Fused deposition modeling with polyamide 1012

2019 ◽  
Vol 25 (7) ◽  
pp. 1145-1154 ◽  
Author(s):  
Xia Gao ◽  
Daijun Zhang ◽  
Xiangning Wen ◽  
Shunxin Qi ◽  
Yunlan Su ◽  
...  

Purpose This work aims to develop a new kind of semicrystalline polymer filament and optimize its printing parameters in the fused deposition modeling process. The purpose of this work also includes producing FDM parts with good ductility. Design/methodology/approach A new kind of semicrystalline filaments composed of long-chain polyamide (PA)1012 was prepared by controlling screw speed and pulling speed carefully. The optimal printing parameters for PA1012 filaments were explored through investigating dimensional accuracy and bonding strength of FDM parts. Furthermore, the mechanical properties of PA1012 specimens were also evaluated by varying nozzle temperatures and raster angles. Findings It is found that PA1012 filaments can accommodate for FDM process under suitable printing parameters. The print quality and mechanical properties of FDM parts highly depend on nozzle temperature and bed temperature. Even though higher temperatures facilitate stronger interlayer bonding, FDM parts with excellent tensile strength were obtained at a moderate nozzle temperature. Moreover, a bed temperature well above the glass transition temperature of PA1012 can eliminate shrinkage and distortion of FDM parts. As expected, FDM parts prepared with PA1012 filaments exhibit good ductility. Originality/value Results in this work demonstrate that the PA1012 filament allows the production of FDM parts with desired mechanical performance. This indicates the potential for overcoming the dependence on amorphous thermoplastics as a feedstock in the FDM technique. This work also provides insight into the effect of materials properties on the mechanical performance of FDM-printed parts.

2018 ◽  
Vol 31 (1) ◽  
pp. 97-106 ◽  
Author(s):  
Shenglong Jiang ◽  
Guangxin Liao ◽  
Dingding Xu ◽  
Fenghua Liu ◽  
Wen Li ◽  
...  

Polyetherimide (PEI) is a kind of high-performance polymer, which possesses a high glass transition temperature ( Tg), excellent flame retardancy, low smoke generation, and good mechanical properties. In this article, PEI was applied in the fused deposition modeling (FDM)–based 3-D printing for the first time. The entire process from filament extrusion to printing was studied. It was observed that the filament orientation and nozzle temperature were closely related to the mechanical properties of printed samples. When the nozzle temperature is 370°C, the mean tensile strength of FDM printing parts can reach to 104 MPa, which is only 7% lower than that of injection molded parts. It can be seen that the 0° orientation set of samples show the highest storage modulus (2492 MPa) followed by the 45° samples, and the 90° orientation set of samples show the minimum storage modulus (1420 MPa) at room temperature. The above results indicated that this technique allows the production of parts with adequate mechanical performance, which does not need to be restricted to the production of mock-ups and prototypes. Our work broke the limitations of traditional FDM technology and expanded the types of material available for FDM to the high-temperature engineering plastics.


2017 ◽  
Vol 23 (4) ◽  
pp. 804-810 ◽  
Author(s):  
Shiqing Cao ◽  
Dandan Yu ◽  
Weilan Xue ◽  
Zuoxiang Zeng ◽  
Wanyu Zhu

