scholarly journals Enhancing removal efficiency of heavy metals and ammonia in bioretention system using quartz sand and zeolite as filter media

2019 ◽  
Vol 536 ◽  
pp. 012071
Author(s):  
A Y Sari ◽  
N Suwartha ◽  
D M Hartono ◽  
I Gusniani
Keyword(s):  
Heavy Metals ◽  
Removal Efficiency ◽  
Quartz Sand ◽  
Filter Media ◽  
Bioretention System

scholarly journals Simultaneous Adsorption of Heavy Metals from Roadway Stormwater Runoff Using Different Filter Media in Column Studies

Water ◽  
2018 ◽  
Vol 10 (9) ◽  
pp. 1160 ◽  
Author(s):  
Tadele Haile ◽  
Maria Fuerhacker
Keyword(s):  
Heavy Metals ◽  
Sandy Soil ◽  
Quartz Sand ◽  
Stormwater Runoff ◽  
Column Experiment ◽  
Poor Performance ◽  
Filter Media ◽  
Column Studies ◽  
Natural Quartz ◽  
Removal Efficiencies

Stormwater runoff from roadways often contains a variety of contaminants such as heavy metals, which can adversely impact receiving waters. The filter media in stormwater filtration/infiltration systems play a significant role in the simultaneous removal of multiple pollutants. In this study, the capacity of five filter media—natural quartz sand (QS), sandy soil (SS) and three mineral-based technical filter media (TF-I, TF-II and TF-III)—to adsorb heavy metals (Cu, Pb and Zn) frequently detected in stormwater, as well as remobilization due to de-icing salt (NaCl), were evaluated in column experiments. The column breakthrough data were used to predict lifespan of the filter media. Column experiment operated under high hydraulic load showed that all technical filters and sandy soil achieved >97%, 94% and >80% of Pb, Cu and Zn load removals, respectively, while natural quartz sand (QS) showed very poor performance. Furthermore, treatment of synthetic stormwater by the soil and technical filter media met the requirements of the Austrian regulation regarding maximum effluent concentrations and minimum removal efficiencies for groundwater protection. The results showed that application of NaCl had only a minor impact on the remobilization of heavy metals from the soil and technical filter media, while the largest release of metals was observed from the QS column. Breakthrough analysis indicated that load removal efficiencies at column exhaustion (SS, TF-I, TF-II and TF-III) were >95% for Cu and Pb and 80–97% for Zn. Based on the adsorption capacities, filtration systems could be sized to 0.4 to 1% (TF-I, TF-II and TF-III) and 3.5% (SS) of their impervious catchment area and predicated lifespan of each filter media was at least 35, 36, 41 and 29 years for SS, TF-I, TF-II and TF-III, respectively. The findings of this study demonstrate that soil—based and technical filter media are effective in removing heavy metals and can be utilized in full-stormwater filtration systems.

scholarly journals Enhanced Monovalent Cation Biomineralization Ability by Quartz Sand for Effective Removal of Soluble Iron in Simulated Acid Mine Drainage

Water ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 732
Author(s):  
Heru Wang ◽  
Mengying Li ◽  
Yongwei Song
Keyword(s):  
Heavy Metals ◽  
Acid Mine Drainage ◽  
Removal Efficiency ◽  
Quartz Sand ◽  
Mine Drainage ◽  
Monovalent Cation ◽  
Iron Minerals ◽  
Precipitation Efficiency ◽  
Acid Mine ◽  
Effective Removal

