Effect of Hydrophobic Iron Oxide Nanoparticles on the Properties of Oil-Based Drilling Fluid

2020 ◽  
Vol 143 (4) ◽  
Author(s):  
Muhammad Awais Ashfaq Alvi ◽  
Mesfin Belayneh ◽  
Kjell Kåre Fjelde ◽  
Arild Saasen ◽  
Sulalit Bandyopadhyay
Keyword(s):  
High Temperature ◽  
Iron Oxide ◽  
Base Fluid ◽  
Drilling Fluid ◽  
Iron Pentacarbonyl ◽  
Inert Atmosphere ◽  
Drilling Fluids ◽  
Oil Well ◽  
The Coefficient Of Friction ◽  
Filtrate Loss

Abstract Lately, nanoparticles (NPs) have shown the potential to improve the performance of oil well fluids significantly. Several studies have reported the ability of NPs to produce improved properties of both water and oil-based drilling fluids. In this study, hydrophobic iron oxide NPs were synthesized by thermal decomposition of iron pentacarbonyl in an inert atmosphere, and its performance was tested in the oil-based drilling fluid with 90/10 oil-to-water ratio (base fluid). Oil-based drilling fluids treated with nanofluids were formulated by adding 0.5 wt% and 1.0 wt% iron oxide NPs in hexane solution to the base drilling fluid. The base fluid and the nanofluid-treated drilling fluids were evaluated by characterizing their rheological properties at different temperatures, viscoelastic properties, lubricity, filtrate loss, static and dynamic settling, and separation properties. Results showed that 0.5 wt% iron oxide dispersed in hexane reduced the high pressure high temperature (HPHT) filtrate loss by 70%, filter cake thickness by 55%, and the coefficient of friction by 39%. Moreover, the nanofluid based drilling fluid reduced the free oil layer caused by syneresis during aging at high temperature by 16.3% compared to the base fluid. This study has shown that hydrophobic iron oxide NPs have the potential to improve the properties of oil-based drilling fluid.

Effect of Hydrophobic Iron Oxide Nanoparticles on the Properties of Oil Based Drilling Fluid

2020 ◽  
Author(s):  
Muhammad Awais Ashfaq Alvi ◽  
Mesfin Belayneh ◽  
Kjell Kåre Fjelde ◽  
Arild Saasen ◽  
Sulalit Bandyopadhyay
Keyword(s):  
Iron Oxide ◽  
Base Fluid ◽  
Drilling Fluid ◽  
Iron Pentacarbonyl ◽  
Inert Atmosphere ◽  
Drilling Fluids ◽  
Oil Well ◽  
Different Temperatures ◽  
The Coefficient Of Friction ◽  
Filtrate Loss

Abstract In recent years, nanoparticles (NPs) have shown the potential to improve the performance of oil well fluids significantly. Several studies have reported the ability of NPs to produce improved properties of both water and oil-based drilling fluids. In this paper, hydrophobic iron oxide NPs were synthesized by thermal decomposition of iron pentacarbonyl in an inert atmosphere, and its performance was tested in the oil-based drilling fluid with 90/10 oil to water ratio (base fluid). Oil-based drilling fluids treated with nanofluids were formulated by adding 0.5 wt. % and 1.0 wt. % iron oxide NPs in hexane solution to the base drilling fluid. The base fluid and the nanofluid treated drilling fluids were evaluated by characterizing their rheological properties at different temperatures, viscoelastic properties, lubricity, filtrate loss, static & dynamic settling, and separation properties. Results showed that 0.5 wt. % iron oxide dispersed in hexane reduced the HPHT filtrate loss by 70%, filter cake thickness by 55%, and the coefficient of friction by 39%. Moreover, the nanofluid based drilling fluid reduced the free oil layer caused by syneresis during aging at high temperature by 16.3% compared to the base fluid. This study has shown that hydrophobic iron oxide NPs have the potential to improve the properties of oil-based drilling fluid.

scholarly journals Effect of Iron Oxide Nanoparticles on the Properties of Water-Based Drilling Fluids

