Flashback Propensity of Syngas Flames at High Pressure: Diagnostic and Control

Author(s):  
S. Daniele ◽  
P. Jansohn ◽  
K. Boulouchos

Nowadays, the establishment of IGCC (integrated gasification combined cycle) plants, prompts a growing interest in synthetic fuels for gas turbine based power generation. This interest has as direct consequence the need for understanding of flashback phenomena for premixed systems operated with H2-rich gases. This is due to the different properties of H2 (e.g. reactivity and diffusivity) with respect to CH4 which lead to higher flame speeds in the case of syngases (mixtures of H2-CO). This paper presents the results of experiments at gas turbine like conditions (pressure up to 15 bar, 0.2 < Φ < 0.7, 577K < T0 < 674K) aimed to determine flashback limits and their dependence on the combustion parameters (pressure, inlet temperature and inlet velocity). For the experimental facility used for this work the back propagation of the flame is believed to happen into the boundary layer of the fuel/air duct. Flashback propensity was found to have an appreciable dependence on pressure and inlet temperature while the effects of inlet velocity variations are weak. Explanations for the dependence on these three parameters, based on consideration on laminar and turbulent flame speed data (from modeling and experiments), are proposed. Within the frame of this work, in order to avoid major damages, the experimental facility was equipped with an automatic control system for flashback described in the paper. The control system is able to detect flame propagation into the fuel/air supply, arrest it and restore safe operating conditions by moving the flame out of the fuel/air section without blowing it out. This avoids destruction of components (burner/mixing) and time consuming shut downs of the test rig.

Author(s):  
Alireza Kalantari ◽  
Nicolas Auwaijan ◽  
Vincent McDonell

Abstract Lean-premixed combustion is commonly used in gas turbines to achieve low pollutant emissions, in particular nitrogen oxides. But use of hydrogen-rich fuels in premixed systems can potentially lead to flashback. Adding significant amounts of hydrogen to fuel mixtures substantially impacts the operating range of the combustor. Hence, to incorporate high hydrogen content fuels into gas turbine power generation systems, flashback limits need to be determined at relevant conditions. The present work compares two boundary layer flashback prediction methods developed for turbulent premixed jet flames. The Damköhler model was developed at University of California Irvine (UCI) and evaluated against flashback data from literature including actual engines. The second model was developed at Paul Scherrer Institut (PSI) using data obtained at gas turbine premixer conditions and is based on turbulent flame speed. Despite different overall approaches used, both models characterize flashback in terms of similar parameters. The Damköhler model takes into account the effect of thermal coupling and predicts flashback limits within a reasonable range. But the turbulent flame speed model provides a good agreement for a cooled burner, but shows less agreement for uncooled burner conditions. The impact of hydrogen addition (0 to 100% by volume) to methane or carbon monoxide is also investigated at different operating conditions and flashback prediction trends are consistent with the existing data at atmospheric pressure.


2014 ◽  
Author(s):  
Roberto Carapellucci ◽  
Lorena Giordano

Efficiency improvement in the gas turbine sector has been mainly driven by increasing the turbine inlet temperature and compressor pressure ratio. For a fixed technology level, a further efficiency gain can be achieved through the utilization of waste thermal energy. Regeneration is an internal recovery technique that allows the reduction of heat input required at combustor, by preheating the air at compressor outlet. Under certain operating conditions, the temperature of exhaust gas leaving the regenerator is still enough high to allow the steam production via an heat recovery steam generator (HRSG). Regeneration in steam-gas power plants (CCGT) has the potential to enhance thermal efficiency, but reduces the margins for external recovery and then the bottoming steam cycle capacity. Moreover, the reduction of exhausts temperature at gas turbine outlet requires the reconsideration of HRSG operating parameters, in order to limit the increase of waste heat at the stack. The aim of this study is to explore the potential benefits that regeneration in the gas cycle gives on the whole steam-gas power plant. The extent of energy and economic performances improvement is evaluated, varying the gas turbine specifications and the layout and operating conditions of HRSG. Hence simple and regenerative configurations based on single and multi-pressure HRSG are compared, focusing on efficiency, specific CO2 emissions and unit cost of electricity (COE).


