scholarly journals Comparison of Rheological Properties of Hopped Wort and Malt Wort

2015 ◽  
Vol 63 (1) ◽  
pp. 131-136
Author(s):  
Petr Trávníček ◽  
Josef Los ◽  
Petr Junga
Keyword(s):  
Activation Energy ◽  
Mathematical Model ◽  
Time Dependence ◽  
Hysteresis Loop ◽  
Rheological Properties ◽  
Newtonian Fluid ◽  
Low Temperatures ◽  
Model Tests ◽  
Temperature Range ◽  
Thixotropic Behaviour

The aim of this work is determination rheological properties of hopped wort and malt wort and their comparison. In the paper following rheological properties has been described: the dependence of viscosity on a temperature of a sample and hysteresis loop test. The time dependence test was performed for a confirmation thixotropic behaviour. Based on measured values Arrhenius mathematical model has been applied. The activation energy was determined by using of this model. Tests have been carried out in the temperature range from 5 °C to 40 °C. Rheological tests proved that malt wort behaves as Newtonian fluid in all temperatures and hopped wort behaves as non-Newtonian fluid at low temperatures. Thixotropic behaviour is caused by the content of the rests of hops heads or malt scraps.

THE REACTION OF HYDROGEN AND DEUTERIUM ATOMS WITH PROPANE

1939 ◽  
Vol 17b (12) ◽  
pp. 371-384 ◽  
Author(s):  
E. W. R. Steacie ◽  
N. A. D. Parlee
Keyword(s):  
Activation Energy ◽  
High Temperatures ◽  
Low Temperatures ◽  
Hydrogen Atoms ◽  
Temperature Range ◽  
Secondary Reactions

The reaction of hydrogen atoms with propane has been investigated over the temperature range 30° to 250 °C. by the Wood-Bonhoeffer method. The products are solely methane at low temperatures, and methane, ethane, and ethylene at higher temperatures.It is concluded that the results can be explained only by the assumption that the reaction[Formula: see text]is of importance. The bearing of this on the Rice-Herzfeld mechanisms is discussed. The activation energy of the reaction is 10 ± 2 Kcal.The main steps in the postulated mechanism are:Primary Reaction[Formula: see text]Secondary Reactions at Low Temperatures[Formula: see text]Additional Secondary Reactions at High Temperatures[Formula: see text]The reaction of deuterium atoms with propane was also investigated. It was found that the methane and ethane produced were highly deuterized, while the propane was not appreciably exchanged.

scholarly journals THE REACTION OF HYDROGEN ATOMS WITH ISOBUTANE

1942 ◽  
Vol 20b (11) ◽  
pp. 255-264 ◽  
Author(s):  
W. Harold White ◽  
C. A. Winkler ◽  
B. J. Kenalty
Keyword(s):  
Activation Energy ◽  
Discharge Tube ◽  
Low Temperatures ◽  
Molecular Hydrogen ◽  
Methane Content ◽  
Hydrogen Atoms ◽  
Dehydrogenation Reaction ◽  
Temperature Range ◽  
Secondary Reactions

The reaction of hydrogen atoms with isobutane has been investigated by the Wood–Bonhoeffer discharge tube method, over a temperature range 30° to 250 °C. An activation energy of 10.5 ± 1.5 kcal. was obtained for the reaction.The nature of the products at a given temperature was found to depend upon the concentration of hydrogen atoms present. With low atom concentrations (5 to 9%) methane was essentially the only product at temperatures below 170 °C. At 250 °C., ethane was formed to the extent of approximately one-half the amount of methane. With higher atom concentrations (14 to 24%) ethane was formed in appreciable quantities at 140° to 170 °C., and exceeded the methane content at 250 °C. Small amounts of propane were formed at the higher temperatures.The results at low temperatures appear to be satisfactorily explained by assuming a primary dehydrogenation reaction:[Formula: see text]followed by a series of "atomic cracking" reactions. To account for the behaviour at higher temperatures, additional secondary reactions, involving decomposition of radicals and their reaction with molecular hydrogen, are assumed.

CREEP ACTIVATION ENERGY OF FLOW PROCESS IN Sn0.2Bi1.8Te3 SINGLE CRYSTALS

2004 ◽  
Vol 11 (04n05) ◽  
pp. 443-446
Author(s):  
P. H. SONI ◽  
C. F. DESAI ◽  
S. R. BHAVSAR
Keyword(s):  
Activation Energy ◽  
Time Dependence ◽  
Temperature Dependence ◽  
Single Crystals ◽  
Vickers Microhardness ◽  
Indentation Creep ◽  
Flow Process ◽  
Creep Activation Energy ◽  
Temperature Range ◽  
Different Temperatures

Temperature dependence of the Vickers microhardness of Sn 0.2 Bi 1.8 Te 3 single crystals has been studied. Loading time dependence of microhardness at different temperatures has been used for creep study in the temperature range 303 K–373 K. The activation energy for indentation creep of the crystals has been evaluated.

