A Highly Selective and Sensitive Chemosensor for Colorimetric and Fluorescent Detection of Al3+ and Living Cell Imaging

2015 ◽  
Vol 68 (1) ◽  
pp. 156 ◽  
Author(s):  
Xiao-Bo Li ◽  
Jia-Yi Chen ◽  
En-Ju Wang

A colorimetric and fluorescent dual chemosensor for detecting Al3+, (E)-N′-((2-hydroxynaphthalen-1-yl)methylene)nicotinohydrazide (HNN), was developed by combining 2-hydroxy-1-naphthaldehyde with nicotinohydrazide. Addition of Al3+ to EtOH–H2O solution of HNN gives rise to a visible colour change from colourless to light blue and a significantly enhanced fluorescence. Other metal ions including Na+, K+, Ca2+, Mg2+, Mn2+, Co2+, Ni2+, Cu2+, Cr3+, Ag+, Pb2+, Zn2+, Cd2+, Hg2+, Fe2+, and Fe3+ have no or little effect on the specific response of HNN to Al3+. The binding mode of HNN–Al3+ complex was further clarified by electrospray ionisation mass spectrometry and 1H NMR titration experiments.

2018 ◽  
Vol 10 (46) ◽  
pp. 5554-5558 ◽  
Author(s):  
Jing Xu ◽  
Honglin Li ◽  
Yanchi Chen ◽  
Bing Yang ◽  
Qingcai Jiao ◽  
...  

A novel fluorescent probe (XL-1) exhibited over 50-fold enhanced fluorescence in the presence of Hg2+ and no interference could be produced by other metal ions, anions and amino acids.


2018 ◽  
Vol 96 (12) ◽  
pp. 1129-1133
Author(s):  
Changping Yang ◽  
Mingliang Zuo ◽  
Xiaoli Hu ◽  
Xuelin Chen ◽  
Duoduo Zhang ◽  
...  

A novel fluorescent rhodamine-based probe L for selective responding to ClO– has been synthesized and characterized. The spectroscopy showed that probe L can detect ClO– in aqueous solution without interaction with other interfering ions, and the detection is also evident by the colour change from colourless to reddish purple under white light. The remarkable fluorescence enhancement showed the high selectivity and sensitivity of probe L for the detection of ClO–. Furthermore, probe L was applied to intracellular fluorescent imaging of HeLa cells treated with ClO– and MTT assay showed nontoxicity in living cells.


2017 ◽  
Vol 241 ◽  
pp. 868-878 ◽  
Author(s):  
Yordkhuan Tachapermpon ◽  
Sumonmarn Chaneam ◽  
Adisri Charoenpanich ◽  
Jitnapa Sirirak ◽  
Nantanit Wanichacheva

2019 ◽  
Vol 282 ◽  
pp. 347-358 ◽  
Author(s):  
Bidyut Kumar Kundu ◽  
Poulami Mandal ◽  
Bhaswati Ghosh Mukhopadhyay ◽  
Ritudhwaj Tiwari ◽  
Debasis Nayak ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (64) ◽  
pp. 40615-40620 ◽  
Author(s):  
Kui Du ◽  
Shizhen Niu ◽  
Li Qiao ◽  
Yandong Dou ◽  
Qing Zhu ◽  
...  

A simple ratiometric sensor (L1) for the cascade detection of Zn2+ and H2PO4− with high selectivity was reported based on the intermolecular charge transfer (ICT) mechanism.


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