Author(s):  
Manikanda Rajagopal ◽  
Abdullah Karimi ◽  
Razi Nalim

A wave-rotor pressure-gain combustor (WRPGC) ideally provides constant-volume combustion and enables a gas turbine engine to operate on the Humphrey-Atkinson cycle. It exploits pressure (both compression and expansion) waves and confined propagating combustion to achieve pressure rise inside the combustor. This study first presents thermodynamic cycle analysis to illustrate the improvements of a gas turbine engine possible with a wave rotor combustor. Thereafter, non-steady reacting simulations are used to examine features and characteristics of a combustor rig that reproduces key features of a WRPGC. In the thermodynamic analysis, performance parameters such as thermal efficiency and specific power are estimated for different operating conditions (compressor pressure ratio and turbine inlet temperature). The performance of the WRPGC is compared with the conventional unrecuperated and recuperated engines that operates on the Brayton cycle. Fuel consumption may be reduced substantially with WRPGC introduction, while concomitantly boosting power. Simulations have been performed of the ignition of propane by a hot gas jet and subsequent turbulent flame propagation and shock-flame interaction.


Author(s):  
Thamir K. Ibrahim ◽  
M.M. Rahman

The combined cycle gas-turbine (CCGT) power plant is a highly developed technology which generates electrical power at high efficiencies. The first law of thermodynamics is used for energy analysis of the performance of the CCGT plant. The effects of varying the operating conditions (ambient temperature, compression ratio, turbine inlet temperature, isentropic compressor and turbine efficiencies, and mass flow rate of steam) on the performance of the CCGT (overall efficiency and total output power) were investigated. The programming of the performance model for CCGT was developed utilizing MATLAB software. The simulation results for CCGT show that the overall efficiency increases with increases in the compression ratio and turbine inlet temperature and with decreases in ambient temperature. The total power output increases with increases in the compression ratio, ambient temperature, and turbine inlet temperature. The peak overall efficiency was reached with a higher compression ratio and low ambient temperature. The overall efficiencies for CCGT were very high compared to the thermal efficiency of GT plants. The overall thermal efficiency of the CCGT quoted was around 57%; hence, the compression ratios, ambient temperature, turbine inlet temperature, isentropic compressor and turbine efficiencies, and mass flow rate of steam have a strong influence on the overall performance of the CCGT cycle.


Author(s):  
B. Law ◽  
B. V. Reddy

In the present work the effect of steam injection in the gas turbine combustion chamber is investigated on gas turbine and steam turbine work output and on thermal efficiency of the combined cycle power plant. The operating conditions investigated include gas turbine pressure ratio and gas turbine inlet temperature. The steam injection decreases the steam cycle output and boosts the gas cycle output and the net combined cycle work output and thermal efficiency significantly.