Acid mine drainage (AMD) is characterized by low pH, high soluble Fe, and heavy metal concentrations. Conventional lime neutralization produces large amounts of Fe(OH)2 and Fe(OH)3, which complicate subsequent disposal. Secondary iron minerals synthesized by biomineralization can reduce the concentration of soluble Fe in addition to adsorbing and removing heavy metals in AMD. Therefore, an appropriate method for improving the precipitation efficiency of Fe is urgently needed for AMD treatment. Using simulated AMD, this work analyzes the influence of quartz sand (40 g/L) on the Fe2+ oxidation and total Fe deposition efficiencies, as well as the phases of secondary iron minerals in an Acidithiobacillus ferrooxidans system including K+, Na+, or NH4+ (53.3 mmol/L). Quartz sand had no significant effect on Fe2+ oxidation and 160 mmol/L Fe2+ was completely oxidized by A. ferrooxidans in 168 h, but contributed to the oxidized product (Fe3+) mineralization, improving the total Fe removal efficiency in simulated AMD. Compared with treatments involving K+ or Na+ alone, quartz sand improved the total Fe precipitation efficiency by 26.6% or 30.2%, respectively. X-ray diffraction showed that quartz sand can promote the transformation of the biomineralization pathway from schwertmannite to jarosite with higher yields, which is important for improving the removal efficiency of heavy metals in AMD.

scholarly journals Removal of heavy metals using kaolinite and Bentonite filter media

2018 ◽  
Vol 8 (6) ◽  
Author(s):  
Ghada Heikal
Keyword(s):  
Heavy Metals ◽  
Removal Efficiency ◽  
Retention Time ◽  
Bentonite Clay ◽  
Industrial Wastes ◽  
Synthetic Wastewater ◽  
Analysis Model ◽  
Filter Media ◽  
Mining Operations ◽  
Initial Concentration

Heavy metals are among the most lethal pollutants of surface water. The main sources of heavy metals are industrial wastes from processes such as mining operations and ore processing, smelter, textile, leather dyeing, coating, metal finishing, chemical manufacturing, refineries, power generation and nuclear fuel processing. The concentration of heavy metals should be reduced to the acceptable levels before discharged into the environment because these are non degradable into nontoxic metals end products and the well known damaging effects of heavy metals on human being and other habitants. Sets of experiments were carried out to examine the ability of (kaolinite and bentonite) to reduce the concentration of chromium and cadmium ions in raw synthetic wastewater using upflow filter respectively. The main parameters were solution pH 2-6, retention time 12-72 hrs, the initial concentration of pollutants 100–500 ppm and filter media height 10.5-42 cm. All data were analyzed by regression analysis model to correlate the different boundary conditions. The highest achieved % removal efficiency of Cr and Cd were 96% and 91% through kaolinite and bentonite clay filter media at pH 6.0 and 5.0 respectively, retention time 24 hr, initial concentration 100 ppm and filter media height 42 cm. The results of regression models indicate that the most influential independent variables in the % removal efficiency of Cr and Cd ions from aqueous solutions using kaolinite and bentonite clay upflow filter pH, retention time and height media filter, which affects positively. Results of the experimental data show that the best empirical correlation achieved the highest fitting of predicted % removal of Cr and Cd using kaolinite and bentonite clay separately that gives the highest value of (R2 = 0.995 and 0.988)respectively.

Utilisation of Biomass and Hybrid Biochar from Elephant Grass and Low Density Polyethylene for the Competitive Adsorption of Pb(II), Cu(II), Fe(II) and Zn(II) from Aqueous Media

2020 ◽  
Vol 13 ◽  
Author(s):  
Joshua O. Ighalo ◽  
Lois T. Arowoyele ◽  
Samuel Ogunniyi ◽  
Comfort A. Adeyanju ◽  
Folasade M. Oladipo-Emmanuel ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Removal Efficiency ◽  
Contact Time ◽  
Competitive Adsorption ◽  
Adsorption Process ◽  
Aqueous Media ◽  
Polluted Water ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Elephant Grass

