An experimental method for predicting the composition and properties of a produced fluid under the conditions of a two-phase filtration of a gas-liquid mixture during field development for depletion

Author(s):  
Sergey A. Zanochuev ◽  
Alexander B. Shabarov

Within the objectives of predicting the composition and properties of the produced fluid during the development of oil and gas condensate fields, this article proposes an experimental method for predicting the composition and properties of the produced fluid. In addition, the authors show its practical use in a situation where the liquid phase (precipitated condensate or oil) is filtered together with the gas phase. Based on the proposed approach, experimental data were obtained on changes in the current gas saturation of the formation, as well as on changes in the composition and properties of the produced fluid during field development for depletion. The studies make use of the real reservoir fluid samples and the data from the results of stream experiments, in order to determine the relative phase permeabilities.

1986 ◽  
Vol 51 (6) ◽  
pp. 1222-1239 ◽  
Author(s):  
Pavel Moravec ◽  
Vladimír Staněk

Expression have been derived in the paper for all four possible transfer functions between the inlet and the outlet gas and liquid steams under the counter-current absorption of a poorly soluble gas in a packed bed column. The transfer functions have been derived for the axially dispersed model with stagnant zone in the liquid phase and the axially dispersed model for the gas phase with interfacial transport of a gaseous component (PDE - AD). calculations with practical values of parameters suggest that only two of these transfer functions are applicable for experimental data evaluation.


Author(s):  
Zhichao Guo ◽  
Zhaoci Li

Abstract In 2018, China’s natural gas import reached 90.39 million tons, and the liquefied natural gas (LNG) import was 53.78 million tons, accounting for 59.5% of total natural gas imports. With the construction of LNG terminals, more studies on the leakage of LNG storage and transportation facilities have emerged to prevent catastrophic consequences such as explosions and frostbite. However, most of previous researches focused on gas pipeline leakage after LNG gasification, and few of those have been done on LNG liquid pipeline leakage. In this paper, Fluent software is used to numerically simulate the process of LNG liquid pipeline leakage. After the occurrence of LNG leakage, it will suffer the process of endothermic, evaporation, and diffusion, which is considered as a two-phase diffusion process. The Euler-Lagrangian method is introduced to simulate the diffusion process of gas phase and liquid phase separately. In the simulation, the liquid phase is regarded as discrete droplets for discrete processing. The movement trajectory, heat transfer process and evaporation process of each droplet are tracked respectively. Different from the liquid phase, the gas phase is regarded as a continuous phase and the Navier-Stokes equations are adopted for calculation. Thereafter, coupling calculations of two phase are performed to determine the concentration field and temperature field of the LNG liquid pipeline leakage. As a supplement to this research, the influence of wind speed on LNG leakage and diffusion process is analysed in detail. Finally, the numerical simulation method is applied to a coastal LNG terminal in northern China to determine the distribution of natural gas concentration and temperature, as well as delimit the combustion range. The results can provide scientific reference for the delimitation of risky zones and the formulation of emergency response strategy.


Author(s):  
S. S. Koussa

A model for the prediction of the distribution of soot concentration in spray combustors is presented. Both gas-phase and liquid-phase soot formation have been considered. The methods have been developed within the constraints on detailed combustion modelling for practical application. Some predictions are assessed by comparison with published experimental data. It is concluded that predictions of the same quality as those of gaseous-fuelled combustors may be obtained neglecting liquid-phase soot formation in case of light fuels.


Author(s):  
J. C. Jepsen ◽  
J. L. Ralph

The object of this study was to obtain data on the radial variation of gas- and liquid-phase mass flux profiles in two-phase upflow in vertical pipelines. Experimental data were obtained on the radial gas-liquid flux, impact pressure, and linear liquid-phase velocity profiles for superficial gas- and liquid-phase velocities ranging from 20 to 125 ft/s and from 5 to 15 ft/s, respectively. Studies were made on 1-in, 4-in, and 8·4-in vertical pipelines and in a 1-in i.d. by 8·4-in o.d. vertical annular flow pipeline. Gas-liquid systems studied were air-water, air-aqueous glycerol, and air-tetrabromoethane. In Part 2 time-averaged radial liquid hold-up and linear-phase velocities were estimated from radial mass flux and impact pressure data. Estimates were also made on the magnitude, frequency, and velocity of the flow disturbances. Empirical correlations for mean liquid hold-up and pressure drop were developed from experimental data.