Author(s):  
S. Daniele ◽  
P. Jansohn ◽  
K. Boulouchos

This paper focuses on the description of the turbulent flame speed, at gas turbine like conditions, for different syngas mixtures, selected in order to simulate syngas compositions typically derived from gasification of coal, oil, biomass, and used for power generation in integrated gasification combined cycle (IGCC) processes. In this paper the turbulent flame speed is reported as global consumption rate and calculated based on a mass continuity approach applied to the combustor inlet area and the flame front surface, which was detected experimentally. Flame front detection was done by means of planar laser induced fluorescence technique taking OH radicals as seeding dyes. An in-house developed flame front detection software tool has been further improved and utilized in this work in order to better fit ultra-lean H2-rich flames. Experiments were carried out in a High Pressure Test Rig for operating pressures up to 15 bar. Data provided in this paper will focus on a pressure level of 5 bar, adiabatic flame temperatures up to 1900 K, inlet velocities from 40 to 80 m/s, and inlet temperature of 672 and 772 K. As expected, the results highlight the strongly elevated values of turbulent flame speed for high hydrogen containing fuel gas mixtures. Compared with flame speed data for pure CH4 the ratio (STSyn/STCH4) takes up values of 7 to 8. In absolute terms values go up even beyond 10 m/s. With increased H2 content in the mixture the burning velocity raises, due to the faster chemical kinetics characteristic of this compound and due to physical properties of H2 (Le&lt;1) which enhance flame front corrugation (i.e. flame front surface). Inlet velocity and pressure variations showed to have weak effect on the average flame front position whereas this last parameter is strongly affected by the mixture composition, the equivalence ratio and inlet temperature.


Author(s):  
S. Daniele ◽  
P. Jansohn

There is an obvious lack of data and understanding of the behavior of turbulent flames at high temperature and high pressure, especially concerning hydrogen containing fuels. Among the many relevant parameters, the turbulent flame speed “ST” is one of the most interesting for scientists and engineers. This paper reports an experimental investigation of premixed syngas combustion at gas-turbine like conditions, with emphasis on the determination of ST/SL derived as global fuel consumption per unit time. Experiments at pressures up to 2.00 MPa, inlet temperatures and velocities up to 773K and 150 m/s respectively, u′/SL greater than 100 are presented. Comparison between different syngas mixtures and methane clearly show much higher ST/SL for the former fuel. It is shown that ST/SL is strongly dependent on preferential diffusive-thermal (PDT) effects, co-acting with hydrodynamic effects, even for very high u′/SL. ST/SL increases with rising hydrogen content in the fuel mixture and with pressure. A correlation for ST/SL valid for all investigated fuel mixtures, including methane, is proposed in terms of turbulence properties (turbulence intensity and integral length scale), combustion properties (laminar flame speed and laminar flame thickness) and operating conditions (pressure and inlet temperature). The correlation captures effects of preferential diffusive-thermal and hydrodynamic instabilities.


Author(s):  
Fan Gong ◽  
Yong Huang

The objective of this work is to investigate the flame stabilization mechanism and the impact of the operating conditions on the characteristics of the steady, lean premixed flames. It’s well known that the flame base is very important to the existence of a flame, such as the flame after a V-gutter, which is typically used in ramjet and turbojet or turbofan afterburners and laboratory experiments. We performed two-dimensional simulations of turbulent premixed flames anchored downstream of the heat-conducting V-gutters in a confined passage for kerosene-air combustion. The flame bases are symmetrically located in the shear layers of the recirculation zone immediately after the V-gutter’s trailing edge. The effects of equivalence ratio of inlet mixture, inlet temperature, V-gutter’s thermal conductivity and inlet velocity on the flame base movements are investigated. When the equivalence ratio is raised, the flame base moves upstream slightly and the temperature gradient dT/dx near the flame base increases, so the flame base is strengthened. When the inlet temperature is raised, the flame base moves upstream very slightly, and near the flame base dT/dx increases and dT/dy decreases, so the flame base is strengthened. As the V-gutter’s thermal conductivity increases, the flame base moves downstream, and the temperature gradient dT/dx near the flame base decreases, so the flame base is weakened. When the inlet velocity is raised, the flame base moves upstream, and the convection heat loss with inlet mixture increases, so the flame base is weakened.


Author(s):  
P. Griebel ◽  
R. Bombach ◽  
A. Inauen ◽  
R. Scha¨ren ◽  
S. Schenker ◽  
...  

