scholarly journals Simulation-based environmental-impact assessment of glycerol-to-hydrogen conversion technologies

Clean Energy ◽  
2021 ◽  
Vol 5 (3) ◽  
pp. 387-402
Author(s):  
Yehia F Khalil

Abstract This simulation-based comparative assessment aims to quantify the environmental and human-health impacts of greener hydrogen (H2) production via three glycerol-based technologies, including: supercritical water reforming (SCWR), aqueous-phase reforming (APR) and autothermal reforming (ATR). The GaBi (2018 edition) life-cycle assessment (LCA) platform is used to develop cradle-to-gate product system models for these technologies and the TRACI 2.1 methodology is used to quantify their midpoint impact categories. Aspen HYSYS (v11) process-simulation software is used to generate the life-cycle inventory (LCI) primary data required to produce 1 kg of H2 via each of the indicated glycerol-reforming technologies. Per ISO 14040:2006 reporting requirements for the LCA results interpretation step, three base case (BC) scenarios and four sensitivity scenarios (SS) are developed and quantified to compare the effects of different process electricity sources (US grid mix versus wind power) and thermal energy sources (natural gas versus biogas) on the LCA results. The high operating pressure (viz. 240 bar) of SCWR enabled assessment of the impact of in situ electricity generation to offset some of electricity required for this technology. The major insights from this research are as follows: (i) per 1 kg of produced H2, APR reduces CO2 emissions by ≈95% compared to ATR and by ≈92% compared to SCWR, (ii) for BC scenarios, the primary energy consumption (in MJ/kg of produced H2) is in the following order from highest to lowest: ATR > SCWR > APR and (iii) H2 production via glycerol APR is more environmentally sustainable than SCWR and ATR, and thus offers a promising path for greener H2 production. Future environmental sustainability studies should focus on expanding the scope of this study to include H2 production via water electrolysis using renewable electricity sources and via solar and nuclear-driven thermochemical water splitting.

2021 ◽  
Vol 13 (21) ◽  
pp. 11693
Author(s):  
Mayra L. Pazmiño ◽  
Angel D. Ramirez

Pork is one of the proteins of greatest demand worldwide. This study has evaluated the environmental sustainability of pig production by applying the life cycle assessment methodological framework. The system boundaries include feed production, pig production, slaughtering, and slaughterhouse by-product management. Within this context, three scenarios have been proposed: the first related to the management of slaughter by-products in an open dump, the second contemplates a model for using these by-products in a rendering plant, and a third where the environmental burden of slaughterhouse co-products is portioned according to economic allocation. The primary data collected correspond to the period of 2019 for the facilities of a producer in a coastal province of Ecuador. Three functional units were used—“1 kg of pig carcass at the slaughterhouse gate”, “1 kg pig live weigh at the farm gate”, and “1 kg of feed at the plant gate”. The impact categories included were global warming, fossil depletion, marine eutrophication, ozone layer depletion, particulate matter formation, photochemical oxidation formation, and terrestrial acidification. The results revealed that the production of ingredients for feed is the largest contributor to the environmental burden of pig and pork. The rendering of slaughter by-products that avoid the production of other fats and proteins results in a lower environmental impact than the other scenarios in almost all categories.


2016 ◽  
Vol 11 (6) ◽  
pp. 225 ◽  
Author(s):  
Jonathan Annan ◽  
Nathaniel Boso ◽  
Dominic Essuman

Following the growing concerns on the inconsistent findings in previous research and drawing on the social exchange and networking theories, this study re-examined the impact of supply chain integration (SCI) on business performance (i.e. value creation and financial performance). The study argues that the impact of SCI on financial performance is through value creation and is depended upon longevity of product life cycle. Using primary data from 79 firms in Ghana, the study finds that value creation is a short-run consequence of SCI while financial performance is a long-run outcome of SCI. Additionally, results show that the financial performance outcome of SCI is experienced more from integrative efforts than from the value creation outcome. Results further indicate that firms whose products stay relatively shorter on the market are more likely to experience lower positive impact of SCI on value creation, and thus firms’ ability to become proactive, monitor, and collect market information on product performance throughout its life cycle is key for coming out with strategies that will enable them maximize product’s life span so as to experience greater benefits that come with pursuing integration with other channel members.


2005 ◽  
Vol 895 ◽  
Author(s):  
Antonia Moropoulou ◽  
Christopher Koroneos ◽  
Maria Karoglou ◽  
Eleni Aggelakopoulou ◽  
Asterios Bakolas ◽  
...  