Energies ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 6718
Author(s):  
Muhammad Awais Ashfaq Alvi ◽  
Mesfin Belayneh ◽  
Sulalit Bandyopadhyay ◽  
Mona Wetrhus Minde
Keyword(s):  
Iron Oxide ◽  
Coefficient Of Friction ◽  
Drilling Fluid ◽  
Precipitation Method ◽  
Fluid Loss ◽  
Drilling Fluids ◽  
The Coefficient Of Friction ◽  
Filtrate Loss ◽  
Co Precipitation ◽  
The Impact

In recent years, several studies have indicated the impact of nanoparticles (NPs) on various properties (such as viscosity and fluid loss) of conventional drilling fluids. Our previous study with commercial iron oxide NPs indicated the potential of using NPs to improve the properties of a laboratory bentonite-based drilling fluid without barite. In the present work, iron oxide NPs have been synthesized using the co-precipitation method. The effect of these hydrophilic NPs has been evaluated in bentonite and KCl-based drilling fluids. Rheological properties at different temperatures, viscoelastic properties, lubricity, and filtrate loss were measured to study the effect of NPs on the base fluid. Also, elemental analysis of the filtrate and microscale analysis of the filter cake was performed. Results for bentonite-based fluid showed that 0.019 wt% (0.1 g) of NPs reduced the coefficient of friction by 47%, and 0.0095 wt% (0.05 g) of NPs reduced the fluid loss by 20%. Moreover, for KCl-based fluids, 0.019 wt% (0.1 g) of additive reduced the coefficient of friction by 45%, while higher concentration of 0.038 wt% (0.2 g) of NPs shows 14% reduction in the filtrate loss. Microscale analysis shows that presence of NPs in the cake structure produces a more compact and less porous structure. This study indicates that very small concentration of NPs can provide better performance for the drilling fluids. Additionally, results from this work indicate the ability of NPs to fine-tune the properties of drilling fluids.

Can Titanium and Copper Oxide Commercial Nanoparticles Be Used for HP/HT Applications? A Comparison With the Very Well Performing Fe3O4 NP

2018 ◽  
Author(s):  
Zisis Vryzas ◽  
Vassilios C. Kelessidis ◽  
Lori Nalbandian ◽  
Vassilios Zaspalis
Keyword(s):  
Iron Oxide ◽  
Copper Oxide ◽  
Rheological Properties ◽  
Yield Stress ◽  
Base Fluid ◽  
Drilling Fluid ◽  
Filter Press ◽  
Fluid Loss ◽  
Drilling Fluids ◽  
Custom Made

Smart drilling fluids, which can change their properties according to the flow environment, must be carefully designed so that they can handle the difficult challenges of HP/HT drilling successfully. Due to their unique physico-chemical properties, nanoparticles (NP) are considered as very good candidates for the formulation of these smart drilling fluids. This study presents filtration and rheological results of newly developed high-performance water-based drilling fluid systems containing different nanoparticles, commercial (C) titanium oxide (TiO2) and commercial (C) copper oxide (CuO) NP and compares them with results from using custom-made (CM) iron oxide (Fe3O4) NP and commercial (C) iron oxide (Fe3O4) NP, previously reported. Novel nano-based drilling fluids were made of de-ionized water, 7 wt% commercial Na-bentonite (base fluid), and NP were added at 0.5 wt%. The rheological properties of the produced suspensions were measured at temperatures up to 60°C and at atmospheric pressure with a Couette-type viscometer. Filtration characteristics were determined at elevated pressures and temperatures in a HP/HT filter press (500 psi/176°C) using ceramic discs as filter media, of permeability, k = 775 mD. The results of this study showed that the samples containing 0.5 wt% C TiO2 caused a reduction in the fluid loss by 23%, while C CuO NP resulted in 16% reduction, when compared to that of the base fluid, at these HPHT conditions. This should be compared to the 47% and 34% reduction in fluid loss of 0.5% CM Fe3O4 NP and of 0.5% of C Fe3O4 NP, reported previously. Analysis of rheological data revealed shear-thinning behavior for all the tested novel drilling fluids. The samples containing TiO2 and CuO NP exhibited a yield stress less than that of the base fluid, compared to the increased yield stress observed for the C and CM Fe3O4 NP. This behavior can be attributed to the fact that TiO2 and CuO NP may also act as deflocculants and prevent the gelation of bentonite suspensions. This study shows that commercial nanoparticles of TiO2 and CuO do not perform as well as the Fe3O4 NP on filtration but provide drilling fluids with lower yield stresses, thus they could be considered as alternatives to Fe3O4 in situations where the rheological properties are critical.