Purpose The purpose of this paper is to prepare a new modified polybutylene terephalate (MPBT) for fused deposition modeling (FDM) to increase the variety of materials compatible with printing. And the printing materials can be used to print components with a complex structure and functional mechanical parts. Design/methodology/approach The MPBT, poly(butylene terephalate-co-isophthalate-co-sebacate) (PBTIS), was prepared for FDM by direct esterification and subsequent polycondensation using terephthalic acid (PTA), isophthalic acid (PIA), sebacic acid (SA) and 1,4-butanediol (BDO). The effects of the content of PIA (20-40 mol%) on the mechanical properties of PBTIS were investigated when the mole per cent of SA (αSA) is zero. The effects of αSA (0-7mol%) on the thermal, rheological and mechanical properties of PBTIS were investigated at nPTA/nPIA = 7/3. A desktop wire drawing and extruding machine was used to fabricate the filaments, whose printability and anisotropy were tested by three-dimensional (3D) printing experiments. Findings A candidate content of PIA introducing into PBT was obtained to be about 30 per cent, and the Izod notched impact strength of PBTIS increased with the increase of αSA. The results showed that the PBTIS (nPTA/nPIA = 7/3, αSA = 3-5mol%) is suitable for FDM. Originality/value New printing materials with good Izod notched impact strength were obtained by introducing PIA and SA (nPTA/nPIA = 7/3, αSA = 3-5 mol%) into PBT and their anisotropy are better than that of ABS.


2021 ◽  
pp. 089270572110530
Author(s):  
Nagarjuna Maguluri ◽  
Gamini Suresh ◽  
K Venkata Rao

Fused deposition modeling (FDM) is a fast-expanding additive manufacturing technique for fabricating various polymer components in engineering and medical applications. The mechanical properties of components printed with the FDM method are influenced by several process parameters. In the current work, the influence of nozzle temperature, infill density, and printing speed on the tensile properties of specimens printed using polylactic acid (PLA) filament was investigated. With an objective to achieve better tensile properties including elastic modulus, tensile strength, and fracture strain; Taguchi L8 array has been used for framing experimental runs, and eight experiments were conducted. The results demonstrate that the nozzle temperature significantly influences the tensile properties of the FDM printed PLA products followed by infill density. The optimum processing parameters were determined for the FDM printed PLA material at a nozzle temperature of 220°C, infill density of 100%, and printing speed of 20 mm/s.


2019 ◽  
Vol 25 (3) ◽  
pp. 462-472 ◽  
Author(s):  
Oluwakayode Bamiduro ◽  
Gbadebo Owolabi ◽  
Mulugeta A. Haile ◽  
Jaret C. Riddick

Purpose The continual growth of additive manufacturing has increased tremendously because of its versatility, flexibility and high customization of geometric structures. However, design hurdles are presented in understanding the relationship between the fabrication process and materials microstructure as it relates to the mechanical performance. The purpose of this paper is to investigate the role of build architecture and microstructure and the effects of load direction on the static response and mechanical properties of acrylonitrile butadiene styrene (ABS) specimens obtained via the fused deposition modeling (FDM) processing technique. Design/methodology/approach Among additive manufacturing processes, FDM is a prolific technology for manufacturing ABS. The blend of ABS combines strength, rigidity and toughness, all of which are desirable for the production of structural materials in rapid manufacturing applications. However, reported literature has varied widely on the mechanical performance due to the proprietary nature of the ABS material ratio, ultimately creating a design hurdle. While prior experimental studies have studied the mechanical response via uniaxial tension testing, this study has aimed to understand the mechanical response of ABS from the materials’ microstructural point of view. First, ABS specimen was fabricated via FDM using a defined build architecture. Next, the specimens were mechanically tested until failure. Then finally, the failure structures were microstructurally investigated. In this paper, the effects of microstructural evolution on the static mechanical response of various build architecture of ABS aimed at FDM manufacturing technique was analyzed. Findings The results show that the rastering orientation of 0/90 exhibited the highest tensile strength followed by fracture at its maximum load. However, the “45” bead direction of the ABS fibers displayed a cold-drawing behavior before rupture. The morphology analyses before and after tensile failure were characterized by a scanning electron microscopy (SEM) which highlighted the effects of bead geometry (layers) and areas of stress concentration such as interstitial voids in the material during build, ultimately compromising the structural integrity of the specimens. Research limitations/implications The ability to control the constituents and microstructure of a material during fabrication is significant to improving and predicting the mechanical performance of structural additive manufacturing components. In this report, the effects of microstructure on the mechanical performance of FDM-fabricated ABS materials was discussed. Further investigations are planned in understanding the effects of ambient environmental conditions (such as moisture) on the ABS material pre- and post-fabrication. Originality/value The study provides valuable experimental data for the purpose of understanding the inter-dependency between build parameters and microstructure as it relates to the specimens exemplified strength. The results highlighted in this study are fundamental to the development of optimal design of strength and complex ultra-lightweight structure efficiency.


