scholarly journals On the Structure of Turbulent Combusting Unconfined Sprays

Author(s):  
S. K. Aggarwal ◽  
S. Chitre

Computations are reported on the detailed structures of unconfined turbulent combusting sprays. Favre-averaged gas-phase equations are used and a k-ε-g turbulence closure model is utilized. Using a conserved scalar approach and assuming the form of probability density function to be a clipped Gaussian, the thermodynamic scalar variables are calculated from a partial equilibrium model. The major features of the liquid-phase model are that a stochastic random-walk approach is used to represent the effect of gas-phase turbulence on droplet trajectory and vaporization, the variable-property effects are considered in a comprehensive manner, and a conduction-limit mode is employed to represent the transient liquid-phase processes. This two-phase model is used to study the structure of an unconfined methanol spray flame. Important observation is that the turbulent spray flame structure is significantly different, both quantitatively and qualitatively, from that of the corresponding gaseous diffusion flame. In addition, the spray flame exhibits a strong sensitively to the transient liquid-phase processes. The latter result is interesting since, in an earlier computational study for an evaporating spray, the vaporization behavior for the same liquid fuel indicated only a weak sensitivity to these processes.

Author(s):  
Zhichao Guo ◽  
Zhaoci Li

Abstract In 2018, China’s natural gas import reached 90.39 million tons, and the liquefied natural gas (LNG) import was 53.78 million tons, accounting for 59.5% of total natural gas imports. With the construction of LNG terminals, more studies on the leakage of LNG storage and transportation facilities have emerged to prevent catastrophic consequences such as explosions and frostbite. However, most of previous researches focused on gas pipeline leakage after LNG gasification, and few of those have been done on LNG liquid pipeline leakage. In this paper, Fluent software is used to numerically simulate the process of LNG liquid pipeline leakage. After the occurrence of LNG leakage, it will suffer the process of endothermic, evaporation, and diffusion, which is considered as a two-phase diffusion process. The Euler-Lagrangian method is introduced to simulate the diffusion process of gas phase and liquid phase separately. In the simulation, the liquid phase is regarded as discrete droplets for discrete processing. The movement trajectory, heat transfer process and evaporation process of each droplet are tracked respectively. Different from the liquid phase, the gas phase is regarded as a continuous phase and the Navier-Stokes equations are adopted for calculation. Thereafter, coupling calculations of two phase are performed to determine the concentration field and temperature field of the LNG liquid pipeline leakage. As a supplement to this research, the influence of wind speed on LNG leakage and diffusion process is analysed in detail. Finally, the numerical simulation method is applied to a coastal LNG terminal in northern China to determine the distribution of natural gas concentration and temperature, as well as delimit the combustion range. The results can provide scientific reference for the delimitation of risky zones and the formulation of emergency response strategy.


Author(s):  
Sergey A. Zanochuev ◽  
Alexander B. Shabarov

Within the objectives of predicting the composition and properties of the produced fluid during the development of oil and gas condensate fields, this article proposes an experimental method for predicting the composition and properties of the produced fluid. In addition, the authors show its practical use in a situation where the liquid phase (precipitated condensate or oil) is filtered together with the gas phase. Based on the proposed approach, experimental data were obtained on changes in the current gas saturation of the formation, as well as on changes in the composition and properties of the produced fluid during field development for depletion. The studies make use of the real reservoir fluid samples and the data from the results of stream experiments, in order to determine the relative phase permeabilities.


2013 ◽  
Vol 19 (1) ◽  
pp. 13-24 ◽  
Author(s):  
Ahmad Shamiria ◽  
M.A. Hussaina ◽  
Farouq Mjallic ◽  
Navid Mostoufid

A comparative study describing gas-phase propylene polymerization in fluidized-bed reactors using Ziegler-Natta catalyst is presented. The reactor behavior was explained using a two-phase model (which is based on principles of fluidization) as well as simulation using the Aspen Polymers process simulator. The two-phase reactor model accounts for the emulsion and bubble phases which contain different portions of catalysts with the polymerization occurring in both phases. Both models predict production rate, molecular weight, polydispersity index (PDI) and melt flow index (MFI) of the polymer. We used both models to investigate the effect of important polymerization parameters, namely catalyst feed rate and hydrogen concentration, on the product polypropylene properties, such as production rate, molecular weight, PDI and MFI. Both the two-phase model and Aspen Polymers simulator showed good agreement in terms of production rate. However, the models differed in their predictions for weight-average molecular weight, PDI and MFI. Based on these results, we propose incorporating the missing hydrodynamic effects into Aspen Polymers to provide a more realistic understanding of the phenomena encountered in fluidized bed reactors for polyolefin production.


