mg.l-1 at Al-Sharash station in July and the lowest values 1mg.l-1 in the Al- Dweab station during December, January, February and April. The highest chemical oxygen demand (250 mg.l-1 was recorded at Al-Sharash station in September and the lowest value was 6.2 mg.l-1 in Al-Dweab station during December. Nitrates was recorded the highest value 41.51 mg nitrogen-nitrate.l-1 at Al-Salhiya station in May and lowest value 1.49 mg nitrogen- nitrate.l-1 at Al-Sharash station during December. The ammonium ion was recorded in highest value 7.7 mg.l-1 at Al- Salhiya station in December and the lowest value 0.5 mg. l-1 at Al-Sharash station during June, while phosphate value was 0.23 and 1.99 mg.l-1 were recorded at Al-Sharash station in August and July respectively. The highest value of organic pollution index was 2.56 at Al-Salihiya station in August and lowest value 0.69 in the Al-Dweab station in April, while the annual rate of organic pollution index for the first, second and third stations were 1.55, 1.81 and 1.47 respectively, and 1.61 for Shatt Al-Arab water.


2020 ◽  
Vol 997 ◽  
pp. 127-138
Author(s):  
Nazzeri Abdul Rahman ◽  
Nur Afifah Tomiran ◽  
Aiman Hakim Hashim

Peat water is an abundant water resource in Sarawak where some of the coastal areas in Sarawak still utilize peat water for domestic usage. Peat water contains natural organic matters especially humic substances which include humic acids. Humic acids contribute to the brown color of peat water and can cause diseases such as stomach cancer, blackfoot disease and etc. if consumed by human. Electrocoagulation is an alternative to conventional water treatment methods which have the advantages of being environmental friendly, minimal sludge production and no addition of chemical substances. The aims of this study are to fabricate a desktop scale electrocoagulation system with galvanised iron electrodes and to investigate the effects of the operating parameters such as inter-electrode distance, applied current density, number of electrodes, and treatment time on peat water in the system. The performance of batch electrocoagulation system in term of their removal efficiency of several parameters such as total organic carbon (TOC), chemical oxygen demand (COD), color and turbidity are evaluated. Through experimental tests conducted, this system successfully removes 98.44% of COD, 92.02% of TOC, 97.92% of turbidity and 99.91% of color by using galvanized iron as an electrode at current density of 25 A/m2in 30 minutes with 10 galvanized iron electrodes. Despite the fact that there is a small amount of iron ions and zinc ions remained in the treated peat water which are 0.001mg/l and 0.0442mg/l respectively, these concentrations are far below the standard limits imposed by Malaysia Ministry of Health (MOH). Generally, all the parameters studied meet the standard limit imposed by MOH except for total organic carbon. This is particularly due to the improper filtration system adopted in this study. The total operating costs for 252 in 30 minutes treatment time of 10 electrode plates is RM 8.75 per . Overall, the study have successfully designed a batch electrocoagulation system to treat peat water by using galvanized iron for domestic usage.


Materials ◽  
2019 ◽  
Vol 12 (22) ◽  
pp. 3784 ◽  
Author(s):  
Violetta Kozik ◽  
Krzysztof Barbusinski ◽  
Maciej Thomas ◽  
Agnieszka Sroda ◽  
Josef Jampilek ◽  
...  

The potential implementation of Envifer®, a commercial product containing potassium ferrate (40.1% K2FeO4), for the purification of highly contaminated tannery wastewater from leather dyeing processes was proposed. The employment of the Taguchi method for optimization of experiments allowed the discoloration (98.4%), chemical oxygen demand (77.2%), total organic carbon (75.7%), and suspended solids (96.9%) values to be lowered using 1.200 g/L K2FeO4 at pH 3 within 9 min. The application of the central composite design (CCD) and the response surface methodology (RSM) with the use of 1.400 g/L K2FeO4 at pH 4.5 diminished the discoloration, the chemical oxygen demand, the total organic carbon, and suspended solids within 9 min. The Taguchi method is suitable for the initial implementation, while the RSM is superior for the extended optimization of wastewater treatment processes.


2019 ◽  
Vol 11 (8) ◽  
pp. 2284 ◽  
Author(s):  
Jin Xu ◽  
Peifang Wang ◽  
Yi Li ◽  
Lihua Niu ◽  
Zhen Xing

In this study, we examined the influence of the organic carbon-to-nitrogen ratio (chemical oxygen demand (COD/N)) and dissolved oxygen (DO) levels on the removal efficiency of pollutants and on the change in total microflora in the cyclic activated sludge system (CASS) in the Nyingchi prefecture in Tibet. The results demonstrated that the treatment performance was the best when the COD/N ratio was 7:1 or the DO levels were 2–2.5 mg/L in comparison with four different tested COD/N ratios (4:1, 5:1, 7:1, and 10:1) and DO concentrations (0.5–1, 1–2, 2–2.5, and 2.5–3.5 mg/L). The treatment performance can be explained by the relative operational taxonomic unit richness and evenness of the microbial communities in activated sludge. Evident microbial variance was observed, especially different COD/N ratios and DO concentrations, which were conducive to the disposal of urban sewage in plateaus. The results help to understand sewage treatment under different COD/N ratios or DO concentrations on plateaus. This work provides practical guidance for the operation of any wastewater treatment plant on a plateau.


2011 ◽  
Vol 64 (1) ◽  
pp. 214-219 ◽  
Author(s):  
Levent Gürel ◽  
Hanife Büyükgüngör

The use of a membrane bioreactor (MBR) for removal of organic substances and nutrients from slaughterhouse plant wastewater was investigated. The chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) concentrations of slaughterhouse wastewater were found to be approximately 571 mg O2/L, 102.5 mg/L, and 16.25 mg PO4-P/L, respectively. A submerged type membrane was used in the bioreactor. The removal efficiencies for COD, total organic carbon (TOC), TP and TN were found to be 97, 96, 65, 44% respectively. The COD value of wastewater was decreased to 16 mg/L (COD discharge standard for slaughterhouse plant wastewaters is 160 mg/L). TOC was decreased to 9 mg/L (TOC discharge standard for slaughterhouse plant wastewaters is 20 mg/L). Ammonium, and nitrate nitrogen concentrations of treated effluent were 0.100 mg NH4-N/L, and 80.521 mg NO3-N/L, respectively. Slaughterhouse wastewater was successfully treated with the MBR process.


2013 ◽  
Vol 821-822 ◽  
pp. 480-483
Author(s):  
Wei Li Zhou ◽  
Wei Ding ◽  
Jie Kuang ◽  
Long Chen ◽  
Jin Jun Li

The decolorization of Orange II in goethite/UV system was investigated. It was discovered that the optimum condition is: pH=3, [α-FeOOH]=0.5 g/L, [Orange II]=10 mg/L. Furthermore, the absorption of Orange II on goethite, and the effect of pH values, goethite dosage and carboxylate on the decolorization were investigated. The decolorization efficiency was 90% after 6h irradiation when the concentration of pyruvic acid was 1.0mmol/L, α-FeOOH concentration was 0.3 g/L, and Orange II concentration was 10 mg/L at pH 3.0. Besides, total organic carbon (TOC) and chemical oxygen demand (COD) were determined, and a possible reaction mechanism was prompted as well.


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