Thermal degradation modeling of flexural strength of wood after exposure to elevated temperatures

2013 ◽  
Vol 8 (2) ◽  
pp. 111-118 ◽  
Author(s):  
Arijit Sinha
Author(s):  
P. Singh ◽  
G.T. Galyon ◽  
J. Obrzut ◽  
W.A. Alpaugh

Abstract A time delayed dielectric breakdown in printed circuit boards, operating at temperatures below the epoxy resin insulation thermo-electrical limits, is reported. The safe temperature-voltage operating regime was estimated and related to the glass-rubber transition (To) of printed circuit board dielectric. The TG was measured using DSC and compared with that determined from electrical conductivity of the laminate in the glassy and rubbery state. A failure model was developed and fitted to the experimental data matching a localized thermal degradation of the dielectric and time dependency. The model is based on localized heating of an insulation resistance defect that under certain voltage bias can exceed the TG, thus, initiating thermal degradation of the resin. The model agrees well with the experimental data and indicates that the failure rate and truncation time beyond which the probability of failure becomes insignificant, decreases with increasing glass-rubber transition temperature.


2001 ◽  
Vol 10 (2) ◽  
pp. 096369350101000 ◽  
Author(s):  
J. George ◽  
E.T.J. Klompen ◽  
T. Peijs

Over the last couple of years, an increasing amount of research has been dedicated to the use of flax fibres as an environmentally friendly alternative to glass fibres in engineering composites. Because of the relatively poor thermal stability of flax fibres compared to glass fibres, knowledge of the thermal degradation profile of these natural fibres is essential for the selection of potential matrix candidates and/or the development of feasible processing and recycling routes. Especially in combination with thermoplastic resins, composite (re)processing may have a detrimental effect on the mechanical properties of the natural fibres. This study reports on the effect of the exposure of two types of flax fibres, green flax and a new upgraded flax fibre called Duralin, to elevated temperatures using thermogravimetric analysis (TGA), residual strength measurements and environmental scanning electron microscopy (ESEM) studies.


2017 ◽  
Vol 8 (4) ◽  
pp. 392-401 ◽  
Author(s):  
Hassan A.M. Mhamoud ◽  
Jia Yanmin

Purpose This study aims to focus on the resistance to elevated temperatures of up to 700ºC of high-performance concrete (HPC) compared to ordinary Portland concrete (OPC) with regards to mass loss and residual compressive and flexural strength. Design/methodology/approach Two mixtures were developed to test. The first mixture, OPC, was used as the control, and the second mixture was HPC. After 28 days under water (per Chinese standard), the samples were tested for compressive strength and residual strength. Findings The test results showed that at elevated temperatures of up to 500ºC, each mixture experienced mass loss. Below this temperature, the strength and the mass loss did not differ greatly. Originality/value When adding a 10 per cent silica fume, 25 per cent fly, 25 per cent slag to HPC, the compressive strength increased by 17 per cent and enhanced the residual compressive strength. A sharp decrease was observed in the residual flexural strength of HPC when compared to OPC after exposure to temperatures of 700ºC.


Carbon ◽  
2020 ◽  
Vol 159 ◽  
pp. 324-332 ◽  
Author(s):  
H. Zielke ◽  
T. Wetzig ◽  
C. Himcinschi ◽  
M. Abendroth ◽  
M. Kuna ◽  
...  

1988 ◽  
Vol 15 (5) ◽  
pp. 776-783
Author(s):  
H. S. Wilson

Two similar mixes were made with cement contents of about 350 kg/m3 and a water–cement ratio of 0.50. The concrete specimens, moist cured for 7 days, were cured in air for 28 and 120 days, respectively, prior to heating. The exposure temperatures were 75, 150, 300, and 450 °C. The periods of exposure at each temperature were 2, 30, and 120 days.The compressive strengths, before heating, of the specimens cured for 35 and 120 days were 41.0 and 46.2 MPa, respectively, and the flexural strengths were 4.9 and 5.8 MPa. Compared with those strengths, the strengths of the specimens heated for 30 days or more increased at 75 °C but decreased at higher temperatures. The losses increased with increase in temperature, reaching about 30% at 450 °C.The flexural strength of the concrete cured in air for 28 days was more adversely affected than was the compressive strength. The flexural and compressive strengths of the concrete cured in air for 120 days were affected to about the same degree. The longer curing period had little effect on the relative losses in compressive strength, but the longer curing period reduced the loss in flexural strength. In most applications, the loss in strength could be compensated by proportioning the mix to overdesign for strength. Key words: high-density concrete, ilmenite, aggregates, high temperature, mechanical properties, nondestructive tests.


