Optimization in trace atomic spectroscopy
Philosophical Transactions of the Royal Society of London Series A Physical and Engineering Sciences
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1990 ◽
Vol 333
(1628)
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pp. 161-161
Keyword(s):
Optimization of analytical instrumentation enables realization of potential and the valid comparisons of techniques, hence the interest in rigorous, mathematically based, optimization procedures. One of the most effective procedures is variable stepsize simplex. Using a simple algorithm, sets of initial operating parameters can be tested and instrumental,response evaluated. The worst response is rejected and a new set evaluated, thus in a logical manner the optimal conditions are identified. Particular benefits are speed, computer compatibility, relative freedom from false optima and the irrelevance of prior assumptions or knowledge about response surfaces
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1973 ◽
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