scholarly journals The application of MWCNT to enhance the rheological behavior of drilling fluids at high temperature

2017 ◽  
Vol 12 (3) ◽  
Author(s):  
Abdul Razak Ismail ◽  
W. R. W Sulaiman ◽  
M. Z. Jaafar ◽  
A. Aftab ◽  
A. A. Razi ◽  
...  
Keyword(s):  
High Temperature ◽  
Rheological Properties ◽  
Rheological Behavior ◽  
Oil And Gas ◽  
Drilling Fluid ◽  
Gel Strength ◽  
Drilling Fluids ◽  
Deep Wells ◽  
Multi Walled Carbon Nanotube ◽  
Filtrate Loss

Drilling fluid is the key component to drill oil and gas wells. The rheological behavior of drilling fluid will be affected when drilling deep wells especially at high temperature and high pressure reservoir. This research was conducted to study the effect of the nanoparticles over the rheological properties of the drilling fluid when aging at high temperature condition. Several drilling fluids were prepared using synthetic based fluids (Sarapar and Saraline) to study the effect of multi-walled carbon nanotube (MWCNT) at different concentrations. The rheological properties of drilling fluid were analyzed after aging at 250 °F and 350 °F for 16 hours. The results revealed that the addition of MWCNT improved the 10-sec gel strength by 33% and filtrate loss volume was reduced to 10% after aging at 250°F in Saraline drilling fluid. Moreover, the plastic viscosity of Saraline and Sarapar drilling fluid after addition of MWCNT was enhanced by 6% and 27% at 350 °F. Filtrate loss volume of Sarapar drilling fluid was reduced by 19 % after aging at 250 °F for 16 hours. The overall results showed that the addition of MWCNT into the drilling fluid have slightly improved the rheological properties of drilling fluids under high temperature conditions.

Effect of MWCNT and MWCNT Functionalized -OH and -COOH Nanoparticles in Laboratory Water Based Drilling Fluid

2018 ◽  
Author(s):  
Muhammad Awais Ashfaq Alvi ◽  
Mesfin Belayneh ◽  
Arild Saasen ◽  
Kjell Kåre Fjelde ◽  
Bernt S. Aadnøy
Keyword(s):  
Oil Recovery ◽  
Xanthan Gum ◽  
Oil And Gas ◽  
Drilling Fluid ◽  
Oil And Gas Industry ◽  
Drilling Fluids ◽  
Gas Industry ◽  
Multi Walled Carbon Nanotube ◽  
The Coefficient Of Friction ◽  
Filtrate Loss

In recent years, the application of nanomaterial has been attracting the oil and gas industry. Nanomaterials research results show an improving performance of cement, drilling fluid and enhanced oil recovery. In this paper, the effect of multi-walled carbon nanotube (MWCNT) and MWCNT functionalized with ligands–OH and - COOH nanoparticles on laboratory drilling fluids formulated from bentonite, KCL, Carboxymethyl cellulose (CMC) and xanthan gum (XG) was studied. The formulations and tests were performed at room temperature. The results show that addition of 0.0095wt.% of MWCNT, MWCNT-OH and MWCNT-COOH nanoparticles in CMC/bentonite system decreases the filtrate-loss by 8.6 %, 7.1 % and 17.9 % respectively. These particles also decreased the coefficient of friction by 34 %, 37 % and 33 % respectively. In xanthan gum drilling fluid, 0.019wt%. MWCNT reduced the friction coefficient by 38 %.

scholarly journals MoS2 Nanoparticle Effects on 80 °C Thermally Stable Water-Based Drilling Fluid

Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7195
Author(s):  
Mesfin Belayneh ◽  
Bernt Aadnøy ◽  
Simen Moe Strømø
Keyword(s):  
High Temperature ◽  
Base Fluid ◽  
Drilling Fluid ◽  
Drilling Fluids ◽  
Thermally Stable ◽  
Bingham Plastic ◽  
Plastic Yield ◽  
Temperature And Pressure ◽  
Operational Issues ◽  
The Impact