AbstractOver the years considerable research has been conducted on masonry mortars regarding their compatibility with under restoration structures. The environmental dimension of these materials may sometimes be a prohibitive factor in the selection of these materials. Life Cycle Assessment (LCA) is a tool that can be used to assess the environmental impact of the materials. LCA can be a very useful tool in the decision making for the selection of appropriate restoration structural material. In this work, a comparison between traditional type of mortars and modern ones (cement-based) is attempted. Two mortars of traditional type are investigated: with aerial lime binder, with aerial lime and artificial pozzolanic additive and one with cement binder. The LCA results indicate that the traditional types of mortars are more sustainable compared to cementbased mortars. For the impact assessment, the method used is Eco-indicator 95


Energies ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4998
Author(s):  
Vasileios Ntouros ◽  
Ioannis Kousis ◽  
Dimitra Papadaki ◽  
Anna Laura Pisello ◽  
Margarita Niki Assimakopoulos

In the last twenty years, research activity around the environmental applications of metal–organic frameworks has bloomed due to their CO2 capture ability, tunable properties, porosity, and well-defined crystalline structure. Thus, hundreds of MOFs have been developed. However, the impact of their production on the environment has not been investigated as thoroughly as their potential applications. In this work, the environmental performance of various synthetic routes of MOF nanoparticles, in particular ZIF-8, is assessed through a life cycle assessment. For this purpose, five representative synthesis routes were considered, and synthesis data were obtained based on available literature. The synthesis included different solvents (de-ionized water, methanol, dimethylformamide) as well as different synthetic steps (i.e., hours of drying, stirring, precursor). The findings revealed that the main environmental weak points identified during production were: (a) the use of dimethylformamide (DMF) and methanol (MeOH) as substances impacting environmental sustainability, which accounted for more than 85% of the overall environmental impacts in those synthetic routes where they were utilized as solvents and as cleaning agents at the same time; (b) the electricity consumption, especially due to the Greek energy mix which is fossil-fuel dependent, and accounted for up to 13% of the overall environmental impacts in some synthetic routes. Nonetheless, for the optimization of the impacts provided by the energy use, suggestions are made based on the use of alternative, cleaner renewable energy sources, which (for the case of wind energy) will decrease the impacts by up to 2%.


Forests ◽  
2022 ◽  
Vol 13 (1) ◽  
pp. 70
Author(s):  
Joshua P. Weyrens ◽  
Obste Therasme ◽  
René H. Germain

Forests are used to mitigate anthropogenic greenhouse gas (GHG) emissions through carbon offset programs, and forest management is generally accepted as “carbon neutral”. However, forest harvesting operations depend heavily on fossil fuels, so it would be remiss to broadly paint all forms of management as carbon neutral without empirical verification of this claim. Biomass feedstock, as a means to supplant fossil fuel consumption, has received the bulk of investigative efforts, as the carbon benefit of biomass is one of the most contentious among wood products, because it does not create long-term carbon storage. A life cycle assessment (LCA) was conducted on a winter shelterwood harvest occurring in the Adirondacks of upstate New York. Primary data were collected daily throughout the operation and used to model the impact attributed to producing clean chips and logs for delivery to a pulp mill and sawmill, respectively. This harvest produced 4894 Mg of clean chips and 527 Mg of sawtimber. We calculated that 39.77 and 25.16 kg of carbon dioxide equivalent were emitted per Mg of clean chips and sawtimber, respectively, with a total observed flow of GHG into the atmosphere between 206 and 210 thousand kilograms. The results contribute to our understanding of the global warming potential of implementing a forest harvest to produce raw materials for medium- and long-term carbon storage products such as paper and dimensional hardwood lumber.


Energies ◽  
2020 ◽  
Vol 13 (23) ◽  
pp. 6345
Author(s):  
Christian Aichberger ◽  
Gerfried Jungmeier

We compiled 50 publications from the years 2005–2020 about life cycle assessment (LCA) of Li-ion batteries to assess the environmental effects of production, use, and end of life for application in electric vehicles. Investigated LCAs showed for the production of a battery pack per kWh battery capacity a median of 280 kWh/kWh_bc (25%-quantile–75%-quantile: 200–500 kWh/kWh_bc) for the primary energy consumption and a median of 120 kg CO2-eq/kWh_bc (25%-quantile–75%-quantile: 70–175 kg CO2-eq/kWh_bc) for greenhouse gas emissions. We expect results for current batteries to be in the lower range. Over the lifetime of an electric vehicle, these emissions relate to 20 g CO2-eq/km (25%-quantile–75%-quantile: 10–50 g CO2-eq/km). Considering recycling processes, greenhouse gas savings outweigh the negative environmental impacts of recycling and can reduce the life cycle greenhouse gas emissions by a median value of 20 kg CO2-eq/kWh_bc (25%-quantile–75%-quantile: 5–29 kg CO2-eq/kWh_bc). Overall, many LCA results overestimated the environmental impact of cell manufacturing, due to the assessments of relatively small or underutilized production facilities. Material emissions, like from mining and especially processing from metals and the cathode paste, could have been underestimated, due to process-based assumptions and non-regionalized primary data. Second-life applications were often not considered.