2020 ◽  
Vol 143 (1) ◽  
Author(s):  
Miguel Ballesteros ◽  
Nicolás Ratkovich ◽  
Eduardo Pereyra

Abstract Low liquid loading flow occurs very commonly in the transport of any kind of wet gas, such as in the oil and gas, the food, and the pharmaceutical industries. However, most studies that analyze this type of flow do not cover actual industry fluids and operating conditions. This study focused then on modeling this type of flow in medium-sized (6-in [DN 150] and 10-in [DN 250]) pipes, using computational fluid dynamics (CFD) simulations. When comparing with experimental data from the University of Tulsa, the differences observed between experimental and CFD data for the liquid holdup and the pressure drop seemed to fall within acceptable error, around 20%. Additionally, different pipe sections from a Colombian gas pipeline were simulated with a natural gas-condensate mixture to analyze the effect of pipe inclination and operation variables on liquid holdup, in real industry conditions. It was noticed that downward pipe inclinations favored smooth stratified flow and decreased liquid holdup in an almost linear fashion, while upward inclinations generated unsteady wavy flows, or even a possible annular flow, and increased liquid holdup and liquid entrainment into the gas phase.


2021 ◽  
Author(s):  
Mohammad J. Ahsan ◽  
Shaikha Al-Turkey ◽  
Nitin M. Rane ◽  
Fatemah A. Snasiri ◽  
Ahmed Moustafa ◽  
...  

Abstract Objectives/Scope The acquisition of mud gas data for well control and gathering of geological information is a common practice in oil and gas drilling. However, these data are scarcely used for reservoir evaluation as they are presumably considered as unreliable and non-representative of the formation content. Recent development in gas extraction from drilling mud and analyzing equipment has greatly improved the data quality. Combined with proper analysis and interpretation, these new datasets give valuable information in real-time lithological changes, hydrocarbons content, water contacts and vertical changes in fluid over a pay interval. Methods, Procedures, Process Post completion, Mud logging data have been compared with PVT results and they have shown excellent correlation on the C1-C5 composition, confirming the consistency between gas readings and reservoir fluid composition. Having such information in real time has given the oil company the opportunity to optimize its operations regarding formation evaluation, e.g downhole sampling, wireline logging or testing programs. Formation fluid is usually obtained during well tests, either by running downhole tools into the well or by collecting the fluid at surface. Therefore, its composition remains unknown until the arrival of the PVT well test results. This case intends to use mud gas information collected while drilling to predict information about the reservoir fluid composition in near real time. To achieve this goal we compared mud gas data collected while drilling with reservoir fluid compositional results. Pressure volume temperature (PVT) analysis is the process of determining the fluid behaviors and properties of oil and gas samples from existing wells. Results, Observations, Conclusions The reason any oil and gas company decides to drill a well is to turn the project into an oil-producing asset. But the value of the oil extracted from a single well is not the same as the value of the oil produced from another. The makeup of the oil, which can be determined from the compositional analysis, is an important piece of the equation that determines how profitable the play will be. The compositional analysis will determine just how much of each type of petroleum product can be produced from a single barrel of oil from that wells. Novel/Additive information Formation samples were obtained from offset wells in the Marrat Formation. These datasets gave valuable indications on fluid properties and phase behavior in the reservoir and provided strong base for reservoir engineering analysis, simulation and surface facilities design. The comparison of the gas data to PVT results gives a good match for reservoir fluid finger print, early acquisition of this data will help for decision enhancement for field development.


2001 ◽  
Vol 4 (04) ◽  
pp. 289-296
Author(s):  
Holger F. Thern ◽  
Songhua Chen