2020 ◽  
Author(s):  
Muhammad Salman Mustafa ◽  
Muhammad Qasim Zafar ◽  
Muhammad Arslan Muneer ◽  
Muhammad Arif ◽  
Farrukh Arsalan Siddiqui ◽  
...  

Abstract Fused Deposition Modeling (FDM) is a widely adopted additive manufacturing process to produce complex 3D structures and it is typically used in the fabrication of biodegradable materials e.g. PLA/PHA for biomedical applications. However, FDM as a fabrication process for such material needs to be optimized to enhance mechanical properties. In this study, dogbone and notched samples are printed with the FDM process to determine optimum values of printing parameters for superior mechanical properties. The effect of layer thickness, infill density, and print bed temperature on mechanical properties is investigated by applying response surface methodology (RSM). Optimum printing parameters are identified for tensile and impact strength and an empirical relation has been formulated with response surface methodology (RSM). Furthermore, the analysis of variance (ANOVA) was performed on the experimental results to determine the influence of the process parameters and their interactions. ANOVA results demonstrate that 44.7% infill density, 0.44 mm layer thickness, and 20C° printing temperatures are the optimum values of printing parameters owing to improved tensile and impact strength respectively. The experimental results were found in strong agreement with the predicted theoretical results.


2017 ◽  
Vol 23 (5) ◽  
pp. 869-880 ◽  
Author(s):  
Ying-Guo Zhou ◽  
Bei Su ◽  
Lih-sheng Turng

Purpose Although the feasibility and effectiveness of the fused deposition modeling (FDM) method have been proposed and developed, studies of applying this technology to various materials are still needed for researching its applicability, especially with regard to polymer blends and composites. The purpose of this paper is to study the deposition-induced effect and the effect of compatibilizers on the mechanical properties of polypropylene and polycarbonate (PP/PC) composites. Design/methodology/approach For this purpose, three different deposition modes for PP/PC composites with or without compatibilizers were used for the FDM method and tested for tensile properties. Also, parts with the same materials were made by injection molding and used for comparison. In addition, different deposition speeds were used to investigate the different deposition-induced effects. Furthermore, the behavior of the mechanical properties was clarified with scanning electron microscope images of the fracture surfaces. Findings The research results suggest that the deposition orientation has a significant influence on the mechanical behavior of PP/PC composite FDM parts. The results also indicate that there is a close relationship between the mechanical properties and morphological structures which are deeply influenced by compatibilization. Compared with injection molded parts, the ductility of the FDM parts can be dramatically improved due to the formation of fibrils and micro-fibrils by the deposition induced during processing. Originality/value This is the first paper to investigate a PP/PC composite FDM process. The results of this paper verified the applicability of PP/PC composites to FDM technology. It is also the first time that the deposition-induced effect during FDM has been investigated and studied.


2017 ◽  
Vol 23 (5) ◽  
pp. 943-953 ◽  
Author(s):  
Anthony A. D’Amico ◽  
Analise Debaie ◽  
Amy M. Peterson

