scholarly journals Reuse of Newspaper As An Adsorbent For Cu (II) Removal By Citric Acid Modification

2018 ◽  
Vol 156 ◽  
pp. 02012 ◽  
Author(s):  
Mardiah ◽  
Rif’an Fathoni ◽  
Pratiwi Pudyaningtyas ◽  
Hamdania Gamu ◽  
Rinaldy
Keyword(s):  
Citric Acid ◽  
Adsorption Process ◽  
Kinetic Studies ◽  
Order Reaction ◽  
Acid Modification ◽  
Pseudo First Order Reaction ◽  
First Order ◽  
Pseudo Second Order ◽  
Heavy Metal Adsorbent ◽  
The Impact

High Consumption of paper, bring the impact of the waste paper itself. And the utilization of the paper is limited to recycled products and crafts, whereas paper such as newspaper still contains cellulose that can be potential to be used as a heavy metal adsorbent. In this study, newspaper was dissolved in sodium bicarbonate to reduce various impurities and then was reacted with citric acid (CA). The modified adsorbent was characterized by FTIR and was tested for adsorb Cu(II) in artificial solution. After adsorption process, the solution was filtered and analysed using Atomic Absorption Spectrophotometer (AAS). The adsorption experimental data was fitted to Langmuir, Freundlich, Tempkin, and Dubinin-Radushkevich for equilibrium model and was fitted to pseudo first order reaction and pseudo second order reaction for kinetic studies. The result showed that CA-modification newspaper able to remove heavy metals Cu(II) in solution.

scholarly journals Solar Active Reusable Photocatalyst Magnetite Doped Calcium Aluminate for Acid Yellow 23 Photodegradation

2020 ◽  
Vol 32 (6) ◽  
pp. 1329-1334
Author(s):  
R. Padmavathi ◽  
V. Natchimuthu ◽  
I. Sharmila Lydia
Keyword(s):  
Calcium Aluminate ◽  
Kinetic Studies ◽  
Order Reaction ◽  
Precipitation Method ◽  
Pseudo First Order Reaction ◽  
Photo Catalyst ◽  
First Order ◽  
Co Precipitation ◽  
Surface Morphologies ◽  
The Impact

Fe3O4 doped calcium aluminate nanoparticles were synthesized by co-precipitation method, an effective route to synthesize novel photocatalyst to enhance the photocatalytic decolourization of acid yellow 23 dye. The structural and surface morphologies were investigated using techniques such as SEM and EDAX. In this study, a degradation of acid yellow 23 dye have been carried out in the presence of sunlight. It was observed that the synthesized Fe3O4 doped calcium aluminate photo catalyst was very useful in degrading the dye entirely within a short span of time (90 min). The impact of various operating parameters on acid yellow 23 including the amount of photocatalyst, dye concentration, H2O2 concentration and temperature was thoroughly examined. The kinetic studies explained that the degradation of photocatalytic reaction showed pseudo first-order reaction.

TiO2 Supported Clinoptilotile: Characterization and Optimization of Operational Parameters for Methyl Orange Removal

2013 ◽  
Vol 781-784 ◽  
pp. 2249-2252 ◽  
Author(s):  
Sanni O. Saheed ◽  
Sekomeng J. Modise ◽  
Allworth M. Sipamla
Keyword(s):  
Methyl Orange ◽  
Photocatalytic Degradation ◽  
Kinetic Studies ◽  
Methyl Orange Solution ◽  
Order Reaction ◽  
Operational Parameters ◽  
Pseudo First Order Reaction ◽  
First Order ◽  
Orange Solution ◽  
Degradation Of Methyl Orange

Titania dispersed on dealuminated Clinoptilotile (TiO2/HCP) was synthesized and characterized by Scanning Electron Microscope (SEM). Supporting characterization techniques reveals partly dispersion of TiO2 within the cavities of dealuminated Clinoptilotile (HCP) and TiO2 exist as nanoparticles or clusters on the HCP surface ascribed to lower loading of TiO2. The photocatalytic degradation of methyl orange solution was conducted under UV-irradiation in the presence of TiO2/HCP. The photocatalytic degradation of methyl orange in the presence of the photocatalyst was optimized at lower loading of TiO2, at a lower initial dye concentration (30 ppm), calcination temperature of 873K and nitrate ion accelerates degradation activities of methyl orange. Kinetic studies depict the photocatalytic degradation of methyl orange follows the pseudo-first order reaction.

scholarly journals Kinetic Studies for the Biosorption of Chromium Using Cherry Leaves (Muntingia calabura L.)

