The study looks into the effect of a silicic acid filler's (SAF) surface chemistry and thermal modification of BNKS-40/PVC-based (80:20) compounds upon material's vibration-absorbing properties. The thermal analysis (TGA and DTA, Shimadzu analyzer, the temperature rise rate - 10 ° С/min), IR spectroscopy (Infralume FT-08, MFTIR) demonstrated, that adsorption of organosilane bis(3triethoxysilylpropyl)disulfide (TESPD) and the following silanization of Newsil 1165МР (145 ° С, 5 min) occur more readily on the surface of the SAF, dried in mild conditions (70 ° С) in advance. Dehydration of the SAF surface contributes to an increase in the proportion of organosilane physically associated with its surface (2.4 times), rather than chemically (1.1 times). SAF silanization results in the decrease in the compounds' Mooney viscosity (MB 1+4, 100 ° С, CU) and the higher content of free TESPD, the more pronounced the decrease is. The dynamic mechanical analysis (Netzsch DMA 242, in the temperature range from -60 to +60 °С and the frequency range from 0.1 to 10 Hz) demonstrated that, free TESPD plasticized the polymer matrix, increasing TanD as well as shifting the peak of mechanical losses into the lower temperature range. In this case, the effective temperature range of vibration absorption (ETRVA, where TanD ≥ 0.3) is somewhat narrowed in comparison with the compound containing the initial SAF. Thermal modification of BNKS-40/PVC compounds (120 ° С, 4 h) is accompanied by ETRVA expansion in the elastomer glass transition range, as well as in the glass transition temperature of the elastomer-thermoplast transition range. This fact is due to the diffusion of polymers in the filler-elastomer/thermoplast- and the elastomer-thermoplast inter-phase zones. Thermal modification is effective with compounds containing silanized filler with the least amount of free TESPD.