Storage of Fuel in Hydrates for Natural Gas Vehicles (NGVs)

1996 ◽  
Vol 118 (3) ◽  
pp. 209-213 ◽  
Author(s):  
G. Y. Yevi ◽  
R. E. Rogers

The need for alternative fuels to replace liquid petroleum-based fuels has been accelerated in recent years by environmental concerns, concerns of shortage of imported liquid hydrocarbon, and congressional prompting. The fact is accepted that natural gas is the cheapest, most domestically abundant, and cleanest burning of fossil fuels. However, socio-economical and technical handicaps associated with the safety and efficiency of on-board fuel storage inhibit its practical use in vehicles as an alternative fuel. A concept is presented for safely storing fuel at low pressures in the form of hydrates in natural gas vehicles. Experimental results lead to gas storage capacities of 143 to 159 volumes/volume. Vehicle travel range could be up to 204 mi. Controlled decomposition rate of hydrates is possible for feeding an automotive vehicle. Upon sudden pressure decrease in the event of a vehicle accident, the rate of release of hydrocarbons from the hydrates at constant temperature is 2.63 to 12.50 percent per min, slow enough to prevent an explosion or a fireball. A model is given for predicting the rates of gas release from hydrates in a vehicle wreck. A storage tank design is proposed and a process is suggested for forming and decomposing hydrates on-board vehicles. A consistent fuel composition is obtained with hydrates.

Molecules ◽  
2020 ◽  
Vol 25 (4) ◽  
pp. 802 ◽  
Author(s):  
Manuel Antonio Díaz-Pérez ◽  
Juan Carlos Serrano-Ruiz

Concerns about depleting fossil fuels and global warming effects are pushing our society to search for new renewable sources of energy with the potential to substitute coal, natural gas, and petroleum. In this sense, biomass, the only renewable source of carbon available on Earth, is the perfect replacement for petroleum in producing renewable fuels. The aviation sector is responsible for a significant fraction of greenhouse gas emissions, and two billion barrels of petroleum are being consumed annually to produce the jet fuels required to transport people and goods around the world. Governments are pushing directives to replace fossil fuel-derived jet fuels with those derived from biomass. The present mini review is aimed to summarize the main technologies available today for converting biomass into liquid hydrocarbon fuels with a molecular weight and structure suitable for being used as aviation fuels. Particular emphasis will be placed on those routes involving heterogeneous catalysts.


Energies ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 8502
Author(s):  
Li Chin Law ◽  
Beatrice Foscoli ◽  
Epaminondas Mastorakos ◽  
Stephen Evans

Decarbonization of the shipping sector is inevitable and can be made by transitioning into low- or zero-carbon marine fuels. This paper reviews 22 potential pathways, including conventional Heavy Fuel Oil (HFO) marine fuel as a reference case, “blue” alternative fuel produced from natural gas, and “green” fuels produced from biomass and solar energy. Carbon capture technology (CCS) is installed for fossil fuels (HFO and liquefied natural gas (LNG)). The pathways are compared in terms of quantifiable parameters including (i) fuel mass, (ii) fuel volume, (iii) life cycle (Well-To-Wake—WTW) energy intensity, (iv) WTW cost, (v) WTW greenhouse gas (GHG) emission, and (vi) non-GHG emissions, estimated from the literature and ASPEN HYSYS modelling. From an energy perspective, renewable electricity with battery technology is the most efficient route, albeit still impractical for long-distance shipping due to the low energy density of today’s batteries. The next best is fossil fuels with CCS (assuming 90% removal efficiency), which also happens to be the lowest cost solution, although the long-term storage and utilization of CO2 are still unresolved. Biofuels offer a good compromise in terms of cost, availability, and technology readiness level (TRL); however, the non-GHG emissions are not eliminated. Hydrogen and ammonia are among the worst in terms of overall energy and cost needed and may also need NOx clean-up measures. Methanol from LNG needs CCS for decarbonization, while methanol from biomass does not, and also seems to be a good candidate in terms of energy, financial cost, and TRL. The present analysis consistently compares the various options and is useful for stakeholders involved in shipping decarbonization.


1991 ◽  
Vol 113 (2) ◽  
pp. 101-107 ◽  
Author(s):  
P. Gandhidasan ◽  
A. Ertas ◽  
E. E. Anderson

Concern over the environment and a potential oil shortage has resulted in an intensified research for alternative fuels for the transportation sector. Two fuels given strong consideration are methanol and compressed natural gas (CNG). This paper is a comprehensive comparative study of methanol and CNG as transportation fuels. The physical properties of methanol and CNG are discussed. The various concerns, such as source and potential fuel supply, safety, toxicity and health hazards, engine performance and emissions, fuel storage, fuel tank and refueling of these alternative fuels are addressed briefly in this paper. We find that no single alternative fuel is best in all categories. The merits and drawbacks of each fuel are tabulated and the vehicle characteristics are compared with gasoline. The study concludes that the neat methanol may be considered as an alternative for passenger cars and CNG may be considered for fleets, light and heavy-duty vehicles as the best near-term solution.