Charge Transport and Relaxation in Triglycine Sulphate (TGS)

1997 ◽  
Vol 52 (8-9) ◽  
pp. 621-628 ◽  
Author(s):  
W. Osak
Keyword(s):  
Phase Transition ◽  
Activation Energy ◽  
Electrical Conductivity ◽  
Relaxation Time ◽  
Low Temperatures ◽  
Relaxation Times ◽  
Crystallographic Direction ◽  
Triglycine Sulphate ◽  
Temperature Range ◽  
Space Charge Limited Currents

Abstract Charging currents, J-V characteristics and electron conductivity have been measured in triglycine sulphate along three crystallographic directions: a, b and c. The measurements have been taken in a wide temperature range between −196°C and 80 °C. It is found that the charging currents have short relaxation times in the directions: a and c and a long relaxation time along the ferroelec-tric b axis. The J-V characteristics in the direction of the a and c axes have the shapes characteristic for linear dielectrics with space charge limited currents. The J-V characteristic for the b axis depends on the temperature: In the region of the phase transition the Fridkin-Kreher formula (J ∝ V4/3) is satisfied; for low temperatures characteristic agrees with SCLC theory for linear dielectrics with Gaussian traps energy distribution. The d.c. conductivity along the c axis is much higher than along the a and b axes. In the investigated temperature range, the electrical conductivity has an activation character. For −100 °C < T < −193 °C there is: σ ∝ (1/T) exp (− E/kT) . The activation energy depends both on the crystallographic direction and on the temperature-range. For low temperatures, T < −100 °C, the activation energies are very small (of the order of a few hundreds eV).

Features of radiothermoluminescence of polypropylene and ethylene propylenediene elastomer SKEPT-4044 compositions with nanoscale metal-containing fillers

2020 ◽  
pp. 66-73
Author(s):  
A.M. Magerramov ◽  
◽  
N.I. Kurbanova ◽  
M.N. Bayramov ◽  
N.A. Alimirzoyeva ◽  
...  
Keyword(s):  
Transition Temperature ◽  
Molecular Mobility ◽  
Fe3o4 Nanoparticles ◽  
Low Temperatures ◽  
Frost Resistance ◽  
Relaxation Processes ◽  
Ethylene Propylene ◽  
Temperature Range ◽  
Β Relaxation

Using radiothermoluminescence (RTL), the molecular mobility features in the temperature range of 77-300 K were studied for the polypropylene (PP)/ethylene propylene diene elastomer SKEPT-4044 with NiO, Cu2O and Fe3O4 nanoparticles (NPs) based on ABS-acrylonitrile butadiene or SCS-divinyl styrene matrices. It has been shown that the introduction of nanofillers in PP significantly affects the nature and temperature of γ- and β-relaxation processes, while the region of manifestation of the β-process noticeably shifts to the region of low temperatures. Composites with Cu2O NPs have a higher β-transition temperature Tβ than composites with other NPs. It was found that PP/SKEPT-4044 composites with Cu2O NPs with a dispersion of 11-15 nm and acrylonitrile butadiene thermoplastics have optimal frost resistance compared to other compositions.

Dynamic Viscosity of Compressed Water to 10 Kilobar and Steam to 1500°C

1969 ◽  
Vol 11 (2) ◽  
pp. 189-205 ◽  
Author(s):  
E. A. Bruges ◽  
M. R. Gibson
Keyword(s):  
Gaseous Phase ◽  
Dynamic Viscosity ◽  
Low Temperatures ◽  
Pressure Range ◽  
Low Pressure ◽  
Temperature Range ◽  
Inversion Temperature ◽  
Pressure Steam ◽  
Correlating Equations ◽  
First Time

Equations specifying the dynamic viscosity of compressed water and steam are presented. In the temperature range 0-100cC the location of the inversion locus (mu) is defined for the first time with some precision. The low pressure steam results are re-correlated and a higher inversion temperature is indicated than that previously accepted. From 100 to 600°C values of viscosity are derived up to 3·5 kilobar and between 600 and 1500°C up to 1 kilobar. All the original observations in the gaseous phase have been corrected to a consistent set of densities and deviation plots for all the new correlations are given. Although the equations give values within the tolerances of the International Skeleton Table it is clear that the range and tolerances of the latter could with some advantage be revised to give twice the existing temperature range and over 10 times the existing pressure range at low temperatures. A list of the observations used and their deviations from the correlating equations is available as a separate publication.

scholarly journals High-Temperature Deformation of Naturally Aged 7010 Aluminum Alloy

Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 581
Author(s):  
Abdulhakim A. Almajid
Keyword(s):  
Activation Energy ◽  
Aluminum Alloy ◽  
High Temperature ◽  
Threshold Stress ◽  
Activation Energies ◽  
Temperature Deformation ◽  
High Temperature Range ◽  
Temperature Range ◽  
True Activation Energy ◽  
Two Temperatures