Bentonite-based drilling fluids are used for drilling, where inhibitive fluids are not required. The rheological and the density properties of the drilling fluids are highly affected by high temperature and pressure. Due to high temperature, the clay particles stick together, and the fluid system becomes more flocculated. Poorly designed drilling fluid may cause undesired operational issues such as poor hole cleaning, drill strings sticking, high torque and drag. In this study, the 80 °C thermally stable Herschel Bulkley’s and Bingham plastic yield stresses drilling fluids were formulated based on lignosulfonate-treated bentonite drilling fluid. Further, the impact of a MoS2 nanoparticle solution on the properties of the thermally stable base fluid was characterized. Results at room temperature and pressure showed that the blending of 0.26 wt.% MoS2 increased the lubricity of thermally stable base fluid by 27% and enhanced the thermal and electrical conductivities by 7.2% and 8.8%, respectively.

scholarly journals Experimental Investigation of the Rheological Behavior of an Oil-Based Drilling Fluid with Rheology Modifier and Oil Wetter Additives

Molecules ◽  
2021 ◽  
Vol 26 (16) ◽  
pp. 4877
Author(s):  
Mobeen Murtaza ◽  
Sulaiman A. Alarifi ◽  
Muhammad Shahzad Kamal ◽  
Sagheer A. Onaizi ◽  
Mohammed Al-Ajmi ◽  
...  
Keyword(s):  
High Temperature ◽  
Zeta Potential ◽  
Hot Rolling ◽  
Emulsion Stability ◽  
Drilling Fluid ◽  
Temperature Tolerance ◽  
Fluid Loss ◽  
Drilling Fluids ◽  
Before And After ◽  
Rheology Modifier

Drilling issues such as shale hydration, high-temperature tolerance, torque and drag are often resolved by applying an appropriate drilling fluid formulation. Oil-based drilling fluid (OBDF) formulations are usually composed of emulsifiers, lime, brine, viscosifier, fluid loss controller and weighting agent. These additives sometimes outperform in extended exposure to high pressure high temperature (HPHT) conditions encountered in deep wells, resulting in weighting material segregation, high fluid loss, poor rheology and poor emulsion stability. In this study, two additives, oil wetter and rheology modifier were incorporated into the OBDF and their performance was investigated by conducting rheology, fluid loss, zeta potential and emulsion stability tests before and after hot rolling at 16 h and 32 h. Extending the hot rolling period beyond what is commonly used in this type of experiment is necessary to ensure the fluid’s stability. It was found that HPHT hot rolling affected the properties of drilling fluids by decreasing the rheology parameters and emulsion stability with the increase in the hot rolling time to 32 h. Also, the fluid loss additive’s performance degraded as rolling temperature and time increased. Adding oil wetter and rheology modifier additives resulted in a slight loss of rheological profile after 32 h and maintained flat rheology profile. The emulsion stability was slightly decreased and stayed close to the recommended value (400 V). The fluid loss was controlled by optimizing the concentration of fluid loss additive and oil wetter. The presence of oil wetter improved the carrying capacity of drilling fluids and prevented the barite sag problem. The zeta potential test confirmed that the oil wetter converted the surface of barite from water to oil and improved its dispersion in the oil.

Improving the rheological properties of water-based calcium bentonite drilling fluids using water-soluble polymers in high temperature applications

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Jinliang Liu ◽  
Fengshan Zhou ◽  
Fengyi Deng ◽  
Hongxing Zhao ◽  
Zhongjin Wei ◽  
...  
Keyword(s):  
High Temperature ◽  
Rheological Properties ◽  
Apparent Viscosity ◽  
Drilling Fluid ◽  
Shear Thickening ◽  
Water Soluble ◽  
Drilling Fluids ◽  
Drilling Depth ◽  
Filtration Loss ◽  
Calcium Bentonite