1982 ◽  
Vol 60 (10) ◽  
pp. 1207-1213 ◽  
Author(s):  
Ramunas J. Motekaitis ◽  
X. B. Cox III ◽  
Patrick Taylor ◽  
Arthur E. Martell ◽  
Brad Miles ◽  
...  

The thermal degradation of Ca(II), Mg(II), Zn(II), Fe(II), and Ni(II) chelates of EDTA was investigated in alkaline aqueous solution at elevated temperatures (230–310 °C). The kinetics of decomposition were followed by nmr, titrimetry, and spectrophotometry. Reaction products were identified through nmr and by gas chromatography. The relative order of degradation rates, as measured by the loss of EDTA, was found to be Mg(II) > Ca(II) > Zn(II) > Fe(II) > Ni(II). The main degradation products formed in the lower temperature range (~250 °C) are iminodiacetic acid, hydroxyethyliminodiacetic acid, and ethylene glycol. Higher temperature products are primarily dimethylamine and carbon dioxide. The rates of degradation of Ca(II), Mg(II), and Zn(II) EDTA chelates are considerably enhanced when either phosphate is present or a glass-lined autoclave is employed.


2013 ◽  
Vol 690-693 ◽  
pp. 323-328
Author(s):  
J. J. Sha ◽  
Y.X. Zhang ◽  
J. Li ◽  
J. X. Dai ◽  
Z. Q. Wei ◽  
...  

In order to investigate the influence of carbon fiber’s surface state on the mechanical properties and the fiber-matrix interaction of CFRP, the change of surface state was achieved by thermal treatment of carbon fibers at elevated temperatures, and the surface state was characterized by XPS. The mechanical properties were measured from the flexural test. The CFRP reinforced with 600 °C treated fabrics containing the highest reactive functional groups, showed the highest flexural strength and modulus. But in the case of CFRP reinforced with 1500 °C treated fabrics containing the lowest reactive functional groups, exhibited the lowest flexural strength and modulus. Combining the mechanical properties with the microstructure analysis, the results indicated that the fiber-matrix interaction (strong or weak) depends on the relative percentage of reactive functional groups present on the carbon fiber surface.


2020 ◽  
Vol 3 (3) ◽  
pp. 111
Author(s):  
Alauddin . ◽  
Azhar Khan ◽  
Imran Ahmad

The degradation of polymer is known, but the effect of CNT composite is the less studied concept. In this article, the effect of CNT on degradation is presented. The first stage involved a literature study for reaction mechanisms in oxidative thermal degradation of Polypropylene (PP). A reaction model is then developed by considering mass balance on various reactive species. Literature is reviewed to find or estimate the model parameters. The parameters not found in the literature are fitted. The model equations are solved after assuming initial conditions and values of various parameters. After the PP polymer degradation modeling comparison drown between PP and PP/MWCNT composite by making a hypothesis based on Arrhenius equations (activation energy increases, the rate constant decreases, and therefore the rate of reaction decreases). The result shows that the CNT composite takes much time to degrade as compared to the polymer.


2022 ◽  
Vol 961 (1) ◽  
pp. 012085
Author(s):  
Aseel Mansi ◽  
Nadhim Hamah Sor ◽  
Nahla Hilal ◽  
Shaker M A Qaidi

Abstract The use of nano clay to improve the qualities of construction materials and engineering applications has attracted a lot of discussion in recent years. This review article summarizes the influence of nano clay as a cement substitute and supplement on the performance of conventional and high-performance concrete. The addition of nano clay to high performance concrete revealed an increase in compressive and flexural strength, as well as durability attributes such as resistance to elevated temperatures and sulfate attack, while simultaneously decreasing porosity, permeability, and water absorption. This enhancement is a result of nano clay’s roles as nano reinforcements, nanofillers, nucleation sites, and reactive pozzolans, which promote hydration and increase material characteristics.


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