Summary Accurate estimates of porosity, fluid saturations, and in-situ gas properties are critical for the evaluation of a gas reservoir. By combining data from a dual wait-time (DTW) nuclear magnetic resonance (NMR) log and a density log, these properties can be determined more reliably than by either of the data alone. The density and NMR dual wait-time (DDTW) technique, introduced in this paper, is applicable to reservoirs where the pore-filling fluid consists of a liquid phase and a gas phase. The low proton density of the gas phase causes a reduction in the NMR signal strength resulting in underestimation of the apparent porosity. The polarization for different wait-times depends on the spin-lattice relaxation time of each fluid and may cause additional NMR porosity underestimation. The density log, on the other hand, delivers a porosity that is overestimated because of the presence of a gas phase. These data, together with known correlations for gas properties, yield a robust approach for the gas-zone porosity, f, and the flushed zone gas saturation, Sg, xo. DDTW also derives gas properties including the in-situ gas density, ?g, as well as the two NMR-related properties, hydrogen index, IH, g, and spin-lattice relaxation time, T1g. Two field examples illustrate the method, and an error propagation study shows the reliability of the technique. Introduction NMR well logging yields information about fluid and rock properties. Depending on the goal of the investigation, various NMR measurement procedures are employed. Differences in the acquisition pulse sequence - including the wait-time (tw) between the echo-train measurements - characterize these procedures. Common evaluation techniques estimate different petrophysical properties, such as incremental and total porosities or movable (fm, NMR) and irreducible (fir, NMR) fluid fractions. More sophisticated methods separate the response of multiple fluids for hydrocarbon typing and saturation estimation. DTW NMR Log. Water as the wetting phase is dominated by surface relaxation and usually has a shorter T1 than hydrocarbons. DTW NMR uses the T1 contrast between aqueous fluid and hydrocarbon phases to achieve partial or full polarization for different fluid phases. The DTW log acquires two echo trains with a long (tw, L) and a short (tw, S) wait-time in a single pass; tw, L is chosen to fully polarize both water and hydrocarbon, and tw, S is sufficiently long to fully polarize the water fraction, while the hydrocarbon fraction is only partially polarized, causing porosity underestimation. An interpretation technique for DTW NMR data - used mainly qualitatively - is the differential spectrum method (DSM).1 A successful quantitative evaluation technique is the time domain analysis (TDA).2 Both techniques require the calculation of either differential echo signals or differential T2 spectra, where the spectra are derived from echo-train data by inversion. The differential signals are significantly weaker than the original signal, and the noise level increases because the incoherent noise of the echo trains is added. Differential data, therefore, are unfavorable in terms of their signal-to-noise ratio (SNR). SNR often limits the applicability of evaluation techniques that are based solely on NMR data. Particularly when coupled with low hydrocarbon saturation and the low proton density of a gas phase, poor SNR is the limiting factor in estimating accurate reservoir properties. Density Log. The density log provides a bulk density, ?b, of the investigated formation. Additional information about the density of the rock matrix and formation fluids determines the density porosity fr. An established method to evaluate gas-bearing formations combines the apparent porosities provided by the density and the neutron logging tools. For many data sets, however, this method yields only semiquantitative results because of the strong influence of rock mineralogy on the neutron measurement. Theory The porosity of clean formations bearing only liquid-phase components can be accurately quantified by either the NMR or the density logging tool. However, the tool's responses are significantly altered by the presence of a gas phase, causing the estimated porosities to deviate from the formation porosity. Three main effects cause the deviation.Low IH, g decreases the NMR porosity.Partial polarization Pg<1 decreases the NMR-derived porosity, if the wait-time between the NMR measurements is insufficiently long.Low ?g increases the density porosity. The characterization of a hydrocarbon gas by three key properties, ?g, IH, g, and T1g, effectively quantifies these effects. DTW NMR Log. In a two-phase system with one gas and one liquid phase, the total NMR porosity ft, NMR is expressed byEquation 1 where the first term on the right side describes the contribution of the gas phase and the second term describes the contribution of the liquid phase. The polarization P (with P?[0,1]) quantifies the reduction of the NMR signal caused by underpolarization. The termsEquation 2Equation 3 describe the polarization of the liquid and gas phases, respectively. Some approximations can be made for common reservoir conditions.IH, l is close to 1 for an aqueous-phase liquid and most oleic-phase liquids. In the presence of a light liquid hydrocarbon, its value can be slightly smaller (IH, l =0.8-1).If tw 3T1, the polarization is nearly unity. Typical tw values range from 1 to several seconds, whereas typical T1 values for formation water range from a few milliseconds to a few seconds. However, in a porous medium saturated with two fluid phases, the wetting phase (i.e., water) saturates smaller pores, and the maximum T1 of the aqueous-phase liquid usually reduces to values less than several hundreds of milliseconds.3 Thus, Pl is unity for aqueous-phase liquids in a two-phase system, when data are acquired with typical wait-time parameters in an MRIL®* DTW acquisition (i.e., tw, S,˜1–2 seconds and tw, L,˜6–10 seconds).