2017 ◽  
Vol 75 (10) ◽  
pp. 2246-2256 ◽  
Author(s):  
Nitin Kumar Singh ◽  
Rana Pratap Singh ◽  
Absar Ahmad Kazmi

In the present study, a life cycle assessment (LCA) approach was used to analyse the environmental impacts associated with the construction and operational phases of an integrated fixed-film activated sludge (IFAS) reactor treating municipal wastewater. This study was conducted within the boundaries of a research project that aimed to investigate the implementation related challenges of a package type IFAS reactor from an environmental perspective. Along with the LCA results of the construction phase, a comparison of the LCA results of seven operational phases is also presented in this study. The results showed that among all the inputs, the use of stainless steel in the construction phase caused the highest impact on environment, followed by electricity consumption in raw materials production. The impact of the construction phase on toxicity impact indicators was found to be significant compared to all operational phases. Among the seven operational phases of this study, the dissolved oxygen phase III, having a concentration of ∼4.5 mg/L, showed the highest impact on abiotic depletion, acidification, global warming, ozone layer depletion, human toxicity, fresh water eco-toxicity, marine aquatic eco-toxicity, terrestrial eco-toxicity, and photochemical oxidation. However, better effluent quality in this phase reduced the eutrophication load on environment.


2021 ◽  
Vol 13 (3) ◽  
pp. 1195
Author(s):  
Ravijanya Chippagiri ◽  
Hindavi R. Gavali ◽  
Rahul V. Ralegaonkar ◽  
Mike Riley ◽  
Andy Shaw ◽  
...  

Under the India “Housing for all” scheme, 20 million urban houses have to be constructed by 2022, which requires the rate of construction to be around 8000 houses/day. Previous results by the team show that present design methods for affordable buildings and structures in India need improvement. The challenges are the disposal of solid waste generated from agro-industrial activities and the energy peak demand in extremely hot and cold seasons. The development of bio-based urban infrastructure which can adapt to the climatic conditions has been proposed. Inclusion of sustainable materials such as agro-industrial by-products and insulation materials has resulted in effective environmental sustainability and climate change adaptability. Precast components are highlighted as a suitable solution for this purpose as well as to fulfil the need of mass housing. India has a lesser record in implementing this prefab technology when compared to a global view. For the first time, a novel and sustainable prefab housing solution is tested for scale-up using industrial waste of co-fired blended ash (CBA) and the results are presented here. A model house of real scale measuring 3 × 3 × 3 m3 was considered as a base case and is compared with 17 other combinations of model house with varying alignment of prefab panels. Comparison was made with commercially available fly ash brick and CBA brick with a conventional roof slab. A simulation study was conducted regarding cost and energy analysis for all the 18 cases. Various brick and panel compositions with CBA for housing were tried and the superior composition was selected. Similarly, 18 model houses of real scale were simulated, with different combinations of walls made of bricks or panels and different building orientations, to check the impact on energy peak cooling and cost. Results show that peak cooling load can be reduced by six times with bio-based prefab panels. Prefab construction can be considered for mass housing ranging above 100 housing units, each consisting of an area of 25 m2.


2021 ◽  
Vol 14 (1) ◽  
pp. 92
Author(s):  
Isabella Bianco ◽  
Deborah Panepinto ◽  
Mariachiara Zanetti

Waste-to-energy (WtE) technologies can offer sustainable solutions for waste, which can no more be reused or recycled, such as the part of municipal solid waste (MSW) that is not suitable for recycling processes. This study focused on the environmental consequences of the production of electricity from incineration and gasification of MSW. To this aim, the standardised life cycle assessment (LCA) methodology was used. A life cycle inventory, mainly composed by primary data, is provided. Starting from these data, different highly shared LCA approaches were used to calculate the potential impacts of 1 kWh provided by the two analysed WtE technologies. The different approaches concern the method of accounting for the by-products (through an economic allocation and a system expansion) and the inclusion/exclusion of environmental benefits due to the avoided landfill for the MSW. For each approach, impact-assessment results were calculated with the ReCiPe midpoint (H) method. A comparison was carried out (i) between the results obtained for the same WtE technology but calculated with different approaches and (ii) between the impact results of electricity generated by the two WtE technologies calculated with the same approach. From the study, it emerged that, according to the accounting rules, the impact results can significantly change and, for some impact categories, even lead to opposite conclusions. In the absence of category rules that harmonise the environmental assessments of WtE processes, it is therefore recommended that the development/use/reproduction/comparison of studies focused on the valorisation of waste should be carried out with caution.


2021 ◽  
Vol 11 ◽  
Author(s):  
Haiyan Li ◽  
Javaria Hameed ◽  
Rafique Ahmed Khuhro ◽  
Gadah Albasher ◽  
Wedad Alqahtani ◽  
...  

This study discusses the impact of different economic indicators on economic stability, including honest leadership, improved infrastructure, revenue generation, and CPEC taking into account the double mediating role of environmental sustainability and sustainable development, while considering the latest COVID-19 situation. This study adopted primary data collection methods and obtained data from the employees of CPEC by using questionnaires and smart-PLS for analysis purposes. The results revealed that honest leadership, improved infrastructure, revenue generation, and CPEC have a positive nexus with economic stability. Despite the severe impact of COVID-19 on the country’s economy, the economic corridor plays a vital role in stabilizing the state’s economy and supports all those related to this phenomenal project either directly or indirectly.


Sign in / Sign up

Export Citation Format

Share Document