2001 ◽  
Vol 4 (04) ◽  
pp. 289-296
Author(s):  
Holger F. Thern ◽  
Songhua Chen

Summary Accurate estimates of porosity, fluid saturations, and in-situ gas properties are critical for the evaluation of a gas reservoir. By combining data from a dual wait-time (DTW) nuclear magnetic resonance (NMR) log and a density log, these properties can be determined more reliably than by either of the data alone. The density and NMR dual wait-time (DDTW) technique, introduced in this paper, is applicable to reservoirs where the pore-filling fluid consists of a liquid phase and a gas phase. The low proton density of the gas phase causes a reduction in the NMR signal strength resulting in underestimation of the apparent porosity. The polarization for different wait-times depends on the spin-lattice relaxation time of each fluid and may cause additional NMR porosity underestimation. The density log, on the other hand, delivers a porosity that is overestimated because of the presence of a gas phase. These data, together with known correlations for gas properties, yield a robust approach for the gas-zone porosity, f, and the flushed zone gas saturation, Sg, xo. DDTW also derives gas properties including the in-situ gas density, ?g, as well as the two NMR-related properties, hydrogen index, IH, g, and spin-lattice relaxation time, T1g. Two field examples illustrate the method, and an error propagation study shows the reliability of the technique. Introduction NMR well logging yields information about fluid and rock properties. Depending on the goal of the investigation, various NMR measurement procedures are employed. Differences in the acquisition pulse sequence - including the wait-time (tw) between the echo-train measurements - characterize these procedures. Common evaluation techniques estimate different petrophysical properties, such as incremental and total porosities or movable (fm, NMR) and irreducible (fir, NMR) fluid fractions. More sophisticated methods separate the response of multiple fluids for hydrocarbon typing and saturation estimation. DTW NMR Log. Water as the wetting phase is dominated by surface relaxation and usually has a shorter T1 than hydrocarbons. DTW NMR uses the T1 contrast between aqueous fluid and hydrocarbon phases to achieve partial or full polarization for different fluid phases. The DTW log acquires two echo trains with a long (tw, L) and a short (tw, S) wait-time in a single pass; tw, L is chosen to fully polarize both water and hydrocarbon, and tw, S is sufficiently long to fully polarize the water fraction, while the hydrocarbon fraction is only partially polarized, causing porosity underestimation. An interpretation technique for DTW NMR data - used mainly qualitatively - is the differential spectrum method (DSM).1 A successful quantitative evaluation technique is the time domain analysis (TDA).2 Both techniques require the calculation of either differential echo signals or differential T2 spectra, where the spectra are derived from echo-train data by inversion. The differential signals are significantly weaker than the original signal, and the noise level increases because the incoherent noise of the echo trains is added. Differential data, therefore, are unfavorable in terms of their signal-to-noise ratio (SNR). SNR often limits the applicability of evaluation techniques that are based solely on NMR data. Particularly when coupled with low hydrocarbon saturation and the low proton density of a gas phase, poor SNR is the limiting factor in estimating accurate reservoir properties. Density Log. The density log provides a bulk density, ?b, of the investigated formation. Additional information about the density of the rock matrix and formation fluids determines the density porosity fr. An established method to evaluate gas-bearing formations combines the apparent porosities provided by the density and the neutron logging tools. For many data sets, however, this method yields only semiquantitative results because of the strong influence of rock mineralogy on the neutron measurement. Theory The porosity of clean formations bearing only liquid-phase components can be accurately quantified by either the NMR or the density logging tool. However, the tool's responses are significantly altered by the presence of a gas phase, causing the estimated porosities to deviate from the formation porosity. Three main effects cause the deviation.Low IH, g decreases the NMR porosity.Partial polarization Pg<1 decreases the NMR-derived porosity, if the wait-time between the NMR measurements is insufficiently long.Low ?g increases the density porosity. The characterization of a hydrocarbon gas by three key properties, ?g, IH, g, and T1g, effectively quantifies these effects. DTW NMR Log. In a two-phase system with one gas and one liquid phase, the total NMR porosity ft, NMR is expressed byEquation 1 where the first term on the right side describes the contribution of the gas phase and the second term describes the contribution of the liquid phase. The polarization P (with P?[0,1]) quantifies the reduction of the NMR signal caused by underpolarization. The termsEquation 2Equation 3 describe the polarization of the liquid and gas phases, respectively. Some approximations can be made for common reservoir conditions.IH, l is close to 1 for an aqueous-phase liquid and most oleic-phase liquids. In the presence of a light liquid hydrocarbon, its value can be slightly smaller (IH, l =0.8-1).If tw 3T1, the polarization is nearly unity. Typical tw values range from 1 to several seconds, whereas typical T1 values for formation water range from a few milliseconds to a few seconds. However, in a porous medium saturated with two fluid phases, the wetting phase (i.e., water) saturates smaller pores, and the maximum T1 of the aqueous-phase liquid usually reduces to values less than several hundreds of milliseconds.3 Thus, Pl is unity for aqueous-phase liquids in a two-phase system, when data are acquired with typical wait-time parameters in an MRIL®* DTW acquisition (i.e., tw, S,˜1–2 seconds and tw, L,˜6–10 seconds).