Author(s):  
H. L. Mo ◽  
R. Prattipati ◽  
C. X. Lin

Pressure drop characteristics of R134a in annular helicoidal pipe was investigated experimentally with R134a flowing in the annular section. The experimental results revealed that when more R134a vapor was condensed, the liquid phase pressure drop increased largely while the vapor phase pressure drop decreased slightly. By comparing with the experimental data obtained from the same test section with R134a flowing in the inner circular tube of the helicoidal pipe, it was observed that the pressure drop for refrigerant in the annular section was always larger. It was also observed that the helicoidal pipe orientation showed little effect on the pressure drop variations. A pressure drop correlation was developed from the experimental data in terms of pressure drop multiplier with respect to Lockhart-Martinelli parameter.


Author(s):  
Vladimir A. Nikiforov ◽  
Elena I. Laguseva ◽  
Evgeny A. Pankratov ◽  
Ilya S. Zhokhov

The brief characteristics of the reaction system of pilot production of fatty-aromatic polyamides based on aliphatic diamines (acylated monomers) and dicarboxylic acid dichloroanhydrides (acylating monomers) by the method of gas-liquid polycondensation in a highly turbulized foamy hydrodynamic mode are described. Technological scheme and rational instrumentation of the technology of polyterephthalamides, the reactor unit (reactor-fibridator), which includes a two-stage reaction chamber and a gas phase generating chamber coaxially located under it, chemistry and operating principle of the facility are shown. The method combines the chemical processes of polyamidation with the physical processes of the reaction molding of polyamide fibrids or gas-structural elements used in the technology of gas-filled plastics. The reaction system of the method includes three structural units: a liquid phase (aqueous alkaline solution of aliphatic, cycloaliphatic and fatty-aromatic diamines), a gas phase (superheated vapours of aromatic and aliphatic dicarboxylic acid dichloroanhydrides, dispersed in a dynamic airflow or inert gas) and an interface (gas-liquid interface). Gas-liquid polyamidation is accompanied by phase formation: the reaction system during the process becomes three-phase system – the swollen polymer forms a solid mobile phase (target product), which acts as a foamy mode stabilizer, which allows technological process to proceed at optimal linear gas phase rates of 30–35 m/s (unlike classical two-phase foamy mode – 4 m/s). A polyamidation mechanism at the liquid-gas interface is proposed, which includes two versions of the process (adsorption and condensation) depending on the ratio of the temperature characteristics of the acylated monomer and the liquid phase carrying the acylating monomer. Analysis of the proposed versions of the mechanism allows you to make an engineering decision on the expediency of organizing a cycle in the liquid phase. Possible criteria for predicting the versions of the mechanism and examples of reaction systems with condensation and absorption versions of polyamidation are given.


2021 ◽  
Vol 24 (4) ◽  
pp. 17-27
Author(s):  
Hanna S. Vorobieva ◽  

The degree of dryness is the most important parameter that determines the state of a real gas and the thermodynamic properties of the working fluid in a two-phase region. This article presents a modified Redlich-Kwong-Aungier equation of state to determine the degree of dryness in the two-phase region of a real gas. Selected as the working fluid under study was CO2. The results were validated using the Span-Wanger equation presented in the mini-REFPROP program, the equation being closest to the experimental data in the CO2 two-phase region. For the proposed method, the initial data are temperature and density, critical properties of the working fluid, its eccentricity coefficient, and molar mass. In the process of its solution, determined are the pressure, which for a two-phase region becomes the pressure of saturated vapor, the volumes of the gas and liquid phases of a two-phase region, the densities of the gas and liquid phases, and the degree of dryness. The saturated vapor pressure was found using the Lee-Kesler and Pitzer method, the results being in good agreement with the experimental data. The volume of the gas phase of a two-phase region is determined by the modified Redlich-Kwong-Aungier equation of state. The paper proposes a correlation equation for the scale correction used in the Redlich-Kwongda-Aungier equation of state for the gas phase of a two-phase region. The volume of the liquid phase was found by the Yamada-Gann method. The volumes of both phases were validated against the basic data, and are in good agreement. The results obtained for the degree of dryness also showed good agreement with the basic values, which ensures the applicability of the proposed method in the entire two-phase region, limited by the temperature range from 220 to 300 K. The results also open up the possibility to develop the method in the triple point region (216.59K-220 K) and in the near-critical region (300 K-304.13 K), as well as to determine, with greater accuracy, the basic CO2 thermodynamic parameters in the two-phase region, such as enthalpy, entropy, viscosity, compressibility coefficient, specific heat capacity and thermal conductivity coefficient for the gas and liquid phases. Due to the simplicity of the form of the equation of state and a small number of empirical coefficients, the obtained technique can be used for practical problems of computational fluid dynamics without spending a lot of computation time.


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