2014 ◽  
Vol 25 ◽  
pp. 6-11 ◽  
Author(s):  
R. Aathithya ◽  
J. Rajani Sowparnika ◽  
V. Balakrishnan
Keyword(s):  
Regression Coefficient ◽  
Kinetic Studies ◽  
Order Reaction ◽  
First Order Reaction ◽  
Standard Errors ◽  
Second Order Reaction ◽  
Pseudo First Order Reaction ◽  
First Order ◽  
Pseudo First Order ◽  
Muntingia Calabura

Biosorption is an attractive technology which is used for the sorption of substances by a biomaterial. In this present work the heavy metal chromium was subjected to biosorption because of their non-degradability nature and causes water and land pollution. Cherry leaves were used as a biomaterial for the biosorption. Kinetic studies were performed for the biosorption experiment. From the experiment it was found that the reaction follows pseudo first order reaction because of the larger value of regression coefficient R2 and lower value of standard errors (χ2) for pseudo first order reaction than second order reaction.

scholarly journals Behaviour of Silica and Florisil as Solid Supports in the Removal Process of As(V) from Aqueous Solutions

2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
Andreea Gabor ◽  
Corneliu Mircea Davidescu ◽  
Adina Negrea ◽  
Mihaela Ciopec ◽  
Lavinia Lupa
Keyword(s):  
Crown Ether ◽  
Aqueous Solutions ◽  
Adsorption Process ◽  
Kinetic Studies ◽  
Solid Supports ◽  
Equilibrium Studies ◽  
First Order ◽  
Pseudo Second Order ◽  
Trace Concentrations ◽  
Solid Liquid

In this study two solid supports, silica and florisil, were impregnated with crown ether (dibenzo-18-crown-6) and Fe(III) ions and their efficiency was compared in the adsorption process of As(V) from aqueous solutions. The solid supports were impregnated with crown ether due to their ability to build complexes with positives ions. Fe(III) was used because of As(V) affinity for it. The impregnated solid supports were characterized by energy dispersive X-ray analysis, scanning electron microscopy, Fourier transform infrared spectroscopy, and the specific surface area. The influence of the solid : liquid ratio on the adsorption process, kinetic studies for the pseudo-first-order and pseudo-second-order, and activation energy were studied. Thermodynamic studies as well as equilibrium studies were carried out. The obtained results showed that, from the two considered materials, impregnated silica presents a higher efficiency with a good selectivity, able to remove As(V) from aqueous solutions containing trace concentrations.

scholarly journals Direct red 83 textile dye degradation using photoperoxidation and photo-fenton: kinetic studies, toxicity and neural networks modeling

2020 ◽  
Vol 42 ◽  
pp. e41
Author(s):  
Nataly Daiany de Oliveira Amorim ◽  
Graziele Elisandra do Nascimento ◽  
Lívia Vieira Carlini Charamba ◽  
Rayany Magali da Rocha Santana ◽  
Pollyanna Michelle da Silva ◽  
...  
Keyword(s):  
Wastewater Treatment Plants ◽  
Dye Degradation ◽  
Kinetic Studies ◽  
Order Reaction ◽  
Textile Dye ◽  
Pseudo First Order Reaction ◽  
Rapid Decay ◽  
First Order ◽  
Physical Chemical ◽  
Oxidative Processes

Textile dyes have been observed in aquatic matrices that receive effluents from different textile industries. These compounds have the peculiarity of being resistant to the physical, chemical and biological treatments commonly used in wastewater treatment plants. Thus, alternative treatments such as advanced oxidative processes (AOP) have been considered in order to promote the degradation of this type of pollutant, being the photoperoxidation and photo-Fenton processes the most used. Therefore, the present work evaluated the efficiency of these AOP in the degradation of direct red 83 dye. It was found a greater efficiency of the photoperoxidation process, especially in the degradation of functional groups observed at 289 nm. This AOP presented a pseudo first order reaction kinetics, with rapid decay in the first minutes. The MLP (5-21-2) neural network model was able to satisfactorily predict the degradation of the dye under study. Finally, it was found that the proposed process showed no adverse effects when studying the toxicity in bacteria.