The present experimental study focuses on flame characteristics and turbulent flame speeds of lean premixed flames typical for stationary gas turbines. Measurements were performed in a generic combustor at a preheating temperature of 673 K, pressures up to 14.4 bars (absolute), a bulk velocity of 40 m/s, and an equivalence ratio in the range of 0.43–0.56. Turbulence intensities and integral length scales were measured in an isothermal flow field with Particle Image Velocimetry (PIV). The turbulence intensity (u′) and the integral length scale (LT) at the combustor inlet were varied using turbulence grids with different blockage ratios and different hole diameters. The position, shape, and fluctuation of the flame front were characterized by a statistical analysis of Planar Laser Induced Fluorescence images of the OH radical (OH-PLIF). Turbulent flame speeds were calculated and their dependence on operating conditions (p, φ) and turbulence quantities (u′, LT) are discussed and compared to correlations from literature. No influence of pressure on the most probable flame front position or on the turbulent flame speed was observed. As expected, the equivalence ratio had a strong influence on the most probable flame front position, the spatial flame front fluctuation, and the turbulent flame speed. Decreasing the equivalence ratio results in a shift of the flame front position farther downstream due to the lower fuel concentration and the lower adiabatic flame temperature and subsequently lower turbulent flame speed. Flames operated at leaner equivalence ratios show a broader spatial fluctuation as the lean blow-out limit is approached and therefore are more susceptible to flow disturbances. In addition, because of a lower turbulent flame speed these flames stabilize farther downstream in a region with higher velocity fluctuations. This increases the fluctuation of the flame front. Flames with higher turbulence quantities (u′, LT) in the vicinity of the combustor inlet exhibited a shorter length and a higher calculated flame speed. An enhanced turbulent heat and mass transport from the recirculation zone to the flame root location due to an intensified mixing which might increase the preheating temperature or the radical concentration is believed to be the reason for that.


Author(s):  
Walter W. Shelton ◽  
Robin W. Ames ◽  
Richard A. Dennis ◽  
Charles W. White ◽  
John E. Plunkett ◽  
...  

The U.S. Department of Energy’s (DOE) provides a worldwide leadership role in the development of advanced fossil fuel-based energy conversion technologies, with a focus on electric power generation with carbon capture and storage (CCS). As part of DOE’s Office of Fossil Energy, the National Energy Technology Laboratory (NETL) implements research, development, and demonstration (RD&D) programs that address the challenges of reducing greenhouse gas emissions. To meet these challenges, NETL evaluates advanced power cycles that will maximize system efficiency and performance, while minimizing CO2 emissions and the costs of CCS. NETL’s Hydrogen Turbine Program has sponsored numerous R&D projects in support of Advanced Hydrogen Turbines (AHT). Turbine systems and components targeted for development include combustor technology, materials research, enhanced cooling technology, coatings development, and more. The R&D builds on existing gas turbine technologies and is intended to develop and test the component technologies and subsystems needed to validate the ability to meet the Turbine Program goals. These technologies are key components of AHTs, which enable overall plant efficiency and cost of electricity (COE) improvements relative to an F-frame turbine-based Integrated Gasification Combined Cycle (IGCC) reference plant equipped with carbon capture (today’s state-of-the-art). This work has also provided the basis for estimating future IGCC plant performance based on a Transformational Hydrogen Turbine (THT) with a higher turbine inlet temperature, enhanced material capabilities, reduced air cooling and leakage, and higher pressure ratios than the AHT. IGCC cases from using system-level AHT and THT gas turbine models were developed for comparisons with an F-frame turbine-based IGCC reference case and for an IGCC pathway study. The IGCC pathway is presented in which the reference case (i.e. includes F-frame turbine) is sequentially-modified through the incorporation of advanced technologies. Advanced technologies are considered to be either 2nd Generation or Transformational, if they are anticipated to be ready for demonstration by 2025 and 2030, respectively. The current results included the THT, additional potential transformational technologies related to IGCC plant sections (e.g. air separation, gasification, gas cleanup, carbon capture, NOx reduction) are being considered by NETL and are topics for inclusion in future reports.


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