Effect of Ni Coating Over Cu Ball on the Microstructure of Flip Chip Joints With Cu-Cored Solder Balls

Author(s):  
Ikuo Shohji ◽  
Yuji Shiratori ◽  
Hiroshi Yoshida ◽  
Masahiko Mizukami ◽  
Akira Ichida

Effect of Ni coating over the Cu core of Cu-cored Sn-5mass%Ag balls was investigated on the microstructures of flip chip joints with Ni/Au plated Cu pads after reflow soldering and the subsequent heat exposure at 423 K. For joints using Cu-cored Sn-5Ag balls with Ni coating over the Cu core, a Ni-Sn reaction layer forms at the Cu core/Sn-5Ag interface. A similar Ni-Sn reaction layer forms at the interface between the Sn-5Ag solder and the Ni/Au plated Cu pad. Although the Ni-Sn reaction layers grow with increasing the thermal exposure time, the growth rate is slower than that of a Cu-Sn reaction layer formed at the Cu core/Sn-5Ag interface in the joint with the Cu-cored Sn-5Ag ball without Ni coating over the Cu core.

2011 ◽  
Vol 462-463 ◽  
pp. 82-87 ◽  
Author(s):  
Ikuo Shohji ◽  
Ryohei Arai ◽  
Hisao Ishikawa ◽  
Masao Kojima

The tensile properties of Sn-x(x=1, 2, 3)Ag-0.5Cu-0.05Ni-0.005Ge (mass%) alloys were investigated. In addition, the ball shear force was investigated with solder balls and two types electrodes, Cu and electroless Ni/Au plated Cu, to examine joint reliability under heat exposure conditions. Tensile strength of the alloy decreases with decreasing the Ag content. On the contrary, elongation increases with decreasing the Ag content. When the Ag content reduces, primary β-Sn phases are coarsened and eutectic microstructures diminish. The decrease of the eutectic microstructures causes a reduction of the tensile strength. In as-soldered joints with Sn-Ag-Cu-Ni-Ge solder balls and Cu electrodes, the ball shear force increases with increasing the Ag content. However, the ball shear force decreases with increasing heat exposure time. After heat exposure treatment at 423 K for 500 h, the ball shear force is relatively stable at lower values regardless of the Ag content. In the joints with electroless Ni/Au plated Cu electrodes, the ball shear force slightly increases with increasing heat exposure time. Even after heat exposure treatment at 423 K for 500 h, hierarchy of the ball shear force is maintained. The ball shear force becomes high with increasing the Ag content.


Atmosphere ◽  
2021 ◽  
Vol 12 (2) ◽  
pp. 175
Author(s):  
Jan Geletič ◽  
Michal Lehnert ◽  
Pavel Krč ◽  
Jaroslav Resler ◽  
Eric Scott Krayenhoff

The modelling of thermal exposure in outdoor urban environments is a highly topical challenge in modern climate research. This paper presents the results derived from a new micrometeorological model that employs an integrated biometeorology module to model Universal Thermal Climate Index (UTCI). This is PALM-4U, which includes an integrated human body-shape parameterization, deployed herein for a pilot domain in Prague, Czech Republic. The results highlight the key role of radiation in the spatiotemporal variability of thermal exposure in moderate-climate urban areas during summer days in terms of the way in which this directly affects thermal comfort through radiant temperature and indirectly through the complexity of turbulence in street canyons. The model simulations suggest that the highest thermal exposure may be expected within street canyons near the irradiated north sides of east–west streets and near streets oriented north–south. Heat exposure in streets increases in proximity to buildings with reflective paints. The lowest heat exposure during the day may be anticipated in tree-shaded courtyards. The cooling effect of trees may range from 4 °C to 9 °C in UTCI, and the cooling effect of grass in comparison with artificial paved surfaces in open public places may be from 2 °C to 5 °C UTCI. In general terms, this study illustrates that the PALM modelling system provides a new perspective on the spatiotemporal differentiation of thermal exposure at the pedestrian level; it may therefore contribute to more climate-sensitive urban planning.


1992 ◽  
Vol 2 (1) ◽  
pp. 15 ◽  
Author(s):  
L Valbuena ◽  
R Tarrega ◽  
E Luis

The influence of high temperatures on germination of Cistus laurifolius and Cistus ladanifer seeds was analyzed. Seeds were subjected to different temperatures for different times, afterwards they were sowed in plastic petri dishes and monitored for germinated seeds over two months.The germination rate observed in Cistus ldanifer was greater than in Cistus laurifolius. In both species, heat increased germination percentages. For Cistus laurifolius higher temperatures or longer exposure times were needed. Germination percentages of Cistus ladanifer were lower when heat exposure time was 15 minutes.It must be emphasized that germination occurred when seeds were not treated, while seeds exposed to 150�C for 5 minutes or more did not germinate.


Author(s):  
Pushkraj Tumne ◽  
Vikram Venkatadri ◽  
Santosh Kudtarkar ◽  
Michael Delaus ◽  
Daryl Santos ◽  
...  