Purpose The aim of this paper is to examine the impact of layer thickness on irreversible thermal expansion, residual stress and mechanical properties of additively manufactured parts. Design/methodology/approach Samples were printed at several layer thicknesses, and their irreversible thermal expansion, tensile strength and flexural strength were determined. Findings Irreversible thermal strain increases with decreasing layer thickness, up to 22 per cent strain. Tensile and flexural strengths exhibited a peak at a layer thickness of 200 μm although the maximum was not statistically significant at a 95 per cent confidence interval. Tensile strength was 54 to 97 per cent of reported values for injection molded acrylonitrile butadiene styrene (ABS) and 29 to 73 per cent of those reported for bulk ABS. Flexural strength was 18 to 41 per cent of reported flexural strength for bulk ABS. Practical implications The large irreversible thermal strain exhibited that corresponding residual stresses could lead to failure of additively manufactured parts over time. Additionally, the observed irreversible thermal strains could enable thermally responsive shape in additively manufactured parts. Variation in mechanical properties with layer thickness will also affect manufactured parts. Originality/value Tailorable irreversible thermal strain of this magnitude has not been previously reported for additively manufactured parts. This strain occurs in parts made with both high-end and consumer grade fused deposition modeling machines. Additionally, the impact of layer thickness on tensile and flexural properties of additively manufactured parts has received limited attention in the literature.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Samir Kasmi ◽  
Geoffrey Ginoux ◽  
Eric Labbé ◽  
Sébastien Alix

Purpose The purpose of this study is to test a flexible polymer with different characteristics compared to other classical polymers mostly used in the additive manufacturing process, and to improve its mechanical properties and microstructure, by modifying different printing parameters, to make it more suitable for various industrial applications. Design/methodology/approach Seven parameters were tested, namely, nozzle temperature, bed temperature, layer thickness, printing speed, flow rate, printing time gap between two successive printed layers and raster orientation. Rheological characterizations were conducted to evaluate the influence of nozzle temperature on the melt viscosity of thermoplastic polyurethane (TPU). The effect of thermal printing parameters on the crystallinity behavior was explored. Tomographic characterizations were realized to measure the porosity and evaluate the internal structure quality of printed specimens. Findings Increases of the nozzle temperature, bed temperature, layer thickness and flow rate had a positive influence on the tensile strength properties of TPU with a reduction of porosity. Higher printing speeds created defects and negatively influenced the strength properties of TPU. An increase in the printing time gap between layers led to poor interlayer adhesion and decreased the tensile strength. Specimens with layers all oriented parallel to the loading direction exhibited superior mechanical properties compared to other raster orientations. Originality/value Thermoplastic elastomers are a unique class of polymers characterized by the combined thermal, chemical and mechanical properties of their elastomer and thermoplastic parts. TPU elastomer, as one of the elastomer families, has found an important position in the bioengineering and three-dimensional printing industry. This study reports a comprehensive study of the impact of additive manufacturing parameters on the properties of TPU.


2017 ◽  
Vol 23 (6) ◽  
pp. 973-982 ◽  
Author(s):  
Hao Li ◽  
Shuai Zhang ◽  
Zhiran Yi ◽  
Jie Li ◽  
Aihua Sun ◽  
...  

Purpose This work aims to evaluate the influence of rheological properties of building materials on the bonding quality and ultimate tensile strength in the fused deposition modeling (FDM) process, through the investigation of parts printed by semi-crystalline and amorphous resins. Little information is currently available about the influence of the crystalline nature on FDM-printed part quality. Design/methodology/approach Semi-crystalline polyamide 12 and amorphous acrylonitrile butadiene styrene (ABS) were used to assess the influence of rheological properties on bonding quality and the tensile strength, by varying three important process parameters: materials, liquefier temperature and raster orientation. A fractography of both tensile and freeze-fractured samples was also investigated. Findings The rheological properties, mainly the melt viscosity, were found to have a significant influence on the bonding quality of fused filaments. Better bonding quality and higher tensile strength of FDM parts printed with semi-crystalline PA12, as compared with amorphous ABS, are suggested to be a result of higher initial sintering rates owing to the lower melt viscosity of PA12 at low shear rates. Near-full dense PA12 parts were obtained by FDM. Originality/value This project provides a variety of data and insight regarding the effect of materials properties on the mechanical performance of FDM-printed parts. The results showed that FDM technique allows the production of PA12 parts with adequate mechanical performance, overcoming the greatest limitation of a dependence on amorphous thermoplastics as a feedstock for the production of prototypes.


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