Multifactorial optimization of the decolorisation parameters of wastewaters resulting from dyeing flowers

2009 ◽  
Vol 59 (7) ◽  
pp. 1361-1369 ◽  
Author(s):  
Edison Gil Pavas ◽  
Miguel Ángel Gómez-García
Keyword(s):  
Hydrogen Peroxide ◽  
Organic Matter ◽  
Experimental Design ◽  
Order Reaction ◽  
Pseudo First Order Reaction ◽  
First Order ◽  
Effluent Standards ◽  
Degradation Of Dyes ◽  
Pseudo First Order ◽  
Dyes Mixture

This work deals with the treatment of the wastewaters resulting from the process of dyeing flowers. In some local cases for growing flowers near to Medellín (Colombia), wastewater color was found to be one of the main problems in meeting local effluent standards. Wastewaters were treated by photodegradation process (which includes photocatalysis) to achieve the degradation of dyes mixture and organic matter in the wastewater. A multifactorial experimental design was proposed, including as experimental factors the following variables: pH, and the concentration of both catalyst (TiO2) and hydrogen peroxide (H2O2). According to the obtained results, at the optimized variables values, it is possible to reach a 99% reduction of dyes, a 76.9% of mineralization (TOC) and a final biodegradability of 0.834. Kinetic analysis allows proposing a pseudo first order reaction for the reduction, the mineralization, and the biodegradation processes.

scholarly journals Spent mushroom substrate: a crucial biosorbent for the removal of ferrous iron from groundwater

2021 ◽  
Vol 3 (1) ◽  
Author(s):  
D. Menaga ◽  
S. Rajakumar ◽  
P. M. Ayyasamy
Keyword(s):  
Ferrous Iron ◽  
Tamil Nadu ◽  
Contaminated Water ◽  
Spent Mushroom Substrate ◽  
Pseudo First Order Reaction ◽  
Time Intervals ◽  
New Approach ◽  
First Order ◽  
Sorption Ability ◽  
Pseudo Second Order

Abstract A new approach was carried out with the spent mushroom substrate (SMS) of Pleurotus florida on ferrous iron (Fe2+) removal using live, dead and pretreated substrate. In this study, the various dosage levels of SMS namely, 0.25, 0.50, 1.0 and 1.50 g/50 mL were used for the removal of Fe2+ at different time intervals for 90 min. The effect of various temperatures and pH on Fe2+ removal was studied with optimized dosages and time intervals. The biosorption potential of P. florida SMS was checked against the iron-contaminated groundwater collected from in and around Salem, Namakkal and Dharmapuri districts of Tamil Nadu. The biosorption data were obtained and analyzed in terms of their kinetic behavior. Among the SMS of P. florida, the live SMS showed potential Fe2+ removal (100%) from aqueous metal solution in all the tested concentrations. SMS of P. florida showed high potential removal of Fe2+ in neutral pH, at room temperature and explored an efficient sorption ability (100%) in the tested water sample (SW10). The adsorption kinetic values fitted very well with pseudo-second-order when comparing with pseudo-first-order reaction. FTIR, SEM and EDX analysis proved the accumulation of Fe2+ by the SMS. The present study confirmed that the live SMS of P. florida may serve as a potential and eco-friendly biosorbent for removal of Fe2+ from the iron-contaminated water. Graphic abstract

scholarly journals Water defluoridation by alumina modified Turkey clinoptilolite: equilibrium, kinetic models and experimental design approaches