Background: The presence of pollutants in polluted water is not singularized hence pollutant species are constantly in competition for active sites during the adsorption process. A key advantage of competitive adsorption studies is that it informs on the adsorbent performance in real water treatment applications. Objective: This study aims to investigate the competitive adsorption of Pb(II), Cu(II), Fe(II) and Zn(II) using elephant grass (Pennisetum purpureum) biochar and hybrid biochar from LDPE. Method: The produced biochar was characterised by Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR). The effect of adsorption parameters, equilibrium isotherm modelling and parametric studies were conducted based on data from the batch adsorption experiments. Results: For both adsorbents, the removal efficiency was >99% over the domain of the entire investigation for dosage and contact time suggesting that they are very efficient for removing multiple heavy metals from aqueous media. It was observed that removal efficiency was optimal at 2 g/l dosage and contact time of 20 minutes for both adsorbent types. The Elovich isotherm and the pseudo-second order kinetic models were best-fit for the competitive adsorption process. Conclusion: The study was able to successfully reveal that biomass biochar from elephant grass and hybrid biochar from LDPE can be used as effective adsorbent material for the removal of heavy metals from aqueous media. This study bears a positive implication for environmental protection and solid waste management.

scholarly journals Investigation of Heavy Metal Effects on the Anaerobic Co-Digestion Process of Waste Activated Sludge and Septic Tank Sludge

2019 ◽  
Vol 2019 ◽  
pp. 1-9
Author(s):  
Quang-Minh Nguyen ◽  
Duy-Cam Bui ◽  
Thao Phuong ◽  
Van-Huong Doan ◽  
Thi-Nham Nguyen ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Activated Sludge ◽  
Removal Efficiency ◽  
Biogas Production ◽  
Cod Removal ◽  
Septic Tank ◽  
Waste Activated Sludge ◽  
Digestion Process ◽  
Cod Removal Efficiency

The effect of copper, zinc, chromium, and lead on the anaerobic co-digestion of waste activated sludge and septic tank sludge in Hanoi was studied in the fermentation tests by investigating the substrate degradation, biogas production, and process stability at the mesophilic fermentation. The tested heavy metals were in a range of concentrations between 19 and 80 ppm. After the anaerobic tests, the TS, VS, and COD removal efficiency was 4.12%, 9.01%, and 23.78% for the Cu(II) added sample. Similarly, the efficiencies of the Zn(II) sample were 1.71%, 13.87%, and 16.1% and Cr(VI) efficiencies were 15.28%, 6.6%, and 18.65%, while the TS, VS, and COD removal efficiency of the Pb(II) added sample was recorded at 16.1%, 17.66%, and 16.03% at the concentration of 80 ppm, respectively. Therefore, the biogas yield also decreased by 36.33%, 31.64%, 31.64%, and 30.60% for Cu(II), Zn(II), Cr(VI), and Pb(II) at the concentration of 80 ppm, compared to the raw sample, respectively. These results indicated that Cu(II) had more inhibiting effect on the anaerobic digestion of the sludge mixture than Zn(II), Cr(VI), and Pb(II). The relative toxicity of these heavy metals to the co-digestion process was as follows: Cu (the most toxic) > Zn > Cr > Pb (the least toxic). The anaerobic co-digestion process was inhibited at high heavy metal concentration, which resulted in decreased removal of organic substances and produced biogas.

Enhancing the soil heavy metals removal efficiency by adding HPMA and PBTCA along with plant washing agents

2017 ◽  
Vol 339 ◽  
pp. 33-42 ◽  
Author(s):  
Yaru Cao ◽  
Shirong Zhang ◽  
Guiyin Wang ◽  
Ting Li ◽  
Xiaoxun Xu ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Removal Efficiency ◽  
Heavy Metals Removal ◽  
Soil Heavy Metals ◽  
Metals Removal

Preparation of Sands Modified by Aluminous Salt and its Adsorption Capability of CD2+

2011 ◽  
Vol 130-134 ◽  
pp. 856-859
Author(s):  
Chun Sheng Ding ◽  
Yang Ping Fu ◽  
Qian Fen Zhu ◽  
Jing Fu
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Influencing Factors ◽  
Removal Efficiency ◽  
Specific Surface Area ◽  
Quartz Sand ◽  
Ph Value ◽  
Alkaline Condition ◽  
Initial Concentration ◽  
Adsorption Capability

In this experiment quartz sand was chosen as a carrier to be coated by aluminous salt under alkaline condition, and then the specific surface area was tested, and the adsorption capability and Cd2+ removal influencing factors of modified sand were studied. The investigation results showed that the specific surface area of modified sand was 75.244m2/g which was 9.38 times of that of original sand; the removal efficiency of Cd2+ by aluminous salt modified sand reached 59% contrast to 39% of original sand with pH 7.00. It was also found that the removal efficiency of Cd2+ by the aluminous salt modified sand was reduced with the increase of initial concentration of Cd2+ solution, and was enhanced with the increase of pH value, the Cd2+ removal efficiency was almost 71% with pH 9.0.