Author(s):  
Vladimir A. Nikiforov ◽  
Elena I. Laguseva ◽  
Evgeny A. Pankratov ◽  
Ilya S. Zhokhov

The brief characteristics of the reaction system of pilot production of fatty-aromatic polyamides based on aliphatic diamines (acylated monomers) and dicarboxylic acid dichloroanhydrides (acylating monomers) by the method of gas-liquid polycondensation in a highly turbulized foamy hydrodynamic mode are described. Technological scheme and rational instrumentation of the technology of polyterephthalamides, the reactor unit (reactor-fibridator), which includes a two-stage reaction chamber and a gas phase generating chamber coaxially located under it, chemistry and operating principle of the facility are shown. The method combines the chemical processes of polyamidation with the physical processes of the reaction molding of polyamide fibrids or gas-structural elements used in the technology of gas-filled plastics. The reaction system of the method includes three structural units: a liquid phase (aqueous alkaline solution of aliphatic, cycloaliphatic and fatty-aromatic diamines), a gas phase (superheated vapours of aromatic and aliphatic dicarboxylic acid dichloroanhydrides, dispersed in a dynamic airflow or inert gas) and an interface (gas-liquid interface). Gas-liquid polyamidation is accompanied by phase formation: the reaction system during the process becomes three-phase system – the swollen polymer forms a solid mobile phase (target product), which acts as a foamy mode stabilizer, which allows technological process to proceed at optimal linear gas phase rates of 30–35 m/s (unlike classical two-phase foamy mode – 4 m/s). A polyamidation mechanism at the liquid-gas interface is proposed, which includes two versions of the process (adsorption and condensation) depending on the ratio of the temperature characteristics of the acylated monomer and the liquid phase carrying the acylating monomer. Analysis of the proposed versions of the mechanism allows you to make an engineering decision on the expediency of organizing a cycle in the liquid phase. Possible criteria for predicting the versions of the mechanism and examples of reaction systems with condensation and absorption versions of polyamidation are given.


2015 ◽  
Vol 264 ◽  
pp. 706-719 ◽  
Author(s):  
Ahmad Shamiri ◽  
Suk Wei Wong ◽  
Mohd Fauzi Zanil ◽  
Mohamed Azlan Hussain ◽  
Navid Mostoufi

2021 ◽  
Vol 1016 ◽  
pp. 268-273
Author(s):  
Agnieszka Betzwar Kotas ◽  
Golta Khatibi ◽  
Farzad Khodabakhshi ◽  
Andreas Steiger-Thrisfeld

Transient liquid phase (TLP) bonds using Cu-Sn system have been suggested as high strength and temperature resistant joints for power electronics applications. While the physical and mechanical properties of these joints has been investigated to some extent, studies on fatigue properties and long term reliability of TLP joints are scarce. In this work TLP bonding was performed to produce thin Cu-Sn intermetallic joints by using Cu and 97Sn3Cu solder alloy as interlayer. Different processing conditions resulted in three types of thin joints consisting of three phases (Cu3Sn/Cu6Sn5/solder remnants), two phases (Cu3Sn/Cu6Sn5) and a single phase (Cu3Sn) with an overall thickness of ≤ 20 μm. The shear strength of the TLP joint containing one or two high melting point IMC layers showed a significant temperature resistance up to 200°C. Fatigue studies of TLP joints were conducted by using a 3-point-cyclic bending test system operating at 20 kHz. The highest fatigue resistance was obtained for the single-phase Cu3Sn joints with superior shear and flexural resistance. The two phase joints (Cu3Sn/Cu6Sn5) showed a slightly lower lifetime than the three phase system containing IMCs and residual solder. Fracture surfaces analysis in correlation with static and cyclic mechanical properties, provided insight into the failure mechanism of the Cu-Sn TLP joints.


Author(s):  
Léo Cunha Caldeira Mesquita ◽  
Aymeric Vié ◽  
Sébastien Ducruix

A two-staged swirling burner is numerically simulated through large eddy simulations. The impact of the liquid phase modeling approach is evaluated comparing the Eulerian and Lagrangian frameworks for two different operation points, full pilot injection and full multipoint injection. For the full multipoint injection, since the operation point is closer to a Lean Premixed Prevaporized (LPP) regime, both liquid phase models present similar flame structure (an M flame). For the full pilot injection, Eulerian and Lagrangian approaches result in different flames for equivalent boundary conditions: the Eulerian simulation produces a ‘tulip’ flame, while the Lagrangian spray forms a lifted flame. To assess the model sensitivity to boundary conditions parameters, complementary Lagrangian simulations are made varying injected droplets’ diameter and spray angle, this time resulting in a ‘tulip’ flame very similar to the Eulerian one. Finally, a last Eulerian simulation is made, where the injected droplets’ diameter is increased, still leading to a ‘tulip’ flame, showing that the strong interaction between liquid phase and flame highly impact the results.


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