Abstract Most of bentonite used in modern drilling engineering is physically and chemically modified calcium bentonite. However, with the increase of drilling depth, the bottom hole temperature may reach 180 °C, thus a large amount of calcium bentonite used in the drilling fluid will be unstable. This paper covers three kinds of calcium bentonite with poor rheological properties at high temperature, such as apparent viscosity is greater than 45 mPa·s or less than 10 mPa·s, API filtration loss is greater than 25 mL/30 min, which are diluted type, shear thickening type and low-shear type, these defects will make the rheological properties of drilling fluid worse. The difference is attributed to bentonite mineral composition, such as montmorillonite with good hydration expansion performance. By adding three kinds of heat-resistant water-soluble copolymers Na-HPAN (hydrolyzed polyacrylonitrile sodium), PAS (polycarboxylate salt) and SMP (sulfomethyl phenolic resin), the rheological properties of calcium bentonite drilling fluids can be significantly improved. For example, the addition of 0.1 wt% Na-HPAN and 0.1 wt% PAS increased the apparent viscosity of the XZJ calcium bentonite suspension from 4.5 to 19.5 mPa·s at 180 °C, and the filtration loss also decreased from 20.2 to 17.8 mL.

Well Clean-Up Using a Combined Thermochemical/Chelating Agent Fluids

2019 ◽  
Vol 141 (10) ◽  
Author(s):  
Mohamed Mahmoud
Keyword(s):  
High Temperature ◽  
Filter Cake ◽  
Oil And Gas ◽  
Drilling Fluid ◽  
Chelating Agent ◽  
Drilling Fluids ◽  
Gas Wells ◽  
Oil And Gas Wells ◽  
Different Types ◽  
Cake Removal

The well clean-up process involves the removal of impermeable filter cake from the formation face. This process is essential to allow the formation fluids to flow from the reservoir to the wellbore. Different types of drilling fluids such as oil- and water-based drilling fluids are used to drill oil and gas wells. These drilling fluids are weighted with different weighting materials such as bentonite, calcium carbonate, and barite. The filter cake that forms on the formation face consists mainly of the drilling fluid weighting materials (around 90%), and the rest is other additives such as polymers or oil in the case of oil-base drilling fluids. The process of filter cake removal is very complicated because it involves more than one stage due to the compatibility issues of the fluids used to remove the filter cake. Different formulations were used to remove different types of filter cake, but the problem with these methods is the removal efficiency or the compatibility. In this paper, a new method was developed to remove different types of filter cakes and to clean-up oil and gas wells after drilling operations. Thermochemical fluids that consist of two inert salts when mixed together will generate very high pressure and high temperature in addition to hot water and hot nitrogen. These fluids are sodium nitrate and ammonium chloride. The filter cake was formed using barite and calcite water- and oil-based drilling fluids at high pressure and high temperature. The removal process started by injecting 500 ml of the two salts and left for different time periods from 6 to 24 h. The results of this study showed that the newly developed method of thermochemical removed the filter cake after 6 h with a removal efficiency of 89 wt% for the barite filter cake in the water-based drilling fluid. The mechanisms of removal using the combined solution of thermochemical fluid and ethylenediamine tetra-acetic acid (EDTA) chelating agent were explained by the generation of a strong pressure pulse that disturbed the filter cake and the generation of the high temperature that enhanced the barite dissolution and polymer degradation. This solution for filter cake removal works for reservoir temperatures greater than 100 °C.

scholarly journals Study on the stability of a shear-thinning suspension used in oil well drilling

2018 ◽  
Vol 73 ◽  
pp. 10 ◽  
Author(s):  
Flávia M. Fagundes ◽  
Nara B.C. Santos ◽  
João Jorge R. Damasceno ◽  
Fábio O. Arouca
Keyword(s):  
Gamma Ray ◽  
Drilling Fluid ◽  
Shear Thinning ◽  
Drilling Fluids ◽  
Oil Well ◽  
Drilling Process ◽  
Well Drilling ◽  
Constant Rate ◽  
The Stability ◽  
Solid Liquid

In order to avoid solid-liquid gravitational separation of particles in the drilling fluid and cuttings generated in this process, the oil industry has been developing drilling fluids with shear-thinning and thixotropic characteristics. In case of operational stops in the drilling process, the intense sedimentation of these particles can damage the equipment used and the well. In this context, this study simulated an operational stop to obtain information about stability of solids in a paraffin-based suspension with time-dependent shear-thinning behavior, which has already been used in current drilling processes. A long-term test using gamma-ray attenuation technique identified the separation dynamics of a set of micrometric particles belonging to and incorporated into the drilling fluid during operation. This test verified the typical regions of gravitational sedimentation and, through constant concentration curves, indicated that the sedimentation process did not occur at a constant rate. This study also proposed a constitutive equation for pressure on solids.

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