This study is focused on the deformation mechanism and behavior of naturally aged 7010 aluminum alloy at elevated temperatures. The specimens were naturally aged for 60 days to reach a saturated hardness state. High-temperature tensile tests for the naturally aged sample were conducted at different temperatures of 573, 623, 673, and 723 K at various strain rates ranging from 5 × 10−5 to 10−2 s−1. The dependency of stress on the strain rate showed a stress exponent, n, of ~6.5 for the low two temperatures and ~4.5 for the high two temperatures. The apparent activation energies of 290 and 165 kJ/mol are observed at the low, and high-temperature range, respectively. These values of activation energies are greater than those of solute/solvent self-diffusion. The stress exponents, n, and activation energy observed are rather high and this indicates the presence of threshold stress. This behavior occurred as a result of the dislocation interaction with the second phase particles that are existed in the alloy at the testing temperatures. The threshold stress decreases in an exponential manner as temperature increases. The true activation energy was computed by incorporating the threshold stress in the power-law relation between the stress and the strain. The magnitude of the true activation energy, Qt dropped to 234 and 102 kJ/mol at the low and high-temperature range, respectively. These values are close to that of diffusion of Zinc in Aluminum and diffusion of Magnesium in Aluminum, respectively. The Zener–Hollomon parameter for the alloy was developed as a function of effective stress. The data in each region (low and high-temperature region) coalescence in a segment line in each region.

SELF-TRAPPED EXCITONS IN ORTHORHOMBIC SnBr2

2001 ◽  
Vol 15 (28n30) ◽  
pp. 4009-4012 ◽  
Author(s):  
Y. YAMASAKI ◽  
N. OHNO
Keyword(s):  
Time Dependence ◽  
Low Temperatures ◽  
Luminescence Band ◽  
Radiative Decay ◽  
Time Resolved ◽  
Tunneling Recombination ◽  
Exciton Region ◽  
Time Resolved Photoluminescence ◽  
Stokes Shifts ◽  
2.5 Ev Luminescence

Luminescence properties of SnBr 2 have been studied to reveal the photo-excited exciton relaxation process. Two types of luminescence with large Stokes shifts are found at low temperatures; the 2.2-eV luminescence band produced under the photo-excitation in the first exciton region, and the 2.5-eV luminescence band stimulated by photons with energies above the bandgap. The time-resolved photoluminescence measurements have revealed that the 2.2-eV luminescence comprises fast (1.2 μs) and slow (6.4 μs) exponential decay components, whereas the 2.5-eV luminescence shows the time dependence of I(t)∞ t-0.9. These results suggest that the former band is attributed to the radiative decay of self-trapped excitons, and the latter band would originate from tunneling recombination of holes with the STEL as in the case of lead halides.

Validation of New Mathematical Model of Flank Wear by Different Methods

2012 ◽  
Vol 729 ◽  
pp. 169-174 ◽  
Author(s):  
Zoltán Pálmai ◽  
Márton Takács ◽  
Balázs Zsolt Farkas
Keyword(s):  
Activation Energy ◽  
Mathematical Model ◽  
Flank Wear ◽  
Technological Parameters ◽  
Wear Process ◽  
Oxidation Processes ◽  
Industrial Manufacturing ◽  
Thermally Activated ◽  
Optical Electron ◽  
The Mean

Having reviewed the literature on cutting and based on the optical, electron-optical and morphological examinations of wear processes we have reached the conclusion that it is possible to describe the abrasive, adhesive and thermally activated diffusion, oxidation processes in a single mathematical model. The model is a non-linear autonomous differential equation, which can be solved by simple numerical methods. The complex wear equation was validated by the results of the cutting tests performed with P20 carbide on C45 carbon steel. If we have this data, we can calculate the activation energy of the process determining the nature of the wear process. The apparent activation energy of wear is Q=151,7kJ/mol. The model can even be used with changing technological parameters, and the data necessary for the constants of the wear equation may as well be determined even by measurements performed on the tool during industrial manufacturing. By the mean of this data, we can calculate the activation energy determining the nature of the wear process.

Lumped Parameter Modeling of a Magnetorheological Fluid Clutch

2006 ◽  
Author(s):  
John C. Ulicny ◽  
Daniel J. Klingenberg ◽  
Anthony L. Smith ◽  
Zongxuan Sun
Keyword(s):  
Mathematical Model ◽  
Physical Properties ◽  
Magnetorheological Fluid ◽  
Input Current ◽  
Fluid Composition ◽  
Fluid Temperature ◽  
Temperature Range ◽  
Lumped Parameter ◽  
Lumped Parameter Modeling ◽  
Fan Speed

A lumped-parameter mathematical model of an automotive magnetorheological (MR) fluid fan clutch was developed. This model is able to describe the average fluid temperature, average clutch temperature, and output fan speed as a function of time, input current, and fluid composition. The model also reproduces numerous features of fan operation observed experimentally and revealed a mechanism for some observed cases of hysteresis. However, it fails to capture certain other features which lead us to conclude that phenomena which are not included in the model, e.g., sedimentation and re-suspension, are important to the clutch behavior. In addition, the results indicate that certain physical properties need to be measured over a larger temperature range in order for the model to better predict the clutch behavior.

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