Today’s consumer market demands electronics that are smaller, faster and cheaper. To cater to these demands, novel materials, new designs, and new packaging technologies are introduced frequently. Wafer Level Chip Scale Package (WLCSP) is one of the emerging package technologies that have the key advantages of reduced cost and smaller footprint. The portable consumer electronics are frequently dropped; hence the emphasis of reliability is shifting towards study of effects of mechanical shock loading increasingly. Mechanical loading typically induces brittle fractures (also known as intermetallic failures) between the solder bumps and bond pads at the silicon die side. This type of failure mechanism is typically characterized by the board level drop test. WLCSP is a variant of the flip-chip interconnection technique. In WLCSPs, the active side of the die is inverted and connected to the PCB by solder balls. The size of these solder balls is typically large enough (300μm pre-reflow for 0.5mm pitch and 250μm pre-reflow for 0.4mm pitch) to avoid use of underfill that is required for the flip-chip interconnects. Several variations are incorporated in the package design parameters to meet the performance, reliability, and footprint requirements of the package assembly. The design parameters investigated in this effort are solder ball compositions with different Silver (Ag) content, backside lamination with different thickness, WLCSP type –Direct and Re-Distribution Layer (RDL), bond pad thickness, and sputtered versus electroplated Under Bump Metallurgy (UBM) deposition methods for 8×8, 9×9, and 10×10 array sizes. The test vehicles built using these design parameters were drop tested using JEDEC recommended test boards and conditions as per JESD22-B11. Cross sectional analysis was used to identify, confirm, and classify the intermetallic, and bulk solder failures. The objective of this research was to quantify the effects and interactions of WLCSP design parameters through drop test. The drop test data was collected and treated as a right censored data. Further, it was analyzed by fitting empirical distributions using the grouped and un-grouped data approach. Data analysis showed that design parameters had a significant effect on the drop performance and played a vital role in influencing the package reliability.


2004 ◽  
Author(s):  
Ridha Baccouche ◽  
Andy Sherman ◽  
Susan Ward ◽  
David Wagner ◽  
Craig Miller ◽  
...  

An investigation of the service life aging and heat exposure effects on extruded aluminum alloy properties and structural crashworthiness has been conducted. This research, part of a broader program, consists of investigating five aluminum alloy extrusions each of which is subjected to two heat treatments. The aluminum extrusion investigated are 6063T6, 6061T6, 6260T6, 6014T6, and 7129T6. The two heat treatments are 177°C for 30 minutes and 200°C for 24 hours. The 200°C/24 hours treatment represents an upper limit thermal exposure i.e. components adjacent to exhaust pipes and manifolds. The 200°C heat treatment was applied in addition to the 177°C for 30 minutes. All specimens were subjected to the reference 177°C for 30 minutes treatment. These ten crash members were subjected to dynamic axial crashing at a target speed of 40 kph (25 mph). Force-time data was collected and responses were plotted for all tests. Force-displacement responses were then integrated for the crash energy management and mean axial crash load for each of the aluminum extruded crash members. Bar charts were then generated to describe the crash loads and energy management behaviors of the various aluminum alloys and associated heat treatments. Service life simulated heat exposure was found to effect the mean crash load and crash energy management of the aluminum structural crash members. The heat exposure effects on the crashworthiness of the extruded aluminum members ranged from a reduction of 10% to over 20% in the mean crash load and crash energy management with highest variation observed with the 6260T6 aluminum extrusion.


2007 ◽  
Vol 201 (18) ◽  
pp. 7952-7960 ◽  
Author(s):  
D. Seo ◽  
K. Ogawa ◽  
M. Tanno ◽  
T. Shoji ◽  
S. Murata

2001 ◽  
Vol 699 ◽  
Author(s):  
Xiaodong Zou ◽  
Tariq Makram ◽  
Rosario A. Gerhardt

AbstractWaspaloy is a nickel base super-alloy used in aircraft engines. When this alloy is placed in service, it is subjected to long term exposure at high temperatures, which can cause the reinforcing gamma prime precipitate population to fluctuate and thus affect its structural integrity. The population fluctuates as a result of coarsening, dissolution or re-precipitation. Samples exposed to 1200° F for times ranging from 0 to 12626 hours were characterized using impedance spectroscopy, microhardness measurements, x-ray diffraction and quantitative stereology. Two important parameters were derived from the impedance measurements: (1) the imaginary admittance peak magnitude (Ymax) and (2) the associated relaxation frequency (fmax). As the distribution, shape and size of the precipitates change with exposure time, these parameters were also found to vary. In addition to the changes in precipitate geometry, lattice constant changes detected by analyzing x-ray diffraction data suggest that there are compositional shifts in the matrix as well as the gamma prime precipitates. Furthermore, the preferred orientation of the precipitates can also be seen to change with exposure time. These changes in composition, size and shape as a function of thermal exposure time are accompanied by changes in the volume fractions of primary and secondary gamma prime particles present. Using effective medium models, it is possible to predict that the measured properties are related to the gamma prime population. The grain boundary carbides do not appear to play any role at the conditions presented.


Author(s):  
Takahiro Kano ◽  
Ikuo Shohji ◽  
Tetsuyuki Tsuchida ◽  
Toshikazu Ookubo

An electroless Ni/Pd/Au plated electrode is expected to be used as an electrode material for lead-free solder to improve joint reliability. The aim of this study is to investigate the effect of the thickness of the Pd layer on joint properties of the lead-free solder joint with the electroless Ni/Pd/Au plated electrode. Solder ball joints were fabricated with Sn-3Ag-0.5Cu (mass%) lead-free solder balls and electroless Ni/Pd/Au and Ni/Au plated electrodes. Ball shear force and microstructure of the joint were investigated. The (Cu,Ni)6Sn5 reaction layer formed in the joint interface in all specimens. The thickness of the reaction layer decreased with increasing the thickness of the Pd layer. In the joint with a Pd layer 0.36 μm thick, the remained Pd layer was observed in the joint interface. In the joint, impact shear force decreased compared with that of the joint without the remained Pd layer. On the contrary, when the thickness of the Pd layer was less than 0.36 μm, the Pd layer was not remained in the joint interface and impact shear force improved. Impact shear force of the joint with the electroless Ni/Pd/Au plated electrode was higher than that with the electroless Ni/Au one.


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