2017 ◽  
Vol 18 (1) ◽  
pp. 14-22 ◽  
Author(s):  
Selim Selimoglu ◽  
Esra Bilgin Simsek ◽  
Ulker Beker
Keyword(s):  
Natural Zeolite ◽  
Kinetic Studies ◽  
Order Reaction ◽  
Operating Conditions ◽  
Second Order Reaction ◽  
Freundlich Model ◽  
Box Behnken Design ◽  
Fluoride Adsorption ◽  
Exothermic Process ◽  
Pseudo Second Order

Abstract In the current work, alumina modified natural zeolite (Z-Al) was used for fluoride adsorption in aqueous solution. Effects of process parameters such as pH, temperature, initial concentration and contact time were investigated. Box–Behnken design was found effective in defining the operating conditions for fluoride sorption onto Z-Al. Confirmatory experiments were conducted to examine the reliability of the regression equation. The predicted (2.261 mg g−1) and experimental (2.289 mg g−1) capacities were found to be similar, demonstrating the accuracy of the model. The fluoride adsorption onto Z-Al was well described by the Freundlich model. Kinetic studies revealed that the adsorption followed a pseudo-second-order reaction. Thermodynamic parameters depicted that the fluoride adsorption on the alumina modified zeolite was a spontaneous and exothermic process. The co-existing ions affected the defluoridation performance significantly. Regeneration of exhausted Z-Al was achieved with H2SO4.

scholarly journals ADSORPTION AND KINETIC STUDIES OF A NATURAL DYE FROM CURCUMA LONGA L., ONTO BAMBOO YARN

2017 ◽  
Vol 2 (1) ◽  
pp. 13-26
Author(s):  
Tengku Khamanur Azma Tg. Mohd Zamri ◽  
Mimi Sakinah Abd Munaim ◽  
Zularisam Ab Wahid
Keyword(s):  
Adsorption Process ◽  
Regression Coefficient ◽  
Curcuma Longa ◽  
Freundlich Isotherm ◽  
Kinetic Studies ◽  
Natural Dye ◽  
Isotherm Models ◽  
Order Model ◽  
Dyeing Process ◽  
Pseudo Second Order

Natural dye extracted from the rhizome of Curcuma longa L. were applied to bamboo yarns using exhaustion dyeing process. This study investigates the dyeing behaviour of Curcumin; the major color component isolated from rhizomes of Curcuma longa L.on bamboo yarn. Langmuir, Freundlich, Tempkin and Dubinin-Radushkevich isotherm models were used to test the adsorption process of curcumin on bamboo yarn. Comparison of regression coefficient value indicated that the Freundlich isotherm most fitted to the adsorption of curcumin onto bamboo yarn. Furthermore, the kinetics study on this research fitted the pseudo-second order model which indicates that the basis of interaction was chemical adsorption.

scholarly journals Enhancing acidic dye adsorption by modified UiO-66

2020 ◽  
Vol 1 (2) ◽  
pp. 54-62
Author(s):  
Naser Al Amery ◽  
Hussein Rasool Abid ◽  
Shaobin Wang ◽  
Shaomin Liu
Keyword(s):  
Adsorption Process ◽  
Dye Adsorption ◽  
Batch Adsorption ◽  
First Order ◽  
Freundlich Isotherms ◽  
Adsorption Capacities ◽  
Pseudo Second Order ◽  
The Stability ◽  
Second Order Equations ◽  
Better Than

In this study, two improved versions of UiO-66 were successfully synthesised. Modified UiO-66 and UiO-66-Ce were characterised to confirm the integrity of the structure, the stability of functional groups on the surface and the thermal stability. Activated samples were used for removal harmful anionic dye (methyl orange) (MO) from wastewater. Batch adsorption process was relied to investigate the competition between those MOFs for removing MO from aqueous solution. Based on the results, at a higher initial concentration, the maximum MO uptake was achieved by UiO-66-Ce which was better than modified-UiO-66. They adsorbed 71.5 and 62.5 mg g-1 respectively. Langmuir and Freundlich isotherms were employed to simulate the experimental data. In addition, Pseudo first order and Pseudo second order equations were used to describe the dynamic behaviour of MO through the adsorption process. The high adsorption capacities on these adsorbents can make them promised adsorbents in industrial areas.

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