Energies ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 127
Author(s):  
Kim Youngok ◽  
Yi Eunkyung ◽  
Son Hyunik

Leading countries are developing clean energy to replace fossil fuels. In this context, Russia is changing its energy policy towards fostering new energy resources, such as hydrogen and helium. Hydrogen will not only contribute to Russia’s financial revenue by replacing natural gas, but will also provide a basis for it to maintain its dominance over the international energy market by pioneering new energy markets. Russia is aiming to produce more than two million tons of hydrogen fuel for export to Europe and Asia by 2035. However, it is facing many challenges, including developing hydrogen fuel storage systems, acquiring the technology required for exporting hydrogen, and building trust in the fuel market. Meanwhile, South Korea has a foundation for developing a hydrogen industry, as it has the highest capacity in the world to produce fuel cells and the ability to manufacture LNG: (liquefied natural gas) carriers. Therefore, South Korea and Russia have sufficient potential to create a new complementary and reciprocal cooperation model in the hydrogen fuel field. This study examines the present and future of Russia’s energy policy in this area as well as discusses South Korea and Russia’s cooperation plans in the hydrogen fuel sector and the related implications.


2021 ◽  
Vol 13 (18) ◽  
pp. 10059
Author(s):  
Sai Manoj Rayapureddy ◽  
Jonas Matijošius ◽  
Alfredas Rimkus

Depletion in the levels of fossil fuels and increasing environmental concerns associated with the rise in consumption of conventional fuels are among the top global concerns. Finding an alternative sustainable fuel that matches the performance characteristics of diesel/petrol fuels as well as decreases the exhaust emissions has been a challenging task. After deliberate research, it is found that every alternative fuel is associated with different problems when they are used independently, thereby limiting its benefits. Scientists suggest that using different fuel blends might lead to sustainability. This article is the analysis of data obtained from the experimentation based on two different alternative fuels, Rapeseed Methyl Ester (RME)-based biodiesel and Rapeseed Oil (RO), blended with diesel (D) and Isopropanol (P) into three different proportions each. Tests were carried out in a compression ignition (CI) engine, and comparisons are based on the resulted performance and exhaust emission characteristics. The two different alternative fuels are blended into the following proportions to make six fuel mixtures, D50RME30P20, D50RME40P10, D50RME45P5, D50RO30P20, D50RO40P10 and D50RO45P5. The tests are carried out at different loads (BMEP) and are compared to that of pure diesel. Using the experimentation results, we also obtained the combustion characteristics of all fuel mixtures for further evaluation


Author(s):  
Gerardo Diaz

Alternative fuels, mainly generated from waste, constitute a possible option to reduce the demand for fossil fuels. For instance, biogas can be obtained from cow manure using anaerobic digesters, a technology that is currently being implemented in several dairy farms. Synthesis gas, also known as syngas, is a mixture of hydrogen and carbon monoxide that may have fractions of other components such as nitrogen, carbon dioxide, and methane, depending on the gasifying method used. However, before a change to alternative fuels can be made, the performance of common appliances and industrial equipment using these fuels needs to be investigated. In this paper, a computational analysis of the performance of an air heater using natural gas, biogas, and syngas is performed. The results show that alternative fuels with heat values almost an order of magnitude lower than natural gas can be used in commercial air heaters with only minor variations in thermal performance. The main drawback is the higher flow rates required for alternative fuels, specially for syngas.


2020 ◽  
Vol 4 (1) ◽  
pp. 1-7
Author(s):  
Made Dirgantara ◽  
Karelius Karelius ◽  
Marselin Devi Ariyanti, Sry Ayu K. Tamba

Abstrak – Biomassa merupakan salah satu energi terbarukan yang sangat mudah ditemui, ramah lingkungan dan cukup ekonomis. Keberadaan biomassa dapat dimaanfaatkan sebagai pengganti bahan bakar fosil, baik itu minyak bumi, gas alam maupun batu bara. Analisi diperlukan sebagai dasar biomassa sebagai energi seperti proksimat dan kalor. Analisis terpenting untuk menilai biomassa sebagai bahan bakar adalah nilai kalori atau higher heating value (HHV). HHV secara eksperimen diukur menggunakan bomb calorimeter, namun pengukuran ini kurang efektif, karena memerlukan waktu serta biaya yang tinggi. Penelitian mengenai prediksi HHV berdasarkan analisis proksimat telah dilakukan sehingga dapat mempermudah dan menghemat biaya yang diperlukan peneliti. Dalam makalah ini dibahas evaluasi persamaan untuk memprediksi HHV berdasarkan analisis proksimat pada biomassa berdasarkan data dari penelitian sebelumnya. Prediksi nilai HHV menggunakan lima persamaan yang dievaluasi dengan 25 data proksimat biomassa dari penelitian sebelumnya, kemudian dibandingkan berdasarkan nilai error untuk mendapatkan prediksi terbaik. Hasil analisis menunjukan, persamaan A terbaik di 7 biomassa, B di 6 biomassa, C di 6 biomassa, D di 5 biomassa dan E di 1 biomassa.Kata kunci: bahan bakar, biomassa, higher heating value, nilai error, proksimat  Abstract – Biomass is a renewable energy that is very easy to find, environmentally friendly, and quite economical. The existence of biomass can be used as a substitute for fossil fuels, both oil, natural gas, and coal. Analyzes are needed as a basis for biomass as energy such as proximate and heat. The most critical analysis to assess biomass as fuel is the calorific value or higher heating value (HHV). HHV is experimentally measured using a bomb calorimeter, but this measurement is less effective because it requires time and high costs. Research on the prediction of HHV based on proximate analysis has been carried out so that it can simplify and save costs needed by researchers. In this paper, the evaluation of equations is discussed to predict HHV based on proximate analysis on biomass-based on data from previous studies. HHV prediction values using five equations were evaluated with 25 proximate biomass data from previous studies, then compared based on error value to get the best predictions. The analysis shows that Equation A predicts best in 7 biomass, B in 6 biomass, C in 6 biomass, D in 5 biomass, and E in 1 biomass. Key words: fuel, biomass, higher heating value, error value, proximate 


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