Understanding the factors influencing the removal of heavy metals in urban stormwater runoff

2016 ◽  
Vol 73 (12) ◽  
pp. 2921-2928 ◽  
Author(s):  
Marla C. Maniquiz-Redillas ◽  
Lee-Hyung Kim
Keyword(s):  
Heavy Metals ◽  
Fine Particles ◽  
Metal Removal ◽  
Low Impact Development ◽  
Heavy Metal Removal ◽  
Stormwater Runoff ◽  
Winter Season ◽  
Filter Media ◽  
Factors Influencing ◽  
Removal Of Heavy Metals

Abstract In this research, an infiltration trench equipped with an extensive pretreatment and filter bed consisting of woodchip, sand and gravel was utilized as a low impact development technique to manage stormwater runoff from a highly impervious road with particular emphasis on heavy metal removal. Findings revealed that the major factors influencing the removal of heavy metals were the concentration of the particulate matters and heavy metals in runoff, runoff volume and flow rates. The reduction of heavy metals was enhanced by sedimentation of particulates through pretreatment. Fine particles (<2 mm) had the most significant amount of heavy metals, thus, enhanced adsorption and filtration using various filter media were important design considerations. Sediment was most highly attached on the surface area of woodchip than to other filter media like sand, gravel and geotextile. It is suggested that maintenance must be performed after the end of the winter season wherein high sediment rate was observed to maintain the efficiency of the treatment system.

scholarly journals Copper and Lead Ions Removal by Electrocoagulation: Process Performance and Implications for Energy Consumption

2021 ◽  
Vol 10 (3) ◽  
pp. 415-424
Author(s):  
Aji Prasetyaningrum ◽  
Dessy Ariyanti ◽  
Widayat Widayat ◽  
Bakti Jos
Keyword(s):  
Heavy Metals ◽  
Energy Consumption ◽  
Removal Efficiency ◽  
Current Density ◽  
High Current Density ◽  
Energy Requirement ◽  
Lead Ions ◽  
Initial Concentration ◽  
Electroplating Wastewater ◽  
Electrocoagulation Process

Electroplating wastewater contains high amount of heavy metals that can cause serious problems to humans and the environment. Therefore, it is necessary to remove heavy metals from electroplating wastewater. The aim of this research was to examine the electrocoagulation (EC) process for removing the copper (Cu) and lead (Pb) ions from wastewater using aluminum electrodes. It also analyzes the removal efficiency and energy requirement rate of the EC method for heavy metals removal from wastewater. Regarding this matter, the operational parameters of the EC process were varied, including time (20−40 min), current density (40−80 A/m2), pH (3−11), and initial concentration of heavy metals. The concentration of heavy metals ions was analyzed using the atomic absorption spectroscopy (AAS) method. The results showed that the concentration of lead and copper ions decreased with the increase in EC time. The current density was observed as a notable parameter. High current density has an effect on increasing energy consumption. On the other hand, the performance of the electrocoagulation process decreased at low pH. The higher initial concentration of heavy metals resulted in higher removal efficiency than the lower concentration. The removal efficiency of copper and lead ions was 89.88% and 98.76%, respectively, at 40 min with electrocoagulation treatment of 80 A/m2 current density and pH 9. At this condition, the specific amounts of dissolved electrodes were 0.2201 kg/m3, and the energy consumption was 21.6 kWh/m3. The kinetic study showed that the removal of the ions follows the first-order model.

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